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UNITEXT for physics

One-Dimensional Potentials

Tapan Kumar Das

Published Jan 1, 2023• 0 citations
Publisher
DOI
10.1007/978-981-99-0494-5_9

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First, this article explains the formula of one - dimensional infinitely deep square potential well's energy levels from stationary state schrodinger equation, and then deduces the same formula from one - dimensional half infinitely high square potential well' s energy levels diagram of graphic. solution, and proves that one - dimensional leveles are limit of one - dimensional half infinitely high square potential well' s energy levels. Finally it discusses the energy levels' number of one - dimensional half infinitely high square potential well and gives out the differentiateating formula about it.
In the previous chapter we have analyzed the peculiarities of quantized electron motion in layered structures with one-dimensional potential wells. From the mathematical point of view, the solution of the Schrödinger equation for one-dimensional potential profiles is much simpler. However, many quantum objects, such as atoms, molecules, and quantum dots, are three-dimensional objects. Thus, in order to analyze electron motion in such objects we need to find solutions of the Schrödinger equation for three-dimensional potential profiles. The electron motion in spaces with dimensionality higher than one, especially for rectangular potential profiles with infinite potential barriers, is not so difficult to analyze. At the same time we have to keep in mind that such potential profiles frequently represent some approximation of the more complex, real potential profiles. Depending on the type of structure and on the form of the potential profile, the electron motion may be limited in two directions (two-dimensional quantization) or in three directions (three-dimensional quantization). In this chapter we will show that the existence of discrete energy levels in the electron spectrum is an intrinsic feature of electron motion in potential wells of any form and dimensionality. An electron in a rectangular potential well (quantum box) In the previous chapter we studied the electron motion in one-dimensional potential wells. An electron's motion along one direction was confined by the potential profile and the momentum in this direction was quantized.
Abstract The one‐electron potential, derived from the electron density, is a three‐dimensional function, whereas Bohm's quantum potential depends on the spatial coordinates of all involved electrons. To analyze the relationship between the two potentials in the many‐electron case, first the dimensionality of the quantum potential needs to be reduced to match that of the one‐electron potential. A possible approach for such dimensionality reduction by calculating the expectation value of the quantum potential over all but one electron, using the factorization of the real part of the wave function into a marginal and conditional function is presented, and a relation between such three‐dimensional local quantum potential and the one‐electron potential is given. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001