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Angular momentum, Hydrogen-oscillator connection and the relation between hydrogen atom basis

Mehdi Hage-Hassan

Published Apr 9, 2016• 0 citations
OpenAlex

Abstract

The angular momentum states may be realized by the wave functions of two dimensional harmonic oscillators in polar coordinates. Using the generating function of these wave functions, Schwinger's generating function of Clebsh-Gordan in Fock space and Gauss integral, we determine the generating function of the couplings function of two angular momentums in coordinates representations. We deduce from the last function the connection of the wave function of the hydrogen atom and the four dimensional harmonic oscillator. We also find the expression of the relation between the spherical and parabolic wave functions of hydrogen atom. In addition, we find a new bilinear generating function involving the products of Laguerre polynomials.

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The angular momentum states may be realized by the wave functions of two dimensional harmonic oscillators in polar coordinates. Using the generating function of these wave functions, Schwinger's generating function of Clebsh-Gordan in Fock space and Gauss integral, we determine the generating function of the couplings function of two angular momentums in coordinates representations. We deduce from the last function the connection of the wave function of the hydrogen atom and the four dimensional harmonic oscillator. We also find the expression of the relation between the spherical and parabolic wave functions of hydrogen atom. In addition, we find a new bilinear generating function involving the products of Laguerre polynomials.
In this paper we follow the Schwinger approach for angular momentum but with the polar basis of harmonic oscillator as a starting point. We derive by a new method two analytic expressions of the elements of passage matrix from the double polar basis to 4- dimensions polar basis of the harmonic oscillator. These expressions are functions of the modules of magnetic moments. The connection between our results and the results derived by the group theory of Laguerre polynomials is found. We determine a new expression for these elements in terms of magnetic moments in the general case. We deduce from these expressions the symmetries of 3j symbols. A new generating function of the Clebsh-Gordan coefficients, functions of the modules of magnetic moments are found. We prove that the generating function of recoupling coefficients 3nj for the polar basis are the same in the Schwinger's approach therefore the polar basis of harmonic oscillator may be a starting point to study the angular momentum.
Abstract In this chapter, we go to three dimensions in space and look at the solution of the time independent Schrödinger equation for the hydrogen atom. The Hamiltonian is then the kinetic energy plus the potential energy due to the Coulomb coupling between the positively charged nucleus and the electron. We construct the angular momentum operator and find that the partial differential equation for the angular momentum eigenfunctions of the spherical coordinates θ,ϕ is the same as the angular part of the ∇2 operator in spherical coordinates. The angular momentum eigenfunctions are the spherical harmonics, with two quantum numbers, l and m, and the solution to the radial part of the Hamiltonian including the Coulomb potential are Laguerre polynomials with one quantum number, called the principle quantum number, n. The hydrogen wave function is the product of a Laguerre polynomial and a spherical harmonic with three quantum numbers. Since these are two- and three-dimensional functions for angular momentum and hydrogen respectively, they are best understood in a series of plots. The chapter concludes by giving the historical letter names to specific orbitals, since they continue to be used today.
A coordinate transformation which exhibits the rotational invariance of the hydrogen atom in four-dimensional Hilbert space is introduced. The coordinates are shown to be directly related to the spherical polar and parabolic coordinates in position space. With the use of the transformation, the Schr\"odinger equation for the hydrogen atom left-multiplied by 4r4r4r is transformed into one for a four-dimensional harmonic oscillator. Solutions are obtained and related to the hydrogenic wave functions. Group-theoretical implications of the transformation and its application to the hydrogen Stark problem are briefly discussed.
The quantization of orbital angular momentum can be introduced simply through the model of the two- and three-dimensional simple harmonic oscillator. Most of the analysis is carried out in the familiar Cartesian coordinate system in which the simple harmonic oscillator Schrödinger equation is separable. Angular momentum eigenfunctions are constructed by superposition, and the resulting functions easily transformed into spherical coordinates. The angle-dependent parts of the solutions are the spherical harmonics, which are the orbital angular momentum eigenfunctions for all central potentials including the Coulomb potential of the hydrogen atom. The method also introduces the separation of variables technique and provides practice in applying the concepts of completeness, orthogonality, superposition of states, and alternative representations.
Schwinger's coupled-boson representation of spherical and hyperbolic angular momentum is related to spherical harmonics and is used for the calculation of matrix elements. It is shown that radial matrix elements of the two-dimensional isotropic oscillator and the closely related hydrogenic matrix elements are proportional to 3j-symbols. Matrix elements of exponentials of hyperbolic angular momentum operators which form a formal analogy to the well known rotation matrice d mm' j ( theta ) and which are written as t mm jj' ( theta ) are derived. As only elementary algebra and some operator formulae are used, the algebraic method supplements analytical and group theoretic methods.