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Physical Review

Perturbation Theory for an Infinite Medium of Fermions

Abraham Klein, R. E. Prange

Published Nov 1, 1958• 92 citations
Publisher

Abstract

The ground-state energy and low-energy excitations of single-particle character of an infinite medium of fermions are discussed with the aid of time-dependent Green's functions, which are convenient generalizations of the exact particle correlation functions in the ground state of $N$ particles. The power series development for the one- and two-particle functions, under the restriction to two-body forces, is derived and described by means of Feynman diagrams. The derivation of the linked-cluster expansion for the energy then follows immediately. The equivalence to previous versions is established. The one-particle function is examined in particular detail, and it is shown that the poles of its space-time Fourier transform studied as a function of the energy variable, for fixed momentum, determined the ($N+1$)-particle and ($N\ensuremath{-}1$)-particle excited states which have single-particle character. For a reasonable assumption about the full spectrum of excited states, it is found that for the interacting system, single-particle excitations with a real energy occur only at the Fermi momentum. It is pointed out that the corresponding energy, termed the perturbed Fermi energy, equals the binding energy per particle in the ground state of $N$ particles for a saturating system at equilibrium density.It is shown, finally, that the entire structure of the theory may be carried over to the case of finite temperature, requiring only a redefinition of the Green's functions. The analogy is constructed from a discussion of the internal energy.

DOI
10.1103/physrev.112.994

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Physical Review A•Apr 1, 1976•45 citations
The ground-state energy and low-energy excitations of single-particle character of an infinite medium of fermions are discussed with the aid of time-dependent Green's functions, which are convenient generalizations of the exact particle correlation functions in the ground state of NNN particles. The power series development for the one- and two-particle functions, under the restriction to two-body forces, is derived and described by means of Feynman diagrams. The derivation of the linked-cluster expansion for the energy then follows immediately. The equivalence to previous versions is established. The one-particle function is examined in particular detail, and it is shown that the poles of its space-time Fourier transform studied as a function of the energy variable, for fixed momentum, determined the (N+1N+1N+1)-particle and (N\ensuremath−1N\ensuremath{-}1N\ensuremath−1)-particle excited states which have single-particle character. For a reasonable assumption about the full spectrum of excited states, it is found that for the interacting system, single-particle excitations with a real energy occur only at the Fermi momentum. It is pointed out that the corresponding energy, termed the perturbed Fermi energy, equals the binding energy per particle in the ground state of NNN particles for a saturating system at equilibrium density.It is shown, finally, that the entire structure of the theory may be carried over to the case of finite temperature, requiring only a redefinition of the Green's functions. The analogy is constructed from a discussion of the internal energy.
The methods employed in the previous papers of this series for the ground-state energy of a normal Fermion system are extended to finite temperatures. The basic assumption is that the density matrix of the actual system in thermodynamic equilibrium can be derived by adiabatic transformation from the density matrix of system of noninteracting particles at the same temperature, volume, and chemical potential. However, the spectrum of the noninteracting system must be dependent on the intensive parameters. The self-consistency of the scheme is exhibited by demonstrating that the effective potential characterizing this system can be related to the self-energy operator of the actual system. Two equivalent versions of the theory are derived. In one of these the basic equations are precisely those of the Landau theory of Fermi liquids with the difference, however, that all quantities are given explicitly from first principles.
This chapter presents field-theoretic methods and discusses three well-known "pictures" or representations used in discussing quantum mechanical problems. It explores how to build up the true one-electron and one-phonon Green's functions as a perturbation series involving the corresponding functions for the non-interacting system. In elementary discussions of quantum mechanics one usually works in the "Schrodinger picture" in which the dynamical variables are taken to be time independent so that the wave function contains the time dependence of the problem. The one-electron Green's function gives information about the spin and charge densities and the momentum distribution of the electrons as well as information about the excitation spectrum of the system. When the system consists only of fermions interacting via an instantaneous two-body potential, the one-particle Green's function also suffices to determine the ground-state energy of the system. The electrical conductivity, magnetic susceptibility, and many other non-equilibrium properties can be obtained from the two-particle Green's function.
We are concerned with few-particle correlations in a fermionic system at finite temperature and density. Within the many-body Green functions formalism the description of correlations is provided by the Dyson equation approach that leads to effective few-body equations. They contain the dominant medium effects, which are self energy corrections and the Pauli blocking. Hence the effective two-body interactions between quasiparticles are momentum/energy-dependent and therefore they can be usesed in the medium modified, momentum space, integral AGS equations for three- and four-body systems. To investigate correlations and clusters beyond four-body, we employ, instead, the configuration space two-variable integro-differential equations (IDEA) for AAA-body bound systems which are based on Hyperspherical Harmonics and the Faddeev decomposition of the wave function in two-body amplitudes. This requires the transformation of the energy dependent two-body interactions to equivalent local, energy independent, ones. To achieve this we use inverse scattering techniques the resulting interactions being, on-- and (to all practical purposes) off--shell equivalent to the energy dependent potentials. In this way we obtain binding energy results for the 2--, 3--, 4--, and 16--particle in a medium at a finite temperature and various densities. Several aspects of the problem are discussed and the behavior of the potential surfaces obtained in the extreme adiabatic approximation, below and above the Mott transition, is investigated.
In this paper we discuss some general properties of the one-particle Green's function, for nonuniform many-fermion systems and the associated single-particle interpretation of physical properties of such systems. We consider, in particular, the ground-state energy, the density of particles in the ground state, and the single-particle excitation spectrum. The investigation is restricted to the case of a static external field and a system at zero temperature. Various general approximation methods are studied starting from one in which the self-energy operator is replaced by an Hermitian and energy-independent operator.
The ground-state wave function and energy of a finite system of interacting fermions are expanded in terms of multiple-particle excitations on an uncorrelated zero-order state. The resulting set of coupled equations constitutes a systematic variational generalization of Hartree-Fock theory. Comparison is made with many-body perturbation theory and it is shown that to any order the theory incorporates an infinite number of perturbation theory terms. Solutions of the equations for ground-state atomic systems are discussed and related to previous work using many-body perturbation theory. It is shown that the sums of perturbation terms necessary for convergence are automatically included in the equations for two-particle excitations. Application of the equations to open-shell atoms is described.
The generalized off-shell scattering of pairs of constituent fermions embedded in an infinite system of identical particles having thermodynamic properties characterized by arbitrary values of the temperature and chemical potential, is examined using a temperature-dependent Green's-function formalism, which treats particle-particle and hole-hole excitations symmetrically. The important features which emerge are (i) the possible existence of bound-state pairs (of quasiparticles which are linear combinations of particle and hole states) which correspond to poles in the scattering amplitude at negative total energies depending parametrically on the properties of the medium and the total momentum of the interacting pair; (ii) a generalized unitarity condition from which one obtains a parametrization of the on-shell positive-energy scattering amplitude by a set of real effective phase shifts; (iii) that these phase shifts completely determine the large-separation asymptotic behavior of the scattering (positive energy) pair wave functions in a manner which is form equivalent to two-particle scattering in free space; and (iv) that the small- and large-momentum asymptotic limits of the phase shifts are related to the number of bound-state pairs in the medium via an analogous, but modified, form of Levinson's theorem for free scattering. The effects of these pairing singularities on the single-particle excitation spectrum, and hence on the thermodynamic behavior of the system are outlined.