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Chemical Physics Reviews

Pure dephasing, quantum decoherence, and wave–particle duality

Minhaeng Cho

Published May 26, 2023• 6 citations
Publisher

Abstract

Ultrafast spectroscopy is a valuable tool for monitoring the timescales of interactions between systems and their environments, resulting in pure dephasing. The superposition of ground and excited states of a molecule in a condensed phase, created by field–matter interactions, loses its coherence due to fluctuations from surrounding molecules that interact differently with the ground and excited states. Recently, quantum decoherence has become an intense area of research due to its relevance to the quantum-to-classical transition and its critical role in developing quantum technologies, such as quantum computers and cryptography. Although both pure dephasing and quantum decoherence result from the same process of environmental monitoring of systems through quantum entanglement between the system and its environment, they have been studied and discussed in very different contexts with seemingly disparate terminologies. In this work, we present a detailed theoretical description of pure dephasing and quantum decoherence in bosonic environments coupled to a two-level system, compare them directly, and demonstrate their connections to the wave–particle duality of isolated systems and the wave-particle-entanglement triality of composite systems consisting of systems and their environments. It is believed that the present review will be helpful for gaining a deeper understanding of ultrafast spectroscopy from a quantum mechanical perspective and the wave–particle duality of quantum objects interacting with their surrounding environments.

