Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

PRX Quantum

Photon-Emission-Correlation Spectroscopy as an Analytical Tool for Solid-State Quantum Defects

Rebecca E. K. Fishman, Raj N. Patel, David A. Hopper, Tzu‐Yung Huang, Lee C. Bassett

Published Mar 6, 2023• 33 citations
Publisher

Abstract

Photon-emission-correlation spectroscopy is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects.In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology.Beyond the single-photon purity of an emitter, however, photon-correlation measurements can provide a wealth of information that can reveal details about its electronic structure and optical dynamics that are hidden by other spectroscopy techniques.This tutorial presents a standardized framework for using photon-emission-correlation spectroscopy to study quantum emitters, including discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation.We highlight important nuances and best practices regarding the commonly used g (2) (τ = 0) < 0.5 test for single-photon emission.Finally, we illustrate how this experimental technique can be paired with optical-dynamics simulations to formulate an electronic model for unknown quantum emitters, enabling the design of quantum control protocols and assessment of their suitability for quantum information science applications.

DOI
10.1103/prxquantum.4.010202

Related papers

Photon emission correlation spectroscopy as an analytical tool for\n quantum defects

Rebecca E. K. Fishman, Raj N. Patel, David A. Hopper +2 more

Photon emission correlation spectroscopy is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects. In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology. Beyond an emitter's single-photon purity, however, photon correlation measurements can provide a wealth of information that can reveal details about its electronic structure and optical dynamics that are hidden by other spectroscopy techniques. This tutorial presents a standardized framework for using photon emission correlation spectroscopy to study quantum emitters, including discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation. We highlight important nuances and best practices regarding the commonly-used $g^{(2)}(\\tau=0)<0.5$ test for single-photon emission. Finally, we illustrate how this experimental technique can be paired with optical dynamics simulations to formulate an electronic model for unknown quantum emitters, enabling the design of quantum control protocols and assessment of their suitability for quantum information science applications.

arXiv:2111.01252•Nov 1, 2021•2 citations

Room temperature dynamics of quantum emitters through photon emission correlation spectroscopy

Rebecca Fishman

Photon emission correlation spectroscopy (PECS) is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects. In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology. Beyond single-photon purity, photon correlation measurements can provide a wealth of information that can reveal details about an emitter's electronic structure and optical dynamics that are hidden by other spectroscopy techniques. This thesis explores the application of PECS to study and understand the optical dynamics of quantum emitters. The first part of this thesis presents a guide to a standardized framework for using PECS to facilitate materials exploration for qubit candidates. This includes discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation of PECS. It also illustrates how this experimental technique can be paired with optical dynamics simulations to formulate an electronic model for unknown quantum emitters. The second part of this thesis implements the practices discussed in the first part to explore the optical dynamics of two systems: the nitrogen-vacancy (NV) center in diamond and a quantum emitter in hexagonal boron nitride (h-BN). The NV center is a promising platform for applications in quantum sensing, quantum communication, and quantum networks. In particular, its spin and charge dynamics constitute useful attributes that can be harnessed for quantum control protocols. This thesis models and quantifies the transition rates that govern spin and charge dynamics in the NV center, utilizing PECS measurements, analysis, and simulations as a function of magnetic field, and excitation power. These findings can further inform the design of quantum control protocols. H-BN hosts pure single-photon emitters that have shown evidence of optically detected electronic spin dynamics. However, the electrical and chemical structure of these optically addressable spins is unknown, and the nature of their spin-optical interactions remains mysterious. This thesis discusses time-domain optical and microwave experiments to characterize a single emitter in h-BN exhibiting room temperature optically detected magnetic resonance. It further discusses use of dynamical simulations to constrain and quantify transition rates in the model, and design of optical control protocols that optimize the signal-to-noise ratio for spin readout. This constitutes a necessary step towards quantum control of spin states in h-BN.

•Jan 1, 2024•0 citations

Experimental certification of level dynamics in single-photon emitters

Lukáš Lachman, Ilya P. Radko, Maxime Bergamin +3 more

Emitters of single photons are essential resources for emerging quantum technologies and developed within different platforms including nonlinear optics and atomic and solid-state systems. The energy-level structures of emission processes are critical for reaching and controlling high-quality sources. The most commonly applied test uses a Hanbury Brown and Twiss (HBT) setup to determine the emitter energy-level structure based on fitting temporal correlations of photon detection events. However, only partial information about the emission process is extracted from such detection, that might be followed by an inconclusive fitting of the data. This process predetermines our limited ability to quantify and understand the dynamics in the photon emission process that are of importance for the applications in communication, sensing, and computing. In this work, we present a complete analysis based on all normalized coincidences between detection and no-detection events recorded in the same HBT setup to certify expected properties of an emitted photonic state. As a proof of concept we apply our methodology to single nitrogen-vacancy centers in diamond, in which case the certification conclusively rejects a model based on a two-level emitter that radiates a photonic state mixed with any classical noise background. Published by the American Physical Society 2024

