The chapter explicates the experimental context in which Bohr worked and offers an account of his gradually devised conceptual approach to experimental apparatus and research in physics at the most basic level. As it explains, two distinct stages in Bohr’s vision of physics provided the foundation for his main contributions to early quantum theory and quantum mechanics: the stage of inducing the basic lower-level hypotheses from experiments and the stage of inducing higher-level theoretical hypotheses via intermediary hypotheses. These stages were also apparent in his reflections on the practice of physics and his gradual development as a physicist.
The chapter explicates the experimental context in which Bohr worked and offers an account of his gradually devised conceptual approach to experimental apparatus and research in physics at the most basic level. As it explains, two distinct stages in Bohr’s vision of physics provided the foundation for his main contributions to early quantum theory and quantum mechanics: the stage of inducing the basic lower-level hypotheses from experiments and the stage of inducing higher-level theoretical hypotheses via intermediary hypotheses. These stages were also apparent in his reflections on the practice of physics and his gradual development as a physicist.
This chapter begins with a brief outline of some of the key motivations for considering a quantum theory: the early attempts to determine the spectral distribution of energy density of black bodies; stability of atoms and molecules; specific heats of solids; interference and diffraction of light beams; polarization of photons. The experimental foundations of wave mechanics are then presented in detail, but in a logical order quite different from its historical development: photo-emission of electrons by metallic surfaces, X- and γ-ray scattering from gases, liquids and solids, interference experiments, atomic spectra and the Bohr hypotheses, the experiment of Franck and Hertz, the Bragg experiment, diffraction of electrons by a crystal of nickel (Davisson and Germer), and measurements of position and velocity of an electron. The need for a quantum theory In the second half of the nineteenth century it seemed that the laws of classical mechanics, developed by the genius of Newton, Lagrange, Hamilton, Jacobi and Poincaré, the Maxwell theory of electromagnetic phenomena and the laws of classical statistical mechanics could account for all known physical phenomena. Still, it became gradually clear, after several decades of experimental and theoretical work, that one has to formulate a new kind of mechanics, which reduces to classical mechanics in a suitable limit, and makes it possible to obtain a consistent description of phenomena that cannot be understood within the classical framework. It is now appropriate to present a brief outline of this new class of phenomena, the systematic investigation of which is the object of the following sections and of chapters 4 and 14.
The first objective of this chapter is to briefly review some of the basic ideas about the structure of matter, in particular the concepts of microscopic physics, in order to recall the knowledge gained in previous physics (and chemistry) courses and make it more precise. Our review will be very concise, and most statements will be made without any proof or detailed discussion. A second objective is to give a brief description of some of the crucial stages in the early development of quantum physics. We shall not follow the strict historical order of this development or present the arguments used at the beginning of the last century by the founding fathers of quantum mechanics; rather, we shall stress the concepts which we shall find useful later on. Our last objective is to give an elementary introduction to some of the basic ideas, like those of a quantum particle or energy level, that will reappear throughout this text. We shall base our review on the Bohr theory, which provides a simple, though far from convincing, explanation of how energy levels are quantized and how the spectrum of the hydrogen atom arises. This chapter should be reread later on, once the basic ideas of quantum mechanics have been made explicit and illustrated by examples. From the practical point of view, it is possible to skip the general considerations of Sections 1.1 and 1.2 at the first reading and begin with Section 1.3, returning to those two sections later on as needed.
From a historical point of view, a distinction can be drawn between ‘old quantum theory’ and the full quantum theory that we now use. Old quantum theory was in essence a patchwork, cobbled together by incorporating some quantum ideas into essentially classical physics. The work of Planck, Einstein, Bohr, and Sommerfeld can be bracketed as old quantum theory. This classification is not meant to undermine the tremendous achievement that old quantum theory represents, but simply to underline its standing as a stage on the way to a fully formed quantum theory, which emerged from the work of Heisenberg, Schrodinger, Born, and Dirac. The development of the photon concept is a key example of a radically new idea gradually gaining acceptance. The process works via a growing realization that more and more things can be explained in the context of the photon model.
To date, quantum mechanics has proven to be our most successful theoretical model. However, it is still surrounded by a "mysterious halo" that can be summarized in a simple but challenging question: Why quantum phenomena are not understood under the same logic as classical ones? Although this is an open question (probably without an answer), from a pragmatist's point of view there is still room enough to further explore the quantum world, marveling ourselves with new physical insights. We just need to look back in the historical evolution of the quantum theory and thoroughly reconsider three key issues: (1) how this has developed since its early stages at a conceptual level, (2) what kind of experiments can be performed at present in a laboratory, and (3) what nonstandard conceptual models are available to extract some extra information. This contribution is aimed at providing some answers (and, perhaps, also raising some issues) to these questions through one of such models, namely Bohmian mechanics, a hydrodynamic formulation of the quantum theory, which is currently trying to open new pathways of understanding. Specifically, the Chapter constitutes a brief and personal overview on the historic and contextual evolution of this quantum formulation, its physical meaning and interest (leaving aside metaphysical issues), and how it may help to overcome some preconceived paradoxical aspects of the quantum theory.
This chapter examines the historical development of quantum mechanics, focusing on key experiments and theories that challenged classical physics. It begins with blackbody radiation, highlighting the discrepancy between classical predictions and experimental observations, leading to Planck's quantization hypothesis, which posits that energy is emitted in discrete packets (quanta). The chapter covers the photoelectric effect and Compton scattering, demonstrating wave–particle duality and validating quantum theory. It also discusses atomic models, culminating in the Bohr model and the energy-level diagram of the hydrogen atom, which explains atomic phenomena such as line spectra and discrete energy transitions. The chapter concludes by introducing the quantum model, which supersedes the Bohr model by incorporating wave–particle duality and the uncertainty principle, highlighting the necessity of quantum mechanics for accurate atomic-scale descriptions.