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The Journal of Physical Chemistry A

Controlling Tunneling Oscillation and Quantum Localization in an Asymmetric Double-Well Potential: A Bohmian Perspective

Bhrigu Chakraborty, Ruchi Jha, Susmita Kar, Pratim Kumar Chattaraj

Published Jul 14, 2022• 1 citation
Publisher

Abstract

The roles of spatial symmetry and strength of external time-dependent perturbation on the dynamics of a quantum particle, initially localized in one of the wells of an asymmetric double-well potential are studied using the recently developed techniques incorporating quantum theory of motion and time-dependent Fourier grid Hamiltonian methods. The model used here includes a mimic of the related experimental situations which is considered as a perturbation to the static double-well potential. Analysis of localized and delocalized phase space structures and corresponding time-profile of tunneling probability reveal the recipe toward controlling the tunneling oscillations by modulating the parameters of applied perturbation. A study on a stochastic pulsating potential also reveals the root to the quantum localization, even in moderate field strength.

DOI
10.1021/acs.jpca.2c03049

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The roles of spatial symmetry and strength of external time-dependent perturbation on the dynamics of a quantum particle, initially localized in one of the wells of an asymmetric double-well potential are studied using the recently developed techniques incorporating quantum theory of motion and time-dependent Fourier grid Hamiltonian methods. The model used here includes a mimic of the related experimental situations which is considered as a perturbation to the static double-well potential. Analysis of localized and delocalized phase space structures and corresponding time-profile of tunneling probability reveal the recipe toward controlling the tunneling oscillations by modulating the parameters of applied perturbation. A study on a stochastic pulsating potential also reveals the root to the quantum localization, even in moderate field strength.
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For an asymmetric double-well potential system, it is shown that, if the potential is quadratic until it reaches several times of the zero-point energies from the bottoms in each well, the energy eigenvalues of the low lying excited states of the double-well system must be close to the eigenvalues of the quadratic potentials. These eigenvalue structures suggest a method for the coherent control of the tunneling as well as realizing almost complete localization of the wave packet in one of the wells, by handling the double-well asymmetry. Numerical examples are included to indicate that the method could be useful also in a more general potential, and to propose experimental confirmations.
Quantum tunneling of particles plays an important role in many chemical reactions. Studying quantum tunneling in time-dependent potential wells is tricky since most of the available solutions of time-dependent potential wells are coupled to specific properties of the Hamiltonian. Here, we investigate the tunneling probability of a quantum wavepacket in time-dependent potential well by using the split operator method. This numerical method can give us an overview of the tunneling probability of a quantum wavepacket for any temporal change in the shape of the potential well. We study a time-dependent potential well model evolving from symmetric to asymmetric quartic double well since quartic potential wells resemble certain practically available potential well models. Quanta 2024; 13: 11–19.
Abstract The effects of discontinuously time‐varying perturbations on the dynamics of a particle moving in harmonic, symmetric double well and symmetric triple well potentials, are investigated both classically and quantum mechanically. The quantum dynamics is followed using the time‐dependent Fourier grid Hamiltonian (TDFGH) method while the classical dynamics is analyzed within the framework of classical Hamiltonian mechanics. Depending on the spatial symmetry of the perturbation and the characteristic features of the reversal time , different types of ‘phase space’ structures are observed in each of the potentials. For symmetric double and triple well potentials, quantum dynamics reveals that complete destruction of tunnelling (CDT) can be achieved in the presence of a time‐dependent spatially asymmetric perturbing field that is continuous in time. Any discontinuity in time‐variation of the perturbation may induce over the barrier transition. The relevance of these results in the context of (i) tunnelling control and (ii) quantum computing with 3‐state or 2‐state quantum registers is briefly discussed.
For a model one-dimensional asymmetric double-well potential we calculated the so-called survival probability (i.e., the probability for a particle initially localized in one well to remain there). We use a semiclassical (WKB) solution of the Schrödinger equation. It is shown that behavior essentially depends on transition probability, and on a dimensionless parameter Lambda that is a ratio of characteristic frequencies for low-energy nonlinear in-well oscillations and interwell tunneling. For the potential describing a finite motion (double-well) one has always a regular behavior. For Lambda<<1, there are well defined resonance pairs of levels and the survival probability has coherent oscillations related to resonance splitting. However, for Lambda>>1 there are no oscillations at all for the survival probability, and there is almost an exponential decay with the characteristic time determined by Fermi golden rule. In this case, one may not restrict himself to only resonance pair levels. The number of levels perturbed by tunneling grows proportionally to square root of [Lambda] (in other words, instead of isolated pairs there appear the resonance regions containing the sets of strongly coupled levels). In the region of intermediate values of Lambda one has a crossover between both limiting cases, namely, the exponential decay with subsequent long period recurrent behavior.