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UNITEXT for physics

Solution of Schrödinger Equation: Boundary and Continuity Conditions in Coordinate Representation

Tapan Kumar Das

Published Jan 1, 2023• 0 citations
Publisher
DOI
10.1007/978-981-99-0494-5_8

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The Schrödinger equation, in hyperspherical coordinates, is solved in closed form for a system of three particles on a line, interacting via pair delta functions. This is for the case of equal masses and potential strengths. The interactions are replaced by appropriate boundary conditions. This leads then to requiring the solution of a free-particle Schrödinger equation subject to these boundary conditions. A generalized Kontorovich–Lebedev transformation is used to write this solution as an integral involving a product of Bessel functions and pseudo-Sturmian functions. The coefficient of the product is obtained from a three-term recurrence relation, derived from the boundary condition. The contours of the Kontorovich–Lebedev representation are fixed by the asymptotic conditions. The scattering matrix is then derived from the exact solution of the recurrence relation. The wavefunctions that are obtained are shown to be equivalent to those derived by McGuire. The method can clearly be applied to a larger number of particles and hopefully might be useful for unequal masses and potentials.
We develop systematically a new unifying approach to the analysis of linear stochastic, quantum stochastic and even deterministic equations in Banach spaces. Solutions to a wide class of these equations (in particular those describing the processes of continuous quantum measurements) are proved to coincide with the interaction representations of the solutions to certain Dirac type equations with boundary conditions in pseudo-Fock spaces. The latter are presented as the semiclassical limit of an appropriately dressed unitary evolutions corresponding to a boundary-value problem for rather general Schrödinger equations with bounded below Hamiltonians.