DOI
10.1063/5.0149363

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In chapter 1, we shall give a survey of the various types of approach which can be employed to analyse the dynamics of open quantum systems that leads to decoherence effects. In chapter 2, we shall give a general description about quantum network and its possible applications. In chapter 3, we shall discuss the problem of quantum state transfer in qubit network and shall give a brief overview of some scheme that enable nearly prefect state transfer. In chapter 4, we shall discuss singlet-triplet networks, that is networks having on each site a pair of (generally entangled) qubit. Then within this framework we propose a model stemming from quantum dot array. There we shall address the problem of ground state preparation and state transfer. Finally we shall describe the inherent entanglement of the ground state of strongly correlated systems can be exploited for both classical and quantum communications. 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•May 11, 2015•0 citations
Ultrafast spectroscopy is a valuable tool for monitoring the timescales of interactions between systems and their environments, resulting in pure dephasing. The superposition of ground and excited states of a molecule in a condensed phase, created by field–matter interactions, loses its coherence due to fluctuations from surrounding molecules that interact differently with the ground and excited states. Recently, quantum decoherence has become an intense area of research due to its relevance to the quantum-to-classical transition and its critical role in developing quantum technologies, such as quantum computers and cryptography. Although both pure dephasing and quantum decoherence result from the same process of environmental monitoring of systems through quantum entanglement between the system and its environment, they have been studied and discussed in very different contexts with seemingly disparate terminologies. In this work, we present a detailed theoretical description of pure dephasing and quantum decoherence in bosonic environments coupled to a two-level system, compare them directly, and demonstrate their connections to the wave–particle duality of isolated systems and the wave-particle-entanglement triality of composite systems consisting of systems and their environments. It is believed that the present review will be helpful for gaining a deeper understanding of ultrafast spectroscopy from a quantum mechanical perspective and the wave–particle duality of quantum objects interacting with their surrounding environments.
This chapter explains the basic concept of decoherence and how it damps out quantum interference of a superposition state. Quantum decoherence plays an important role in the interpretation of quantum mechanics. The quantum information processing fields like quantum computers, quantum communication and quantum cryptography depend very much on how to minimize and control the quantum decoherence. Quantum decoherence helps to know the fundamental reasons of understanding the very nature of quantum mechanics, the measurement process and the boundary between quantum and classical behaviour. A double-slit experiment can be used to explain the basic concept of decoherence. The chapter discusses the master equations which give the dynamical evolution of the quantum system and the environment entangled state. It also discusses some of the decoherence models. In the collisional decoherence model, a massive free quantum particle scatters environmental particles. In the spin-boson models, the quantum system is represented by qubits and the environment by collision of harmonic oscillators.
Two-path interference of quantum particles with internal spin (qubits) interacting on one arm of the interferometer with bosonic environment is studied. It is assumed that the energy exchange between the qubit and its environment is either absent, which is a pure dephasing (decoherence) model, or very weak. Both the amplitude and the position of maximum of an output intensity discussed as a function of a phase shift can serve as a quantifier of parameters describing coupling between qubit and its environment. The time evolution of the qubit–environment system is analyzed in the Schrödinger picture and the output intensity for qubit–environment interaction close to pure decoherence is analyzed by means of perturbation theory. Quality of the applied approximation is verified by comparison with numerical results.
Decoherence of quantum signals is one of the main challenges of modern quantum information systems and technologies. This phenomenon is defined as the degradation of the coherent state of a quantum system as a result of environmental influences, which directly affects the information reliability of qubits, as well as the preservation of oscillations and superposition. Decoherence is a natural process of a quantum system when the system interacts with a thermally active or other quantum-mechanically active environment. This effect is important both in theoretical research and in practical quantum devices, including the development of quantum telecommunications, quantum computing, and high-precision quantum sensors. In cryogenic environments, where the temperature approaches zero Kelvin, the reduction of thermal excitations ensures the long-term preservation of the quantum signal. Under such conditions, zero-point fluctuations remain the only source of decoherence, which significantly increases the coherence of qubits and the possibility of performing complex quantum operations. At relatively high temperatures, bosonic and color spectrum excitations significantly increase the decoherence rate, which leads to rapid degradation of the quantum signal and a rapid transition of the system state towards the classical paradigm.
Decoherence is a relatively recent concept in the field of quantum mechanics. Although the pioneers of the field must have understood that loss of phase coherence in quantum superpositions is the reason underlying the appearance of definite outcomes in the quantum measurement problem, the latter was not treated in terms of decoherence until sixty years after the formulation of quantum mechanics as described in a report by Joos and Zeh in 1983 [1]. However, soon after, the theory was developed in further detail, and experiments to measure the actual decoherence rates in various systems commenced. Today, decoherence is the main concern for another reason, i.e., the fact that superposition states must be maintained undisturbed in the quantum communication systems and decoherence presents a strong limitation for their practical application. Decoherence appears in open quantum systems, where the basic system under consideration interacts relatively strongly with an environment. Decoherence times may be as long as seconds for small atomic systems in extreme vacua, although below what is presently measurable (i.e., less than a fraction of a femtosecond) in most liquids and solids, where coupling to the surrounding molecules or atomic arrangements is strong. The relatively slow decoherence in well-isolated particle systems has been described in several recent articles on quantum optics, while the rapid decoherence in liquids and solids has not received this kind of attention. It is the purpose of the present review to fill this gap.
