Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Nanophotonics

Unveiling atom‐photon quasi‐bound states in hybrid plasmonic‐photonic cavity

Yuwei Lu, Wenjie Zhou, Yongyao Li, Runhua Li, Jingfeng Liu, Lin Wu, Haishu Tan

Published Jun 8, 2022• 22 citations
Publisher

Abstract

Dissipation, often associated with plasmons, leads to decoherence and is generally considered fatal for quantum nonlinearities and entanglement. Counterintuitively, by introducing a dissipative plasmonic nanoantenna into a typical cavity quantum electrodynamics (QED) system, we unveil the wide existence of the atom-photon quasi-bound state (qBS), a kind of exotic eigenstate with anomalously small decay, in the hybrid plasmonic-photonic cavity. To derive the analytical condition of atom-photon qBS, we formulate a quantized two-mode model of the local density of states by connecting the interacting uncoupled cavity modes to the macroscopic QED. With resonant plasmon-photon coupling, we showcase the single-atom qBS that improves the efficiency of single-photon generation over one order of magnitude; and the two-atom qBS that significantly enhances spontaneous entanglement generation compared with a bare photonic cavity. Notably, such single-atom and multi-atom qBS can be simultaneously accessed in realistic plasmonic-photonic cavities, providing a versatile platform for advanced quantum technologies, such as quantum light sources, quantum computation, and quantum information.

DOI
10.1515/nanoph-2022-0162

Related papers

Light-Matter Interaction in Hybrid Quantum Plasmonic Systems

Jakob Straubel

Attempting to implement quantum information related applications utilizing atoms and photons, as they naturally form quantum systems supporting superposition states, hybrid quantum plasmonic systems emerged in the past as a platform to study and engineer light-matter interaction. This platform combines the unrivaled electromagnetic field localization of surface plasmon polaritons, boosting the light-matter coupling rate, with the tremendous integration potential of truly nanoscale structures, and both the significant emission rates of nanoantennas and photonic transmission velocities. In this work, a classical description of surface plasmon polaritons is combined with a light-matter interaction model based on a cavity quantum electrodynamical formalism. The resulting composite semi-classical method, introduced and described in this thesis, provides efficient and versatile means to simulate the dynamical behavior of radiative atomic transitions coupled to plasmonic cavity modes in the weak incoherent coupling regime. Both the emission into the far field and various dissipation mechanisms are included by expanding the model to an open quantum system. The variety of light-matter interaction applications that can be modeled with the outlined method is indicated by the four different exemplary scenarios detailed in the application chapter of this thesis. The classical description of localized surface plasmon polaritons is benchmarked by reproducing the experimental measurements of the molecular fluorescence manipulation through optical nanoantennas in a collaborative effort with experimental partners. Furthermore, in the weak light-matter coupling regime, the potential of achieving a higher nanoantenna functionality and simultaneously realizing more elaborate quantum dynamics is revealed by the three remaining applications. Each pivotally involving a bimodal nanoantenna and demonstrating different quantum optical phenomena, the implementation of cavity radiation mode conversion, non-classical cavity emission statistics, and non-classical cavity emission properties is shown and described in the application chapter.

•Jan 1, 2018•0 citations

Dissipation in the broadband and ultrastrong coupling regimes of cavity quantum electrodynamics: an ab initio quantized quasinormal mode approach

Chris Gustin, Juanjuan Ren, Sebastian Franke +1 more

Phenomenological approaches to photon loss have long been the workhorse of cavity-QED, but prove inadequate in the presence of sufficiently broadband light-matter interactions. We present a rigorous and ab initio derivation of a quantum master equation for a quantized optical cavity mode coupled to a dipole, using a quasinormal mode (QNM) quantization procedure for plasmonic and dielectric open-system cavity-QED, which is valid in broadband light-matter interaction regimes, including ultrastrong coupling (USC). The theory supports general three-dimensional resonators with arbitrary dispersion and loss, and thus can be applied to a wide range of realistic open cavities. Our ab initio and gauge-invariant approach fully recovers a recent result for the spectral density of a quantized cavity with a single dipole and reveals important departures from previous heuristic assumptions about system-reservoir coupling. We identify a new criterion for what we term the "broadband dissipative" regime of cavity-QED, where phenomenological models require corrections in accordance with the intrinsic and spatially-dependent complex phase of the QNM, and also shed light on fundamental limits to single-mode models in extreme coupling regimes. Using experimentally motivated plasmonic and dielectric cavity examples, we show validity ranges of our QNM master equation and spectral USC calculations, and discuss prospects for near-term experimental observation of the broadband dissipative effects.

arXiv:2507.21408•Light Science & Applications•Aug 26, 2026•1 citation

Quantized pseudomodes for plasmonic cavity QED

Stephen Hughes, Marten Richter, Andreas Knorr

We present a quantized pseudomode theory for solving system-level cavity quantum electrodynamics with quantum emitters coupled to plasmonic resonators. Exploiting the Green function response of a silver nanoparticle and an exact solution for the input-output coupling, we study the non-Markovian coupling regimes of multi-mode vacuum Rabi oscillations and coherently pumped multi-photon resonances from the higher lying ladder states of collective plasmon modes. The nonlinear pumping regime also facilitates pronounced population inversion of a single two-level atom through multiphoton resonances dominated by dark plasmons.

