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Chemical Physics

Comment to the paper “Quantum mechanical effects for a hydrogen atom confined in a dielectric spherical microcavity”

Michael‐Adán Martínez‐Sánchez, Rubicelia Vargas, Jorge Garza

Published Aug 7, 2023• 0 citations
Publisher
DOI
10.1016/j.chemphys.2023.112040

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The research on the disorder of quantum system plays a very important role in the field of quantum information, and has received much attention from theoretical and experimental researchers. However, it is very difficult to study the disorder of atoms trapped in microcavity due to their complex nonlocal space-time evolution characteristics. To solve this problem, we present a method to study the internal disorder of hydrogenic atoms trapped in microcavity, that is, to characterize and investigate the disorder of the confined system by using the quantum information entropy and shape complexity of the system. The Shannon information entropy and shape complexity in position space and momentum space (Sr, Sp, C[r], C[p]) are calculated and analyzed for different quantum states of hydrogenic atom in InN dielectric spherical microcavity, and pay special attention to the exploration of the influence of quantum confinement effect on the disorder of the system. The results show that when the radius of the spherical microcavity is very small, the quantum confinement effect is more significant, and a series of extreme points appears in the shape complexity curve of the system, which is caused by the joint interaction of information entropy and spatial inhomogeneity. With the increase of the radius of the spherical cavity, the effect of quantum confinement is weakened, and the Shannon information entropy and shape complexity of the confined hydrogenic atom are similar to the counterparts of the hydrogenic atom in free space. Our work provides an effective method to study the internal disorder of a confined quantum. This work provides an effective method for studying the internal disorder of confined quantum systems and presents some references for the information measurement of confined quantum systems.