The idea of a single particle cannot be retained in relativistic quantum mechanics if there are interactions which lead to creation and annihilation of pair of particles. Therefore, the number of particles is not conserved in the relativistic theory. Most of the applications of quantum mechanics are in the realm of the three phases of matters: gases, liquids and solids. In these cases a nonrelativistic quantum theory is sufficient. However, in principle, a strictly correct treatment should include relativity. In 1928 Paul Adrian Maurice Dirac introduced a wave equation for a relativistic electron. The KG equation without mass corresponds to elastic stretching of an isolated vortex filament in the ideal fluid. The wave function has the meaning of the curve's position vector. The mass part of the KG equation describes the rotation of the helical curve about the screw axis due to the hydrodynamic self-inductor of the bent vortex filament.
The idea of a single particle cannot be retained in relativistic quantum mechanics if there are interactions which lead to creation and annihilation of pair of particles. Therefore, the number of particles is not conserved in the relativistic theory. Most of the applications of quantum mechanics are in the realm of the three phases of matters: gases, liquids and solids. In these cases a nonrelativistic quantum theory is sufficient. However, in principle, a strictly correct treatment should include relativity. In 1928 Paul Adrian Maurice Dirac introduced a wave equation for a relativistic electron. The KG equation without mass corresponds to elastic stretching of an isolated vortex filament in the ideal fluid. The wave function has the meaning of the curve's position vector. The mass part of the KG equation describes the rotation of the helical curve about the screw axis due to the hydrodynamic self-inductor of the bent vortex filament.
Most of the applications of quantum mechanics are in the realm of the three phases of matters: gases, liquids and solids. In these cases a nonrelativistic quantum theory is sufficient. However, in principle, a strictly correct treatment should include relativity. For relativistic particles, that is, for particles travelling at speeds close to the speed of light, the nonrelativistic Schrödinger equation is not applicable. Oskar Klein and Walter Gordon1 proposed a relativistic wave equation for a free particle. Their equation fell into dispute because the probability density function is not positive definite, thereby preventing the probability interpretation.
In special relativity, time and space are transformed according to the Lorentz transformation. Relativistic quantum mechanics is quantum mechanics that is consistent with special relativity. Nevertheless, relativistic quantum mechanics is only an approximation to a fully self-consistent relativistic theory of known particle interactions because it does not describe cases where the number of particles changes. In special relativity, mass can emerge from energy, which is not possible in quantum mechanics based on the conservation of probability. Dirac proposed the equation named after him to solve the difficulty encountered in the Klein-Gordon equation stemmed from the fact that it is a second-order differential equation in time.
We underscore the need of relativistic quantum mechanics in dealing with particles. Various notations used in relativity are defined and explained. We derive the Klein–Gordon equation for free particle as well as for particle in electromagnetic field. We obtain a solution and interpret it. We derive the Dirac equation for free particle as well as for particle in electromagnetic field. Plane wave solution to the Dirac equation is obtained. We show how spin of electron, idea of antiparticle , phenomena of pair production and pair annihilation follow from the Dirac equation.
The purpose of this chapter is to introduce the Dirac equation, which will provide us with a basis for developing the relativistic quantum mechanics of electronic systems. Thus far we have reviewed some basic features of the classical relativistic theory, which is the foundation of relativistic quantum theory. As in the nonrelativistic case, quantum mechanical equations may be obtained from the classical relativistic particle equations by use of the correspondence principle, where we replace classical variables by operators. Of particular interest are the substitutions In terms of the momentum four-vector introduced earlier, this yields In going from a classical relativistic description to relativistic quantum mechanics, we require that the equations obtained are invariant under Lorentz transformations. Other basic requirements, such as gauge invariance, must also apply to the equations of relativistic quantum mechanics. We start this chapter by reexamining the quantization of the nonrelativistic Hamiltonian and draw out some features that will be useful in the quantization of the relativistic Hamiltonian. We then turn to the Dirac equation and sketch its derivation. We discuss some properties of the equation and its solutions, and show how going to the nonrelativistic limit reduces it to a Schrödinger-type equation containing spin.
The aim of relativistic quantum mechanics is to describe the finer details of the structure of atoms and molecules, where relativistic effects become nonnegligible. It is a sort of intermediate realm, between the familiar nonrelativistic quantum mechanics and fully relativistic quantum field theory, and thus it lacks the simplicity and elegance of both. Yet it is a necessary tool, mostly for quantum chemists. Pilkuhn's book offers to this audience an up-to-date survey of these methods, which is quite welcome since most previous textbooks are at least ten years old. The point of view of the author is to start immediately in the relativistic domain, following the lead of Maxwell's equations rather than classical mechanics, and thus to treat the nonrelativistic version as an approximation. Thus Chapter 1 takes off from Maxwell's equations (in the noncovariant Coulomb gauge) and gradually derives the basic aspects of Quantum Mechanics in a rather pedestrian way (states and observables, Hilbert space, operators, quantum measurement, scattering,. Chapter 2 starts with the Lorentz transformations, then continues with the Pauli spin equation and the Dirac equation and some of their applications (notably the hydrogen atom). Chapter 3 is entitled `Quantum fields and particles', but falls short of treating quantum field theory properly: only creation/annihilation operators are considered, for a particle in a box. The emphasis is on two-electron states (the Pauli principle, the Foldy--Wouthuysen elimination of small components of Dirac spinors, Breit projection operators. Chapter 4 is devoted to scattering theory and the description of relativistic bound states. Chapter 5, finally, covers hyperfine interactions and radiative corrections. As we said above, relativistic quantum mechanics is by nature limited in scope and rather inelegant and Pilkuhn's book is no exception. The notation is often heavy (mostly noncovariant) and the mathematical level rather low. The central topic is the description of atoms and molecules, including relativistic effects. The author fulfils this program in a reasonable way and offers a valuable tool to the targeted audience. I am not overly enthusiastic about the end result, but I might be prejudiced. Clearly, going further would require the full power of quantum field theory, but this is clearly beyond the scope of the book.
The search for a theory of the elementary particles which is founded on the well-established principles of quantum mechanics and conforms at the same time with the requirements of the principle of relativity has, in recent years, taken several divergent directions. On the one hand, the second quantization of wave fields derived from a Lagrangian by a variational procedure(1) has succeeded in accounting for the existence and most of the properties of the electron, the photon, and the meson. On the other hand, many generalizations of the Dirac wave equation of the electron(2) have been attempted, with applications to the meson(3) and the proton(4). Heisenberg(5) has considered the much more difficult problem of the interaction between different particles, and has found that the key to the situation is the so-called ‘scattering matrix’, which is nothing other than a limiting form of the relativistic density matrix, as defined in § 2 of this paper. It seems probable that the relativistic density matrix ρ; or statistical operator, as it may be called without reference to representation, will play an important part in relativistic quantum mechanics in the future. It satisfies the same equation as the wave function, but differs from it in being a real linear operator, or a dynamical variable, in the terminology of Dirac.