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Coherent manipulation of molecular qudits by broadband NMR

Simone Chicco, Elena Garlatti, G. Allodi, Alessandro Chiesa, Matteo Atzori, Lorenzo Sorace, R. De Renzi, Roberta Sessoli, Stefano Carretta

Published Jan 1, 2022• 0 citations
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Abstract

We review recent results showing the capability of broadband Nuclear Magnetic Resonance (NMR) to coherently manipulate the state of multi-level molecular qudits with radiofrequency pulses. Several qubit-qudit systems have been studied, paving the way for the realization of quantum-error correction protocols. Here we focus on the recent prototypical [VO(TPP)] complex, a very promising\nsystem with long coherence times and strong hyperfine interaction.

DOI
10.1393/ncc/i2022-22163-y

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We review recent results showing the capability of broadband Nuclear Magnetic Resonance (NMR) to coherently manipulate the state of multi-level molecular qudits with radiofrequency pulses. Several qubit-qudit systems have been studied, paving the way for the realization of quantum-error correction protocols. Here we focus on the recent prototypical [VO(TPP)] complex, a very promising\nsystem with long coherence times and strong hyperfine interaction.
We show that [VO(TPP)] (vanadyl tetraphenylporphyrinate) is a promising system to implement quantum computation algorithms based on encoding information in multi-level (qudit) units. Indeed, it embeds a nuclear spin 7/2 coupled to an electronic spin 1/2 by hyperfine interaction. This qubit-qudit unit can be exploited to implement quantum error correction and quantum simulation algorithms. Through a combined theoretical and broadband nuclear magnetic resonance study, we demonstrate that the elementary operations of such algorithms can be efficiently implemented on the nuclear spin qudit. Manipulation of the nuclear qudit can be achieved by resonant radio-frequency pulses, thanks to the remarkably long coherence times and the effective quadrupolar coupling induced by the strong hyperfine interaction. This approach may open new perspectives for developing new molecular qubit-qudit systems.
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Rapid developments in quantum information processing have been made, and remarkable achievements have been obtained in recent years, both in theory and experiments. Coherent control of nuclear spin dynamics is a powerful tool for the experimental implementation of quantum schemes in liquid and solid nuclear magnetic resonance (NMR) system, especially in liquid-state NMR. Compared with other quantum information processing systems, the NMR platform has the advantages such as the long coherence time, the precise manipulation, and well-developed quantum control techniques, which make it possible to accurately control a quantum system with up to 12-qubits. Extensive applications of liquid-state NMR spectroscopy in quantum information processing such as quantum communication, quantum computing, and quantum simulation have been thoroughly studied over half a century. This article introduces the general principles of NMR quantum information processing, and reviews the new-developed techniques. The review will also include the recent achievements of the experimental realization of quantum algorithms for machine learning, quantum simulations for high energy physics, and topological order in NMR. We also discuss the limitation and prospect of liquid-state NMR spectroscopy and the solid-state NMR systems as quantum computing in the article.
A three-qubit 13C^{13}\mathrm{C}13C solid-state nuclear magnetic resonance (NMR) system for quantum-information processing, based on the malonic acid molecule, is used to demonstrate high-fidelity universal quantum control via strongly modulating radio-frequency pulses. This control is achieved in the strong-coupling regime, in which the time scales of selective qubit addressing and of two-qubit interactions are comparable. State evolutions under the internal Hamiltonian in this regime are significantly more complex, in general, than those of typical liquid-state NMR systems. Moreover, the transformations generated by the strongly modulating pulses are shown to be robust against the types of ensemble inhomogeneity that dominate in the employed molecular crystal system. The secondary focus of the paper is upon detailed characterization of the malonic acid system. The internal Hamiltonian of the qubits is determined through spectral simulation. A pseudopure state preparation protocol is extended to make a precise measurement of the dephasing rate of a three-quantum coherence state under residual dipolar interactions. The spectrum of intermolecular 13C−−13C^{13}\mathrm{C}--^{13}\mathrm{C}13C−−13C dipolar fields in the crystal is simulated, and the results compared with single-quantum dephasing data obtained using appropriate refocusing sequences. We conclude that solid-state NMR systems tailored for quantum-information processing have excellent potential for extending the investigations begun in the liquid-state systems to a greater number of qubits.
Thanks to the quantum simulation, more and more problems in quantum mechanics which were previously inaccessible are now open to us. Capitalizing on the state-of-the-art techniques on quantum coherent control developed in past few decades, e.g., the high-precision quantum gate manipulating, the time-reversal harnessing, the high-fidelity state preparation and tomography, the nuclear magnetic resonance (NMR) system offers a unique platform for quantum simulation of many-body physics and high-energy physics. Here, we review the recent experimental progress and discuss the prospects for quantum simulation realized on NMR systems.