Abstract Modern applications of quantum mechanics are illustrated, and the simplifications offered by operator and algebraic techniques are highlighted. The various "pictures" (Schrödinger, Heisenberg, and Interaction or Dirac) are discussed and their origins are motivated. It is shown that operator techniques simplify the harmonic oscillator and angular momentum through the use of ladder operators. The WKB approximation boundary conditions are developed through the use of complex number algebra. Other topics that benefit from these techniques are discussed, including the squeezing of optical fields and various alternative solutions to the hydrogen atom.
Abstract Modern applications of quantum mechanics are illustrated, and the simplifications offered by operator and algebraic techniques are highlighted. The various "pictures" (Schrödinger, Heisenberg, and Interaction or Dirac) are discussed and their origins are motivated. It is shown that operator techniques simplify the harmonic oscillator and angular momentum through the use of ladder operators. The WKB approximation boundary conditions are developed through the use of complex number algebra. Other topics that benefit from these techniques are discussed, including the squeezing of optical fields and various alternative solutions to the hydrogen atom.
Since the main purpose of the book was to demonstrate the philosophy and spirit behind the standard formulation of quantum mechanics, a thorough discussion of applications have taken a somewhat backseat. This was also done to keep the book accessible to a wide audience. Even outsiders interested to get a glimpse of quantum mechanics could get by with some minimal linear algebra provided in the book itself. Thus, technical and calculational details (which cannot be avoided if one were to discuss applications) had to be mostly avoided in the main text. However, in order that the book could still serve as an introductory text for a mainstream course, we make an exception in this chapter. Here we treat three of the mostwell known applications of quantum mechanics: Harmonic Oscillator, Angular Momentum and Hydrogen Atom. Both the analytical and the algebraic, ladder operator methods are demonstrated for solving the eigenvalue problems for the Harmonic oscillator and angular momentum. Topics involving technical calculations (e.g., calculations involving Hermite polynomials, spherical harmonics, etc.), modelling of real life systems (e.g., atomic polarizability) and spin have been relegated to the problem sets with elaborate hints and guidelines for working through them.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.
This text presents a rigorous mathematical account of the principles of quantum mechanics, in particular as applied to chemistry and chemical physics. Applications are used as illustrations of the basic theory. The first two chapters serve as an introduction to quantum theory, although it is assumed that the reader has been exposed to elementary quantum mechanics as part of an undergraduate physical chemistry or atomic physics course. Following a discussion of wave motion leading to Schrödinger's wave mechanics, the postulates of quantum mechanics are presented along with essential mathematical concepts and techniques. The postulates are rigorously applied to the harmonic oscillator, angular momentum, the hydrogen atom, the variation method, perturbation theory, and nuclear motion. Modern theoretical concepts such as hermitian operators, Hilbert space, Dirac notation, and ladder operators are introduced and used throughout. This text is appropriate for beginning graduate students in chemistry, chemical physics, molecular physics and materials science.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.