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World Journal of Mechanics

Explanation of Relation between Wave Function and Probability Density Based on Quantum Mechanics in Phase Space

Chol Jong, Jin-Sim Kim, Shin-Hyok Jon, Son-Il Jo

Published Jan 1, 2023• 1 citation
Publisher

Abstract

The main problem of quantum mechanics is to elucidate why the probability density is the modulus square of wave function. For the purpose of solving this problem, we explored the possibility of deducing the fundamental equation of quantum mechanics by starting with the probability density. To do so, it is necessary to formulate a new theory of quantum mechanics distinguished from the previous ones. Our investigation shows that it is possible to construct quantum mechanics in phase space as an alternative autonomous formulation and such a possibility enables us to study quantum mechanics by starting with the probability density rather than the wave function. This direction of research is contrary to configuration-space formulation of quantum mechanics starting with the wave function. Our work leads to a full understanding of the wave function as the both mathematically and physically sufficient representation of quantum-mechanical state which supplements information on quantum state given solely by the probability density with phase information on quantum state. The final result of our work is that quantum mechanics in phase space satisfactorily elucidates the relation between the wave function and the probability density by using the consistent procedure starting with the probability density, thus corroborating the ontological interpretation of the wave function and withdrawing a main assumption of quantum mechanics.

DOI
10.4236/wjm.2023.131002

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The main problem of quantum mechanics is to elucidate why the probability density is the modulus square of wave function. For the purpose of solving this problem, we explored the possibility of deducing the fundamental equation of quantum mechanics by starting with the probability density. To do so, it is necessary to formulate a new theory of quantum mechanics distinguished from the previous ones. Our investigation shows that it is possible to construct quantum mechanics in phase space as an alternative autonomous formulation and such a possibility enables us to study quantum mechanics by starting with the probability density rather than the wave function. This direction of research is contrary to configuration-space formulation of quantum mechanics starting with the wave function. Our work leads to a full understanding of the wave function as the both mathematically and physically sufficient representation of quantum-mechanical state which supplements information on quantum state given solely by the probability density with phase information on quantum state. The final result of our work is that quantum mechanics in phase space satisfactorily elucidates the relation between the wave function and the probability density by using the consistent procedure starting with the probability density, thus corroborating the ontological interpretation of the wave function and withdrawing a main assumption of quantum mechanics.
The wave function gives not the density of stuff, but gives rather (on squaring its modulus) the density of probability. Probability of what, exactly? Not of the electron being there, but of the electron being found there, if its position is ‘measured’. Why this aversion to ‘being’ and insistence on ‘finding’? The founding fathers were unable to form a clear picture of things on the remote atomic scale . John S. Bell (1990) Introduction The physical meaning of the wave function is an important interpretative problem of quantum mechanics. Notwithstanding nearly ninety years of development of the theory, it is still an unsolved issue. During recent years, more and more research has been done on the ontological status and meaning of the wave function (see, e.g. Monton, 2002; Lewis, 2004; Gao, 2011a, 2011b; Pusey, Barrett and Rudolph, 2012; Ney and Albert, 2013). In particular, Pusey, Barrett and Rudolph (2012) demonstrated that under certain non-trivial assumptions such as the preparation independence assumption, the wave function of a quantum system is a representation of the physical state of the system. This poses a further question, namely whether the reality of the wave function can be argued without resorting to non-trivial assumptions. Moreover, a harder problem is to determine the ontological meaning of the wave function, which is still a hot topic of debate in the realistic alternatives to quantum mechanics such as the de Broglie–Bohm theory or Bohmian mechanics (Belot, 2012). In this chapter, we will first give a clearer argument for the reality of the wave function in terms of protective measurements, which does not depend on non-trivial assumptions and can also overcome existing objections. Next, based on an analysis of the mass and charge properties of a quantum system, we will propose a new ontological interpretation of the wave function. According to this interpretation, the wave function of an N -body system represents the state of ergodic motion of N particles.