We are in the midst of a renaissance in the study and interpretation of fundamental quantum mechanics, from quantum coherence and quantum entanglement to the quantum measurement process. This stems partly from the impressive advances in experimental techniques that are making yesterday's gedanken experiment today's reality. Another reason quantum coherence and entanglement have come to the forefront is the emerging and tantalizing field of quantum information science. The ability to store information in quantum systems may someday yield devices that process quantum superpositions of inputs in parallel or improve communication through the `wiring' implicit in quantum entanglement. Indeed, quantum computing has the remote prospect of revolutionizing the way we store and process information. This has become particularly important in the face of impending limits on the miniaturization of conventional computers due to quantum effects. Of course, all real systems face limits imposed by decoherence, or the environmentally-induced destruction of quantum coherence. Here, superpositions of quantum states suddenly become probabilistic mixtures of states when they interact with the environment or when the system parameters are fluctuating. Decoherence theory is commonly interpreted as a way to quantify the elusive boundary between quantum and classical worlds and almost always precludes the existence of complex quantum superpositions, except at extremely short time scales. In practice, it is very important to study how decoherence appears in particular quantum systems and try to fight against it. In this special issue of Journal of Optics B: Quantum and Semiclassical Optics , we highlight recent results in the exciting area of quantum coherence and entanglement, including generating interesting and complex quantum states, characterizing coherence and entanglement in these systems, and triumphing over relevant decoherence processes. We hope this issue will not only act as a bookmark in the ongoing study of fundamental quantum mechanics, but will also help guide the rapid developments in quantum information science.
The title of the present dissertation Decoherence in Quantum Network sounds very general and all-inclusive. Indeed it embraces two topics (decoherence and quantum network) from the area of Quantum Mechanics each of which is described in all respects by a huge literature developed in the last three decades [...]. Quantum decoherence, as the name lets it mean, is the mechanism that makes a quantum system loose its coherence properties, and with them the capability of giving rise to interference phenomena or to other interesting quantum effects [...]. The key idea promoted by decoherence is the insight that realistic quantum systems are never isolated, but are immersed in the surrounding environment and interact continuously with it [...]. As an example one may consider a two-level quantum system (i.e. a quantum bit, usually shortened with a terminology from information science to \\qubit" ) in contact with a wide environment. Hence, quantum systems are open systems, and continuously interact or exchange information with an external environment whose degrees of freedom are too numerous to be monitored. The resulting correlation between the system and the environment spoils quantum coherence and brings about the transition from a pure quantum state to a mixture of quantum state resulting a classical state. To describe decoherence different kind of approaches can be used (for example Master equation, random matrix, etc). A quantum network typically consists of a number of quantum objects (e.g., atoms, ions, quantum dots, cavities, etc.), to be referred to hereafter as the sites or the nodes of the network. They can interact and the interactions (or their correlations) will be usually described by the edges of a graph. Quantum networks can address different information processing tasks. For instance a quantum state can be transferred from qubit to qubit down a chain solely due to the interactions, that is according to the laws of quantum physics [...]. Quantum networks offer us new opportunities and phenomena as compared to classical networks. An extension to large scale of the idea of a quantum network could lead to a futurible quantum internet [...]. The study of networks has traditionally been the territory of graph theory [...], also with the advent of their quantum versions. Within simple quantum network model information processing is usually described by assuming perfect control of the underlying graph. However, this is not much realistic since randomness is often present and it leads to decoherence effects [...]. In contrast, the conservation of coherence is essential for any quantum information process [...], hence there is a persistent interest in decoherence effects in quantum networks, which motivate us to study models for describing such noisy effects. We consider a simple model of quantum network, employing qubits (spin-1/2 particles) attached to the nodes of an underlying graph and we study the simplest task, namely information storage (on a single and two qubits), when the graph randomly changes in time. Actually we randomly add edges to an initially disconnected graph according to the Gilbert model characterized by a weighting parameter ex [...] and in an identically and independent way at each time step. We find that by increasing ex the dynamics of relevant quantities like fidelity, entropy or concurrence, gradually transforms from damped to damped oscillatory and finally to purely oscillatory. That leads to the paper [see, Information dissipation in random quantum networks, by U. Farooq and S. Mancini, OSID 21(3), 1450004, 2014]. We also study a system composed by pairs of qubits attached to each node of a linear chain, a model that stems from quantum dot arrays. Here we use the approach of evolution with a stochastic Hamiltonian to describe the noisy effects. We then evaluate the effect of two most common disorders, namely exchange coupling and hyperfine interaction fluctuations, in adiabatic preparation of ground state in such model. We show that the adiabatic ground state preparation is highly robust against these disorders making the chain a good analog simulator. Moreover, we also study the adiabatic information transfer, using singlet-triplet states, across the chain. In contrast to ground state preparation the transfer mechanism is highly affected by disorders. This suggested that for communication tasks across such chains adiabatic evolution is not as effective and quantum quenches would be preferable. That leads to the paper [see, Adiabatic many-body state preparation and information transfer in quantum dot arrays, by U. Farooq, A. Bayat, S. Mancini and S. Bose Phys. Rev. B 91, 134303, 2015]. The present work is organized as follows. In chapter 1, we shall give a survey of the various types of approach which can be employed to analyse the dynamics of open quantum systems that leads to decoherence effects. In chapter 2, we shall give a general description about quantum network and its possible applications. In chapter 3, we shall discuss the problem of quantum state transfer in qubit network and shall give a brief overview of some scheme that enable nearly prefect state transfer. In chapter 4, we shall discuss singlet-triplet networks, that is networks having on each site a pair of (generally entangled) qubit. Then within this framework we propose a model stemming from quantum dot array. There we shall address the problem of ground state preparation and state transfer. Finally we shall describe the inherent entanglement of the ground state of strongly correlated systems can be exploited for both classical and quantum communications. In chapter 5, we shall propose a decoherence model for qubit networks based on edges representing XY interactions randomly added to a disconnected graph accordingly to a suitable probability distribution. In this way we shall describe dissipation of information initially localize in single or two qubits all over the network. In chapter 6 we shall model the noisy effects in the quantum dot array introduced in chapter 4 and investigate their consequences on the preparation of ground state and quantum state transfer mechanism. Finally we shall draw conclusions.