arXiv:2407.13273•Physical Review Research•Sep 5, 2024•2 citations

Polarization Dynamics of Solid-State Quantum Emitters

Anand Kumar, Çağlar Samaner, Chanaprom Cholsuk +10 more

Quantum emitters in solid-state crystals have recently attracted a lot of attention due to their simple applicability in optical quantum technologies. The polarization of single photons generated by quantum emitters is one of the key parameters that play a crucial role in the applications, such as quantum computation that uses the indistinguishability of photons. However, the degree of single photon polarization is typically quantified using time-averaged photoluminescence intensity of single emitters, which provides limited information about the dipole properties in solids. In this work, we use single defects in hexagonal boron nitride and nanodiamond as efficient room-temperature single photon sources to reveal the origin and the temporal evolution of dipole orientation in solid-state quantum emitters. The angle of excitation and emission dipoles relative to the crystal axes are determined experimentally and then calculated using density functional theory, which results in characteristic angles for every specific defect that can be used as an efficient tool for defect identification and understanding their atomic structure. Moreover, the temporal polarization dynamics reveal a strongly modified linear polarization visibility that depends on the excited state decay time of individual excitation. This effect can be traced back potentially to the excitation of excess charges in the local crystal environment. Understanding such hidden time-dependent mechanisms can further be used to improve the performance of polarization-sensitive experiments, in particular that of quantum communication with single photon emitters.

arXiv:2303.04732•Mar 8, 2023•4 citations

A Concise Primer on Solid-State Quantum Emitters

Shicheng Yu, Xiaojie Zhang, Xia Lei +1 more

Quantum emitters serve as essential on-demand photonic resources, generating quantum states of light such as single photons and entangled photon pairs while serving as interfaces between light and matter. Buried in the solid state, quantum emitters enable a straightforward adoption of advanced nanofabrication techniques, facilitating precise engineering of their photonic environment for scalable quantum technologies. In this review, we introduce the fundamentals of quantum emitters and the key metrics characterising their performance. We highlight three material platforms: quantum dots, defect centres in diamond, and defect centres in silicon carbide. We summarise the recent developments of these platforms and discuss their advancements in quantum applications, including quantum communication, computation, and sensing. Finally, we provide a comparison across the three platforms, along with an outlook on future directions and potential challenges.

arXiv:2506.06684•IEEE Journal of Selected Topics in Quantum Electronics•May 27, 2025•2 citations

Many-Body Entanglement in Solid-State Emitters

Emma Daggett, Christian M. Lange, Bennet Windt +23 more

The preparation and control of quantum states lie at the heart of quantum information science (QIS). Recent advances in solid-state quantum emitters (QEs) and nanophotonics have transformed the landscape of quantum photonic technologies, enabling scalable generation of quantum states of light and matter. A new frontier in solid-state quantum photonics is the engineering of many-body interactions between QEs and photons to achieve robust coherence and controllable many-body entanglement. These entangled states, including photonic graph and cluster states, superradiant emission, and emergent quantum phases, are promising for quantum computation, sensing, and simulation. However, intrinsic inhomogeneities and decoherence in solid-state platforms pose significant challenges to realize such complex entangled states. This review provides an overview of the fundamental many-body interactions and dynamics at the light-matter interfaces of solid-state QEs, and discusses recent advances in mitigating decoherence and harnessing robust many-body coherence.