In this paper, we propose an ontological interpretation of the wave function in terms of random discontinuous motion of particles. Ac-cording to this interpretation, the wave function of an N-body quan-tum system describes the state of random discontinuous motion of N particles, and in particular, the modulus squared of the wave function gives the probability density that the particles appear in every possible group of positions in space. We present three arguments supporting this new interpretation of the wave function. These arguments are mainly based on an analysis of the mass and charge properties of a quantum system. It is realized that the Schrödinger equation, which governs the evolution of a quantum system, contains more information about the system than the wave function of the system, such as the mass and charge properties of the system, which might help understand the ontological meaning of the wave function. Finally, we briefly an-alyze possible implications of the suggested ontological interpretation of the wave function for the solutions to the measurement problem. The wavefunction gives not the density of stuff, but gives rather (on squaring its modulus) the density of probability. Probability of what exactly? Not of the electron being there, but of the electron being found there, if its position is ‘measured’. Why this aversion to ‘being ’ and insistence on ‘finding’? The founding fathers were unable to form a clear picture of things on the remote atomic scale. (Bell 1990)
In quantum mechanics, the physical state of an electron is described by a wave function. According to the standard probability interpretation, the wave function of an electron is probability amplitude, and its modulus square gives the probability density of finding the electron in a certain position in space. In this article, we show that this central assumption of quantum mechanics may have an ontological extension. It is argued that microscopic particles such as electrons are indeed particles, but their motion is not continuous but discontinuous and random. On this view, the modulus square of the wave function not only gives the probability density of the particles being found in certain locations, but also gives the probability density of the particles being there. In other words, the wave function in quantum mechanics can be regarded as a representation of the state of random discontinuous motion of particles, and at a deeper level, it may represent the dispositional property of the particles that determines their random discontinuous motion.
The review of new formulation of conventional quantum mechanics where the quantum states are identified with probability distributions is presented. The invertible map of density operators and wave functions onto the probability distributions describing the quantum states in quantum mechanics is constructed both for systems with continuous variables and systems with discrete variables by using the Born's rule and recently suggested method of dequantizer-quantizer operators. Examples of discussed probability representations of qubits (spin-1/2, two-level atoms), harmonic oscillator and free particle are studied in detail. Schrödinger and von Neumann equations, as well as equations for the evolution of open systems, are written in the form of linear classical-like equations for the probability distributions determining the quantum system states. Relations to phase-space representation of quantum states (Wigner functions) with quantum tomography and classical mechanics are elucidated.
A quantum mechanical representation suitable for studying the time evolution of quantum densities in phase space is proposed and examined in detail. This representation on ℒ2 (2) phase space is based on definitions of the operators P̂ and Q̂ in phase space that satisfy various correspondences for the Liouville equation in classical and quantum phase space, as well as quantum position and momentum ℒ2 (1) spaces. The definitions presented here, P̂=p/2−iℏ∂/∂q and Q̂=q/2+iℏ∂/∂p, are related to definitions that have been recently proposed [J. Chem. Phys. 93, 8862 (1990)]. The resulting quantum phase space representation shares many of the mathematical properties of usual representations in coordinate and momentum spaces. Within this representation, time evolution equations for complex-valued functions (wave functions) and their square magnitudes (distribution functions) are derived, and it is shown that the coordinate and momentum space time evolution equations can be recovered by a simple Fourier projection. The phase space quantum probability conservation equation obtained is a good illustration of the quantization rule that requires one to replace the classical Poisson bracket between the Hamiltonian and the probability density with the quantum commutator between the corresponding operators. The possible classical analogs to quantum probabilities densities are also considered and some of the present results are illustrated for the dynamics of the coherent state.
This paper discusses the relationship between the Wigner function, along with other related quasiprobability distribution functions, and the probability density distribution function constructed from the wave function of the Schr\"odinger equation in quantum phase space, as formulated by Torres-Vega and Frederick (TF). At the same time, a general approach in solving the wave function of the Schr\"odinger equation of TF quantum phase space theory is proposed. The relationship of the wave functions between the TF quantum phase space representation and the coordinate or momentum representation is thus revealed.