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CRC Press eBooks

Operators, Eigenvalues and Eigenfunctions

S. Rajasekar, R. Velusamy

Published Sep 29, 2022• 0 citations
Publisher

Abstract

Operators in quantum mechanics which represent observables are of a special type: They are linear and Hermitian. Such operators not only form computation tools, but also form the most effective language in terms of which the theory can be formulated. This chapter presents important properties of linear operators and their eigenfunctions. It discusses the features of various operators which are necessary for studying quantum mechanical systems. The chapter shows how rich and beautiful the mathematical structure of quantum mechanics is. There exists a class of eigenvalue problems, the so-called parity-time reversal (PT) -symmetric non-Hermitian Hamiltonian problems. They have arisen in recent years in a number of physical contexts such as localization transitions, vortex pinning and population biology. Such non-Hermitian Hamiltonians can be used to describe certain experimental phenomena. PT-symmetry has been noticed in certain optical systems, such as optical couplers, microwave billiard and large-scale temporal lattices.

DOI
10.1201/9781003172178-3

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Operators in quantum mechanics which represent observables are of a special type: They are linear and Hermitian. Such operators not only form computation tools, but also form the most effective language in terms of which the theory can be formulated. This chapter presents important properties of linear operators and their eigenfunctions. It discusses the features of various operators which are necessary for studying quantum mechanical systems. The chapter shows how rich and beautiful the mathematical structure of quantum mechanics is. There exists a class of eigenvalue problems, the so-called parity-time reversal (PT) -symmetric non-Hermitian Hamiltonian problems. They have arisen in recent years in a number of physical contexts such as localization transitions, vortex pinning and population biology. Such non-Hermitian Hamiltonians can be used to describe certain experimental phenomena. PT-symmetry has been noticed in certain optical systems, such as optical couplers, microwave billiard and large-scale temporal lattices.
A basic quantity in quantum mechanics is the wave function ψ. Given a quantum mechanical system we write the Schrödinger equation for it. Its solution is the wave function. When introducing the wave function we stated that the maximum information about the state of a system can be obtained only from ψ. How do we extract observable properties of the system from the wave function? In quantum mechanics for every classical dynamical variable there exists an operator. For example, the operator of momentum p is −i~∇ while the operator of energy variable H = p2/(2m)+V (X) is −(~2/2m)∇2+V (X). Operation of an operator on ψ gives another function. If the new function is λψ, then λ is the eigenvalue of the operator. For example, the energy of a particle in a particular state represented by ψ can be obtained by operating H on ψ. That is, we have Hψ = Eψ where E is the energy eigenvalue. The expectation value of A(X,p) can be obtained from the formula 〈A〉 = ∫ ∞ −∞ ψ∗Aψ dτ , (3.1) where ψ is the solution of the equation Hψ = Eψ. Operators in quantum mechanics which represent observables are of a spe- cial type: They are linear and Hermitian. Such operators not only form computation tools, but also form the most effective language in terms of which the theory can be formulated. The fascinating point is that using linear operators we can understand the quantum mechanics. Therefore, it is important to study the basic theory of linear operators. In this chapter, we present important properties of linear operators and their eigenfunctions. We discuss the features of various operators which are necessary for studying quantum and ematical structure of quantum mechanics is.
With the postulates already formulated in the language of an abstract inner product spaces, this chapter shows how an observable can be naturally expressed as a linear Hermitian operator acting on the inner product space where the states live. We start by introducing linear operators acting on vector spaces and their representations. Next, we discuss the systems of eigenvalues and eigenvectors associated with such operators. The important case of Hermitian operator and the properties of their eigenvalues and eigenvectors, relevant to quantum mechanics, are introduced. After developing the necessary background in linear algebra, the connection of Hermitian operators with quantum observables is established. We then proceed to explain what this connection actually accomplishes. In particular, we show how it translates the target questions of quantum mechanics into an eigenvalue problem. This makes it evident what the nature of the input to a quantum theory should be. This input enters the formalism through what are known as “quantization rules”. I discuss this in the last section of this chapter. An illustration using a disguised spin-half system winds up the chapter.
Abstract Mathematical formalism of quantum mechanics is closely connected with the theory of linear operators. A key quantum-mechanical principle is that physical quantities (observables) are represented by Hermitian linear operators that act on state vectors that belong to a Hilbert vector space. This chapter analyzes problems that deal with the basic concepts of the theory of linear operators; eigenfunctions, eigenvalues, mean values; the projection operators; quantum-mechanical representations of operators and wave-functions; and unitary operators.
This chapter provides a simple general introduction to some basic mathematics necessary for a subsequent discussion of Lie algebras, operator methods, and their applications to theoretical physics and chemistry. It also provides some useful mathematical tools to derive important theoretical results and expressions in a simple and elegant way. In quantum mechanics the state of a system is represented by an element of a particular vector space, in which one defines an appropriate scalar or inner product, known in mathematics as Hilbert space. Hermitian operators with a complete set of eigenvectors belonging to that state space represent physical observables. Moreover, in certain cases it proves useful to work with vector spaces formed by linear operators. Hermitian operators are particular cases of linear operators and physical observables are particular cases of Hermitian operators. In many physical applications of operator methods one needs to reorder products of exponential operators or to rewrite one such operator as a product of simpler ones.
In most introductory courses on quantum mechanics one is taught that the Hamiltonian operator must be Hermitian in order that the energy levels be real and that the theory be unitary (probability conserving). To express the Hermiticity of a Hamiltonian, one writes H = H †, where the symbol † denotes the usual Dirac Hermitian conjugation; that is, transpose and complex conjugate. In the past few years it has been recognized that the requirement of Hermiticity, which is often stated as an axiom of quantum mechanics, may be replaced by the less mathematical and more physical requirement of space – time reflection symmetry (𝒫𝒯 symmetry) without losing any of the essential physical features of quantum mechanics. Theories defined by non-Hermitian 𝒫𝒯-symmetric Hamiltonians exhibit strange and unexpected properties at the classical as well as at the quantum level. This paper explains how the requirement of Hermiticity can be evaded and discusses the properties of some non-Hermitian 𝒫𝒯-symmetric quantum theories.
The traditional framework of quantum mechanics and many classical wave phenomena is underpinned by Hermitian operators, which guarantee real eigenvalues corresponding to observable quantities and orthogonal eigenvectors. However, a growing number of physical systems exhibit non-reciprocal interactions, leading to Hamiltonians or system matrices that are inherently non-Hermitian. This paper delves into the spectral theory of such non-reciprocal systems, exploring the unique mathematical and physical characteristics that emerge when the constraint of Hermiticity is relaxed. We discuss phenomena like complex energy eigenvalues, exceptional points where both eigenvalues and eigenvectors coalesce, and the breakdown of standard perturbation theory. The implications of non-Hermitian spectral properties extend to diverse fields, including parity-time (PT) symmetric photonics, active matter, open quantum systems, and even classical wave propagation in active or lossy media. By extending spectral analysis beyond the Hermitian paradigm, we aim to provide a comprehensive overview of the current understanding, challenges, and future directions in characterizing the dynamics and phases of non-reciprocal systems. This exploration is crucial for advancing both fundamental theoretical understanding and practical applications in emerging technologies that leverage tailored non-reciprocity.