quant-pharXiv:2511.20797•Nov 27, 2025•0 citations
Photon-emission-correlation spectroscopy is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects.In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology.Beyond the single-photon purity of an emitter, however, photon-correlation measurements can provide a wealth of information that can reveal details about its electronic structure and optical dynamics that are hidden by other spectroscopy techniques.This tutorial presents a standardized framework for using photon-emission-correlation spectroscopy to study quantum emitters, including discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation.We highlight important nuances and best practices regarding the commonly used g (2) (τ = 0) < 0.5 test for single-photon emission.Finally, we illustrate how this experimental technique can be paired with optical-dynamics simulations to formulate an electronic model for unknown quantum emitters, enabling the design of quantum control protocols and assessment of their suitability for quantum information science applications.
Photon emission correlation spectroscopy is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects. In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology. Beyond an emitter's single-photon purity, however, photon correlation measurements can provide a wealth of information that can reveal details about its electronic structure and optical dynamics that are hidden by other spectroscopy techniques. This tutorial presents a standardized framework for using photon emission correlation spectroscopy to study quantum emitters, including discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation. We highlight important nuances and best practices regarding the commonly-used g(2)(tau=0)<0.5g^{(2)}(\\tau=0)<0.5g(2)(tau=0)<0.5 test for single-photon emission. Finally, we illustrate how this experimental technique can be paired with optical dynamics simulations to formulate an electronic model for unknown quantum emitters, enabling the design of quantum control protocols and assessment of their suitability for quantum information science applications.
Photon emission correlation spectroscopy (PECS) is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects. In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology. Beyond single-photon purity, photon correlation measurements can provide a wealth of information that can reveal details about an emitter's electronic structure and optical dynamics that are hidden by other spectroscopy techniques. This thesis explores the application of PECS to study and understand the optical dynamics of quantum emitters. The first part of this thesis presents a guide to a standardized framework for using PECS to facilitate materials exploration for qubit candidates. This includes discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation of PECS. It also illustrates how this experimental technique can be paired with optical dynamics simulations to formulate an electronic model for unknown quantum emitters. The second part of this thesis implements the practices discussed in the first part to explore the optical dynamics of two systems: the nitrogen-vacancy (NV) center in diamond and a quantum emitter in hexagonal boron nitride (h-BN). The NV center is a promising platform for applications in quantum sensing, quantum communication, and quantum networks. In particular, its spin and charge dynamics constitute useful attributes that can be harnessed for quantum control protocols. This thesis models and quantifies the transition rates that govern spin and charge dynamics in the NV center, utilizing PECS measurements, analysis, and simulations as a function of magnetic field, and excitation power. These findings can further inform the design of quantum control protocols. H-BN hosts pure single-photon emitters that have shown evidence of optically detected electronic spin dynamics. However, the electrical and chemical structure of these optically addressable spins is unknown, and the nature of their spin-optical interactions remains mysterious. This thesis discusses time-domain optical and microwave experiments to characterize a single emitter in h-BN exhibiting room temperature optically detected magnetic resonance. It further discusses use of dynamical simulations to constrain and quantify transition rates in the model, and design of optical control protocols that optimize the signal-to-noise ratio for spin readout. This constitutes a necessary step towards quantum control of spin states in h-BN.
Emitters of single photons are essential resources for emerging quantum technologies and developed within different platforms including nonlinear optics and atomic and solid-state systems. The energy-level structures of emission processes are critical for reaching and controlling high-quality sources. The most commonly applied test uses a Hanbury Brown and Twiss (HBT) setup to determine the emitter energy-level structure based on fitting temporal correlations of photon detection events. However, only partial information about the emission process is extracted from such detection, that might be followed by an inconclusive fitting of the data. This process predetermines our limited ability to quantify and understand the dynamics in the photon emission process that are of importance for the applications in communication, sensing, and computing. In this work, we present a complete analysis based on all normalized coincidences between detection and no-detection events recorded in the same HBT setup to certify expected properties of an emitted photonic state. As a proof of concept we apply our methodology to single nitrogen-vacancy centers in diamond, in which case the certification conclusively rejects a model based on a two-level emitter that radiates a photonic state mixed with any classical noise background. Published by the American Physical Society 2024
Quantum emitters in solid-state crystals have recently attracted a lot of attention due to their simple applicability in optical quantum technologies. The polarization of single photons generated by quantum emitters is one of the key parameters that play a crucial role in the applications, such as quantum computation that uses the indistinguishability of photons. However, the degree of single photon polarization is typically quantified using time-averaged photoluminescence intensity of single emitters, which provides limited information about the dipole properties in solids. In this work, we use single defects in hexagonal boron nitride and nanodiamond as efficient room-temperature single photon sources to reveal the origin and the temporal evolution of dipole orientation in solid-state quantum emitters. The angle of excitation and emission dipoles relative to the crystal axes are determined experimentally and then calculated using density functional theory, which results in characteristic angles for every specific defect that can be used as an efficient tool for defect identification and understanding their atomic structure. Moreover, the temporal polarization dynamics reveal a strongly modified linear polarization visibility that depends on the excited state decay time of individual excitation. This effect can be traced back potentially to the excitation of excess charges in the local crystal environment. Understanding such hidden time-dependent mechanisms can further be used to improve the performance of polarization-sensitive experiments, in particular that of quantum communication with single photon emitters.
Quantum emitters serve as essential on-demand photonic resources, generating quantum states of light such as single photons and entangled photon pairs while serving as interfaces between light and matter. Buried in the solid state, quantum emitters enable a straightforward adoption of advanced nanofabrication techniques, facilitating precise engineering of their photonic environment for scalable quantum technologies. In this review, we introduce the fundamentals of quantum emitters and the key metrics characterising their performance. We highlight three material platforms: quantum dots, defect centres in diamond, and defect centres in silicon carbide. We summarise the recent developments of these platforms and discuss their advancements in quantum applications, including quantum communication, computation, and sensing. Finally, we provide a comparison across the three platforms, along with an outlook on future directions and potential challenges.
The preparation and control of quantum states lie at the heart of quantum information science (QIS). Recent advances in solid-state quantum emitters (QEs) and nanophotonics have transformed the landscape of quantum photonic technologies, enabling scalable generation of quantum states of light and matter. A new frontier in solid-state quantum photonics is the engineering of many-body interactions between QEs and photons to achieve robust coherence and controllable many-body entanglement. These entangled states, including photonic graph and cluster states, superradiant emission, and emergent quantum phases, are promising for quantum computation, sensing, and simulation. However, intrinsic inhomogeneities and decoherence in solid-state platforms pose significant challenges to realize such complex entangled states. This review provides an overview of the fundamental many-body interactions and dynamics at the light-matter interfaces of solid-state QEs, and discusses recent advances in mitigating decoherence and harnessing robust many-body coherence.