Optics Letters•Apr 9, 2018•31 citations

Nanoplasmonic cavity quantum electrodynamic architectures for room-temperature quantum technologies

Ortwin G. Hess

Abstract Quantum nanophotonics places nanoscale structuring in direct dialogue with photonic quantum information—compressing functionality to the few-nanometre, few-femtosecond frontier while retaining energy efficiency, speed and room-temperature operation. We highlight nanoplasmonic cavity-QED architectures in which extreme mode confinement delivers strong coupling under ambient conditions, enabling ultrafast single-photon emission and near-field multipartite entanglement using industry-grade near-field transducers that nanofocus guided light at practical efficiencies. We set these advances against the arc from early plasmonic cQED proposals and single-emitter Purcell studies to modern time-domain measurements that resolve sub-picosecond polariton/Rabi dynamics—establishing a clear route from concept to device. In parallel, we point to low-loss, high-index Mie resonators whose spectrally sharp electric and magnetic modes afford narrow-band coherent control, filtering and radiation-pattern engineering, and which naturally co-integrate in hybrid metal–dielectric stacks that combine ultrastrong local coupling with low-loss routing and storage. Finally, we discuss quantum nanoplasmonic coherent perfect absorption (qnCPA)—a waveguide-fed, non-perturbing protocol that selectively prepares and protects plasmon–emitter dressed states via dissipation-assisted, unidirectional feeding. Together with macroscopic QED and quantum quasinormal-mode quantization, which regularize open, lossy resonators and clarify when loss can be a resource, these developments chart robust, chip-scale routes to room-temperature quantum technologies.

The European Physical Journal Special Topics•Dec 2, 2025•2 citations

Two-Photon Spontaneous Emission in Atomically Thin Plasmonic Nanostructures

Yunuhen Muñiz, Alejandro Manjavacas, Carlos Farina +2 more

The ability to harness light-matter interactions at the few-photon level plays a pivotal role in quantum technologies. Single photons-the most elementary states of light-can be generated on demand in atomic and solid state emitters. Two-photon states are also key quantum assets, but achieving them in individual emitters is challenging because their generation rate is much slower than competing one-photon processes. We demonstrate that atomically thin plasmonic nanostructures can harness two-photon spontaneous emission, resulting in giant far field two-photon production, a wealth of resonant modes enabling tailored photonic and plasmonic entangled states, and plasmon-assisted single-photon creation orders of magnitude more efficient than standard one-photon emission. We unravel the two-photon spontaneous emission channels and show that their spectral line shapes emerge from an intricate interplay between Fano and Lorentzian resonances. Enhanced two-photon spontaneous emission in two-dimensional nanostructures paves the way to an alternative efficient source of light-matter entanglement for on-chip quantum information processing and free-space quantum communications.

arXiv:2006.15219•Physical Review Letters•Jul 15, 2020•34 citations

Generation of quantum entangled states in nonlinear plasmonic structures and metamaterials (Presentation Recording)

Alexander N. Poddubny, Andrey A. Sukhorukov

The practical development of quantum plasmonic circuits incorporating non-classical interference [1] and sources of entangled states calls for a versatile quantum theoretical framework which can fully describe the generation and detection of entangled photons and plasmons. However, majority of the presently used theoretical approaches are typically limited to the toy models assuming loss-less and nondispersive elements or including just a few resonant modes. Here, we present a rigorous Green function approach describing entangled photon-plasmon state generation through spontaneous wave mixing in realistic metal-dielectric nanostructures. Our approach is based on the local Huttner-Barnett quantization scheme [2], which enables problem formulation in terms of a Hermitian Hamiltonian where the losses and dispersion are fully encoded in the electromagnetic Green functions. Hence, the problem can be addressed by the standard quantum mechanical perturbation theory, overcoming mathematical difficulties associated with other quantization schemes. We derive explicit expressions with clear physical meaning for the spatially dependent two-photon detection probability, single-photon detection probability and single-photon density matrix. In the limiting case of low-loss nondispersive waveguides our approach reproduces the previous results [3,4]. Importantly, our technique is far more general and can quantitatively describe generation and detection of spatially-entangled photons in arbitrary metal-dielectric structures taking into account actual losses and dispersion. This is essential to perform the design and optimization of plasmonic structures for generation and control of quantum entangled states. [1] J.S. Fakonas, H. Lee, Y.A. Kelaita and H.A. Atwater, Nature Photonics 8, 317(2014) [2] W. Vogel and D.-G. Welsch, Quantum Optics, Wiley (2006). [3] D.A. Antonosyan, A.S. Solntsev and A.A. Sukhorukov, Phys. Rev. A 90 043845 (2014) [4] L.-G. Helt, J.E. Sipe and M.J. Steel, arXiv: 1407.4219

Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE•Sep 2, 2015•0 citations
Dissipation, often associated with plasmons, leads to decoherence and is generally considered fatal for quantum nonlinearities and entanglement. Counterintuitively, by introducing a dissipative plasmonic nanoantenna into a typical cavity quantum electrodynamics (QED) system, we unveil the wide existence of the atom-photon quasi-bound state (qBS), a kind of exotic eigenstate with anomalously small decay, in the hybrid plasmonic-photonic cavity. To derive the analytical condition of atom-photon qBS, we formulate a quantized two-mode model of the local density of states by connecting the interacting uncoupled cavity modes to the macroscopic QED. With resonant plasmon-photon coupling, we showcase the single-atom qBS that improves the efficiency of single-photon generation over one order of magnitude; and the two-atom qBS that significantly enhances spontaneous entanglement generation compared with a bare photonic cavity. Notably, such single-atom and multi-atom qBS can be simultaneously accessed in realistic plasmonic-photonic cavities, providing a versatile platform for advanced quantum technologies, such as quantum light sources, quantum computation, and quantum information.
Attempting to implement quantum information related applications utilizing atoms and photons, as they naturally form quantum systems supporting superposition states, hybrid quantum plasmonic systems emerged in the past as a platform to study and engineer light-matter interaction. This platform combines the unrivaled electromagnetic field localization of surface plasmon polaritons, boosting the light-matter coupling rate, with the tremendous integration potential of truly nanoscale structures, and both the significant emission rates of nanoantennas and photonic transmission velocities. In this work, a classical description of surface plasmon polaritons is combined with a light-matter interaction model based on a cavity quantum electrodynamical formalism. The resulting composite semi-classical method, introduced and described in this thesis, provides efficient and versatile means to simulate the dynamical behavior of radiative atomic transitions coupled to plasmonic cavity modes in the weak incoherent coupling regime. Both the emission into the far field and various dissipation mechanisms are included by expanding the model to an open quantum system. The variety of light-matter interaction applications that can be modeled with the outlined method is indicated by the four different exemplary scenarios detailed in the application chapter of this thesis. The classical description of localized surface plasmon polaritons is benchmarked by reproducing the experimental measurements of the molecular fluorescence manipulation through optical nanoantennas in a collaborative effort with experimental partners. Furthermore, in the weak light-matter coupling regime, the potential of achieving a higher nanoantenna functionality and simultaneously realizing more elaborate quantum dynamics is revealed by the three remaining applications. Each pivotally involving a bimodal nanoantenna and demonstrating different quantum optical phenomena, the implementation of cavity radiation mode conversion, non-classical cavity emission statistics, and non-classical cavity emission properties is shown and described in the application chapter.
Phenomenological approaches to photon loss have long been the workhorse of cavity-QED, but prove inadequate in the presence of sufficiently broadband light-matter interactions. We present a rigorous and ab initio derivation of a quantum master equation for a quantized optical cavity mode coupled to a dipole, using a quasinormal mode (QNM) quantization procedure for plasmonic and dielectric open-system cavity-QED, which is valid in broadband light-matter interaction regimes, including ultrastrong coupling (USC). The theory supports general three-dimensional resonators with arbitrary dispersion and loss, and thus can be applied to a wide range of realistic open cavities. Our ab initio and gauge-invariant approach fully recovers a recent result for the spectral density of a quantized cavity with a single dipole and reveals important departures from previous heuristic assumptions about system-reservoir coupling. We identify a new criterion for what we term the "broadband dissipative" regime of cavity-QED, where phenomenological models require corrections in accordance with the intrinsic and spatially-dependent complex phase of the QNM, and also shed light on fundamental limits to single-mode models in extreme coupling regimes. Using experimentally motivated plasmonic and dielectric cavity examples, we show validity ranges of our QNM master equation and spectral USC calculations, and discuss prospects for near-term experimental observation of the broadband dissipative effects.
