We introduce the NCA and NCA-Markov dynamical maps for open quantum systems, which go beyond weak-coupling master equations replacing the Born approximation with a non-crossing approximation (NCA). We apply these NCA maps on a prototype model of open quantum systems, the Ohmic spin-boson model at zero temperature, showing that they can qualitatively reproduce its non-perturbative behaviour, including its crossover from a coherent to an incoherent dynamics and its localization quantum phase transition, which are entirely missed by perturbative master equations. Remarkably, the time-local NCA-Markov map qualitatively captures this physics entirely, opening up the possibility to address strong-coupling effects at a numerical cost comparable to standard Markovian master equations.
We introduce the NCA and NCA-Markov dynamical maps for open quantum systems, which go beyond weak-coupling master equations replacing the Born approximation with a non-crossing approximation (NCA). We apply these NCA maps on a prototype model of open quantum systems, the Ohmic spin-boson model at zero temperature, showing that they can qualitatively reproduce its non-perturbative behaviour, including its crossover from a coherent to an incoherent dynamics and its localization quantum phase transition, which are entirely missed by perturbative master equations. Remarkably, the time-local NCA-Markov map qualitatively captures this physics entirely, opening up the possibility to address strong-coupling effects at a numerical cost comparable to standard Markovian master equations.
In several cases, open quantum systems can be successfully described using master equations relying on Born-Markov approximations, but going beyond these approaches has become often necessary. In this work, we introduce the NCA and NCA-Markov dynamical maps for open quantum systems, which go beyond these master equations replacing the Born approximation with a self-consistent approximation, known as non-crossing approximation (NCA). These maps are formally similar to master equations, but allow to capture non-perturbative effects of the environment at a moderate extra numerical cost. To demonstrate their capabilities, we apply them to the spin-boson model at zero temperature for both a Ohmic and a sub-Ohmic environment, showing that they can both qualitatively capture its strong-coupling behaviour, and be quantitatively correct beyond standard master equations.
We present an exact expansion of the master equation for an open quantum system. The resulting equation is time local and enables us to calculate clearly defined higher-order corrections to the Born-Markov approximation. In particular, we show that non-Markovian terms are of the same order of magnitude as higher-order terms in the system-bath coupling. As a result, we emphasize that analyzing non-Markovian behavior of a system implies going beyond the Born approximation. Additionally, we address with this approach the initial-state problem occurring in non-Markovian master equations.
Recent advances in quantum technologies and related experiments have created a need for highly accurate, versatile, and computationally efficient simulation techniques for the dynamics of open quantum systems. Long-lived correlation effects (non-Markovianity), system-environment hybridization, and the necessity for accuracy beyond the Born-Markov approximation form particular challenges. Approaches to meet these challenges have been introduced, originating from different fields, such as hierarchical equations of motion, Lindblad-pseudomode formulas, chain-mapping approaches, quantum Brownian motion master equations, stochastic unravelings, and refined quantum master equations. This diversity, while indicative of the field's relevance, has inadvertently led to a fragmentation that hinders cohesive advances and their effective cross-community application to current problems for complex systems. How are different approaches related to each other? What are their strengths and limitations? Here we give a systematic overview and concise discussion addressing these questions. We make use of a unified framework which very conveniently allows to link different schemes and, this way, may also catalyze further progress. In line with the state of the art, this framework is formulated not in a fully reduced space of the system but in an extended state space which in a minimal fashion includes effective reservoir modes. This in turn offers a comprehensive understanding of existing methods, elucidating their physical interpretations, interconnections, and applicability.
Quantum systems are inherently open to their environment and thus they evolve under the influence of dissipation, decoherence and driving from external fields. This poses a significant theoretical challenge: how to track the dynamics of the system of interest while tracing out environmental degrees of freedom. Markovian master equations offer a longstanding solution to this problem, where under a series of assumptions the reduced density matrix of the system can be obtained. These flexible approaches provide a conceptually and numerically simple framework for describing complex many-body systems. However, the assumptions enforced by Markovian master equations create a gap in the availability of generic, simple, and analytical techniques capable of treating open quantum systems beyond the regimes of standard Markovian master equations. In this thesis, we introduce three studies addressing three regimes that are inaccessible to standard Markovian master equations and investigate their consequences in quantum thermodynamics-inspired applications. We begin by developing a Markovian embedding technique to tackle non-Markovian dynamics induced by the long correlation times of a qubit coupled to a structured environment. Subsequently, we propose an "effective" Hamiltonian theory enabling the study of equilibrium properties of strong coupling to a thermal reservoir through a dressed version of the Gibbs state. This framework can also be applied to address problems of equilibration, transport, quantum thermal machines, and quantum dynamics. Lastly, we showcase the importance of including non-secular terms in the quantum master equation, which results in a drastic separation of timescales leading to rich metastable dynamics. We apply this quantum master equation approach to temperature sensing in a nonequilibrium setting offering an alternative to standard equilibrium probes. Overall, this thesis contributes novel theoretical techniques for tackling open quantum systems beyond standard approximations with applications in quantum thermodynamics.
Positivity preservation is naturally guaranteed in exact non-Markovian master equations for open quantum system dynamics. However, in many approximated non-Markovian master equations, the positivity of the reduced density matrix is not guaranteed. In this paper we provide a general class of time-local, perturbative, and positivity-preserving non-Markovian master equations generated from stochastic Schr\"odinger equations, particularly quantum-state-diffusion equations. Our method has an expanded range of applicability for accommodating a variety of non-Markovian environments. We show the positivity-preserving master equation for a three-level system coupled to a dissipative bosonic environment as a particular example to exemplify our general approach. We illustrate the numerical simulations with an analysis explaining why the previous approximated non-Markovian master equations cannot guarantee positivity. Our work provides a consistent master equation for studying the non-Markovian dynamics in ultrafast quantum processes and strong-coupling systems.
We study the dynamics of open quantum systems driven by an external time-periodic force. Combining Floquet theory and the time-convolutionless projection operator technique we derive a time-local quantum master equation which exactly takes into account the periodic driving, while treating the system-environment interaction within second order in the coupling strength without performing the Markov approximation. The resulting equation of motion for the reduced density matrix is called Floquet time-convolutionless master equation. Employing the example of the driven spin-boson system, we demonstrate that this master equation is capable of describing strong non-Markovian effects, while yielding the Floquet-Lindblad master equation in the Markovian limit. A characteristic feature of memory effects in such driven dissipative systems is the emergence of sharp peaks of the trace-distance based non-Markovianity measure as a function of the driving amplitude, which can be traced back to quasienergy crossings leading to almost decoherence-protected subspaces through a quasienergy-induced dissipative decoupling mechanism.