Quantum dynamics.: The Schrödinger equation

Abraham Nitzan

This chapter focuses on the time-dependent Schrödinger equation and its solutions for several prototype systems. It provides the basis for discussing and understanding quantum dynamics in condensed phases, however, a full picture can be obtained only by including also dynamical processes that destroy the quantum mechanical phase. Such a full description of quantum dynamics cannot be handled by the Schrödinger equation alone; a more general approach based on the quantum Liouville equation is needed. This important part of the theory of quantum dynamics is discussed in Chapter 10. Given a system characterized by a Hamiltonian Ĥ , the time-dependent Schrödinger equation is For a closed, isolated system Ĥ is time independent; time dependence in the Hamiltonian enters via effect of time-dependent external forces. Here we focus on the earlier case. Equation (1) is a first-order linear differential equation that can be solved as an initial value problem.

V. M. Somsikov

Extension of the Schrodinger equation is submitted by removing its limitations appearing due to the limitations of the formalism of Hamilton, based on which this equation was obtained. For this purpose the problems of quantum mechanics arising from the limitations of classical mechanics are discussed. These limitations, in particular, preclude the use of the Schrodinger equation to describe the time symmetry violation. The extension of the Schrodinger equation is realized based on the principle of duality symmetry. According to this principle the dynamics of the systems is determined by the symmetry of the system and by the symmetry of the space. The extension of the Schrodinger equation was obtained from the dual expression of energy, represented in operator form. For this purpose the independent micro - and macro-variables that determine respectively the dynamics of quantum particle system relative to its center of mass and the movement of the center of mass in space are used. The solution of the extended Schrodinger equation for the system near equilibrium is submitted. The main advantage of the extended Schrodinger equation is that it is applicable to describe the interaction and evolution of quantum systems in inhomogeneous field of external forces.

A. Bramley

Arthur Bramley

Zhaoyuan Meng, Yue Yang

Simulating fluid dynamics on a quantum computer is intrinsically difficult due to the nonlinear and non-Hamiltonian nature of the Navier-Stokes equation (NSE). We propose a framework for quantum computing of fluid dynamics based on the hydrodynamic Schr\"odinger equation (HSE), which can be promising in simulating three-dimensional turbulent flows in various engineering applications. The HSE is derived by generalizing the Madelung transform to compressible or incompressible flows with finite vorticity and dissipation. Since the HSE is expressed as a unitary operator on a two-component wave function, it is more suitable than the NSE for quantum computing. The flow governed by the HSE can resemble a turbulent flow consisting of tangled vortex tubes with the five-thirds scaling of energy spectrum. We develop a prediction-correction quantum algorithm to solve the HSE. This algorithm is implemented for simple flows on the quantum simulator Qiskit with partial exponential speedup.