We present a quantized pseudomode theory for solving system-level cavity quantum electrodynamics with quantum emitters coupled to plasmonic resonators. Exploiting the Green function response of a silver nanoparticle and an exact solution for the input-output coupling, we study the non-Markovian coupling regimes of multi-mode vacuum Rabi oscillations and coherently pumped multi-photon resonances from the higher lying ladder states of collective plasmon modes. The nonlinear pumping regime also facilitates pronounced population inversion of a single two-level atom through multiphoton resonances dominated by dark plasmons.
Abstract Quantum nanophotonics places nanoscale structuring in direct dialogue with photonic quantum information—compressing functionality to the few-nanometre, few-femtosecond frontier while retaining energy efficiency, speed and room-temperature operation. We highlight nanoplasmonic cavity-QED architectures in which extreme mode confinement delivers strong coupling under ambient conditions, enabling ultrafast single-photon emission and near-field multipartite entanglement using industry-grade near-field transducers that nanofocus guided light at practical efficiencies. We set these advances against the arc from early plasmonic cQED proposals and single-emitter Purcell studies to modern time-domain measurements that resolve sub-picosecond polariton/Rabi dynamics—establishing a clear route from concept to device. In parallel, we point to low-loss, high-index Mie resonators whose spectrally sharp electric and magnetic modes afford narrow-band coherent control, filtering and radiation-pattern engineering, and which naturally co-integrate in hybrid metal–dielectric stacks that combine ultrastrong local coupling with low-loss routing and storage. Finally, we discuss quantum nanoplasmonic coherent perfect absorption (qnCPA)—a waveguide-fed, non-perturbing protocol that selectively prepares and protects plasmon–emitter dressed states via dissipation-assisted, unidirectional feeding. Together with macroscopic QED and quantum quasinormal-mode quantization, which regularize open, lossy resonators and clarify when loss can be a resource, these developments chart robust, chip-scale routes to room-temperature quantum technologies.
The ability to harness light-matter interactions at the few-photon level plays a pivotal role in quantum technologies. Single photons-the most elementary states of light-can be generated on demand in atomic and solid state emitters. Two-photon states are also key quantum assets, but achieving them in individual emitters is challenging because their generation rate is much slower than competing one-photon processes. We demonstrate that atomically thin plasmonic nanostructures can harness two-photon spontaneous emission, resulting in giant far field two-photon production, a wealth of resonant modes enabling tailored photonic and plasmonic entangled states, and plasmon-assisted single-photon creation orders of magnitude more efficient than standard one-photon emission. We unravel the two-photon spontaneous emission channels and show that their spectral line shapes emerge from an intricate interplay between Fano and Lorentzian resonances. Enhanced two-photon spontaneous emission in two-dimensional nanostructures paves the way to an alternative efficient source of light-matter entanglement for on-chip quantum information processing and free-space quantum communications.
The practical development of quantum plasmonic circuits incorporating non-classical interference [1] and sources of entangled states calls for a versatile quantum theoretical framework which can fully describe the generation and detection of entangled photons and plasmons. However, majority of the presently used theoretical approaches are typically limited to the toy models assuming loss-less and nondispersive elements or including just a few resonant modes. Here, we present a rigorous Green function approach describing entangled photon-plasmon state generation through spontaneous wave mixing in realistic metal-dielectric nanostructures. Our approach is based on the local Huttner-Barnett quantization scheme [2], which enables problem formulation in terms of a Hermitian Hamiltonian where the losses and dispersion are fully encoded in the electromagnetic Green functions. Hence, the problem can be addressed by the standard quantum mechanical perturbation theory, overcoming mathematical difficulties associated with other quantization schemes. We derive explicit expressions with clear physical meaning for the spatially dependent two-photon detection probability, single-photon detection probability and single-photon density matrix. In the limiting case of low-loss nondispersive waveguides our approach reproduces the previous results [3,4]. Importantly, our technique is far more general and can quantitatively describe generation and detection of spatially-entangled photons in arbitrary metal-dielectric structures taking into account actual losses and dispersion. This is essential to perform the design and optimization of plasmonic structures for generation and control of quantum entangled states. [1] J.S. Fakonas, H. Lee, Y.A. Kelaita and H.A. Atwater, Nature Photonics 8, 317(2014) [2] W. Vogel and D.-G. Welsch, Quantum Optics, Wiley (2006). [3] D.A. Antonosyan, A.S. Solntsev and A.A. Sukhorukov, Phys. Rev. A 90 043845 (2014) [4] L.-G. Helt, J.E. Sipe and M.J. Steel, arXiv: 1407.4219