Chinese Physics B

Mixed-field effect at the hyperfine level of 127I79Br in its rovibronic ground state: Toward field manipulation of cold molecules

Zhengbin 正斌 Bao 包, Defu 得富 Wang 王, Xu-Ping Shao, Yunxia 云霞 Huang 黄, Xiaohua 晓华 Yang 杨

Published Jul 11, 2023• 5 citations

Abstract

The mixed-field effect at the hyperfine level of the rovibronic ground state of the 127I79Br (X1Σ, v = 0, J = 0) molecule is computed on the J–I uncoupled basis of |JMJI 1 M 1 I 2 M 2〉, where J is the molecular total angular momentum excluding nuclear spin, MJ is the projection number of J, I 1 and I 2 are the nuclear spins of the iodine and bromine atoms, and M 1 and M 2 are the projection numbers of I 1 and I 2, respectively. When the two applied electric and magnetic fields are parallel, the perturbations are rare and only one perturbation is observed in a relatively large field regime in our computation range. However, when the two fields are off-parallel, the perturbations increase significantly and some sublevels show the Feshbach-like resonance phenomenon. Therefore, such sublevels transit between weak-field seeking and strong-field seeking repeatedly, which can be utilized to enhance or suppress cold molecular collision and chemical reaction rates. Such behavior of the molecular hyperfine structure in the mixed off-parallel fields may also be utilized to construct an electric-field-assisted anti-Helmholtz magnetic trap for cold molecules and to realize evaporative cooling of cold molecules (sub-mK) into the ultracold regime (μK).

DOI: 10.1088/1674-1056/ace61c

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