A study is made of the temporal evolution and its implications in regards to the approach to equilibrium of a system of noninteracting particles that has undergone a sudden expansion. It is assumed that the system is initially in thermal equilibrium. It is shown that the particle density approaches an equilibrium density essentially as $\frac{1}{t}$ for times shortly after expansion up to one-half the characteristic period. This period is the same as for a single-particle system. An expression is derived for the particle density that is valid for Bose, Fermi, and Boltzmann particles. The density for Bose and Fermi particles is compared with that found for Boltzmann particles.
A study is made of the temporal evolution and its implications in regards to the approach to equilibrium of a system of noninteracting particles that has undergone a sudden expansion. It is assumed that the system is initially in thermal equilibrium. It is shown that the particle density approaches an equilibrium density essentially as t1 for times shortly after expansion up to one-half the characteristic period. This period is the same as for a single-particle system. An expression is derived for the particle density that is valid for Bose, Fermi, and Boltzmann particles. The density for Bose and Fermi particles is compared with that found for Boltzmann particles.
The time evolution and its implications with regard to the approach to equilibrium of a single-particle system in a suddenly expanded box with perfectly reflecting walls is investigated using density-matrix techniques. It is shown that the time-dependent quantities exhibit a periodic behavior which is independent of the initial density matrix as long as the dimensions of the system are finite. The period is found to be $\frac{2\ensuremath{\pi}\ensuremath{\hbar}}{{E}_{1}}$ where E1 is the ground-state energy of the expanded system. The continuum approximation is employed to determine the explicit time dependence of the particle density of a system initially in thermal equilibrium. It is found that the density for an expansion into a finite volume decays essentially as t1 with small oscillations superposed on this behavior for times ranging from shortly after expansion up to one-fourth the characteristic period.
The far-from-equilibrium dynamics of an ultracold, one-dimensional Bose gas is studied. The focus is set on the comparison between the solutions of fully dynamical evolution equations derived from the two-particle irreducible (2PI) effective action and their corresponding kinetic approximation in the form of Boltzmann-type transport equations. It is shown that during the time evolution of the gas a kinetic description which includes non-Markovian memory effects in a gradient expansion becomes valid. The timescale at which this occurs is shown to exceed significantly the timescale at which the system's evolution enters a near-equilibrium drift period where a fluctuation–dissipation relation is found to hold and which would seem to be predestined for the kinetic approximation.
The time-dependent non-equilibrium dynamics of a Bose–Einstein condensate (BEC) typically generates incoherent excitations out of the condensate due to the finite frequencies present in the time evolution. We present a detailed derivation of a general non-equilibrium Greenʼs function technique that describes the coupled time evolution of an interacting BEC and its single-particle excitations in a trap, based on an expansion in terms of the exact eigenstates of the trap potential. We analyze the dynamics of a Bose system in a small double-well potential with initially all particles in the condensate. When the trap frequency is larger than the Josephson frequency, , the dynamics changes at a characteristic time, , abruptly from the slow Josephson oscillations of the BEC to fast Rabi oscillations driven by quasiparticle excitations in the trap. For times , the Josephson oscillations are undamped, in agreement with the experiments. We analyze the physical origin of the finite scale as well as its dependence on the trap parameter Δ .
We consider the temporal evolution of the entropy S of an isolated system from an initial non-equilibrium state 2· of entropy S = S i to the equilibrium state of maximum entropy S = S max > S i. The application of usual density matrix theory of quantum mechanics leads us to the surprising result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, because the entropy of the isolated system could not spontaneously increase from S i to S max by entropy production P > 0. This contradicts the second law of thermodynamics. We avoid this discrepancy by changing from quantum mechanics to quantum thermodynamics. Now the entropy production P = dS/dt and the time t are the relevant observables. In order to treat the temporal development of S and P, we at first prepare an initial state i of entropy production P i at time t < 0. Subsequently at ϑ t ≥ 0 the initial state i interacts with a continuum of final states f, which transfers the entropy production from i to f. The temporal evolution of the entropy production P(t) of our system is treated by means of the time-dependent perturbation theory. For that reason we split the operator of entropy production P = P 0 + W into two parts. The operator P 0 describes the unperturbed basic vectors of entropy production | i > and | f >, while the perturbation operator W determines the interaction between | i > and | f >. We expand the time-dependent state function < t | ψ > of the isolated system into the complete set of stationary eigenvectors | i > and | f > and calculate the time-dependent expansion coefficients c i(t) and c(f, t) by means of the dynamic equation of quantum thermodynamics − i k (d/dt) < t | ψ > = < t | P | ψ >. Here k means the Boltzmann constant, which is characteristic of quantum thermodynamics and represents the atomic entropy unit. The expansion coefficients are given by a system of coupled differential equations, from which we deduce an integral-differential equation for the coefficient c i(t) of the initial state i. Unfortunately it has been impossible to obtain an analytic solution of the complicated equation. However approximations are available. Accordingly, in the vicinity of the equilibrium state, the probability of still finding the initial state i of entropy production P i at time t is given by ω i(t) = | c i(t) |2 = exp (−Lt). The rate constant L ≥ σ depends on the density ρ(P f) of final states f of entropy production P f near by P i, and on the squared modulus of the perturbation matrix elements W if = < i | W | f >, which determines the interaction between | i > and | f >. The entropy production P(t) = P i ω i(t) = P i exp (−ϑLt) of the isolated system decreases exponentially and irreversibly with proceeding time t. Its rate-determining step is the transfer of entropy production from i to f. The integral over the entropy production of the final states f vanishes. Therefore the continuum states f do not contribute to the total entropy production P(t). The temporal evolution of the entropy S(t) can easily be calculated by integration of P(t). In conclusion, the entropy production of a non-equilibrium state is finite P(t) > 0 and only vanishes in the case of the equilibrium state P(∞) = 0. Thus, quantum thermodynamics agrees with the second law of thermodynamics.
A variety of recent studies have shed light on the far from equilibrium behavior of quantum systems. Research suggests that this away from equilibrium approach may lead to the realization of unfamiliar dynamical quantum states. For instance, we see ballistic transport at finite temperature, an absence of thermalization, and development of long-range entanglement from initially uncorrelated states. It has been shown that in some cases a time-evolving quantum state is equivalent to the ground state of an "emergent" Hamiltonian where the time enters as a param- eter. This mapping gives us insight into the nature of correlations between particles. For high temperatures, we expect no long-range correlations to develop. However, the emergent model demonstrates that the time-evolved state can be realized as a low energy eigenstate, which naturally possesses long-range correlations. Here, we study the dynamical behavior of both noninteracting and interacting particles in a one-dimensional lattice under various conditions. As the system un- dergoes time evolution, we look at the distribution of particles as well as correlations between particles in the system. We then compare the actual time-evolving state of the system to the ground state of the emergent Hamiltonian to study how long this description is valid. We generally expect that the description is valid in a given region as long as the boundary effects do not propagate into the region. We first verify and reproduce results in the literature (see Vidmar et al. [1]). We proceed to study the effect of interaction strength in a particular interacting model that shows both ballistic and diffusive transport. We then apply this formalism to calculate infinite temperature dynamics of a noninteracting system. Interestingly, this system also develops long-range correlations over time in spite of starting out from an infinite temperature state.
Abstract We consider the temporal evolution of an isolated system of N particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy, S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to dS/dt = 0: The entropy S does not change in time t. Thereby it is irrelevant, whether we consider a non-equilibrium state or an equilibrium state. Consequently, the system cannot irreversibly change by entropy production dS/dt > 0 from S′ to S max. This is a paradoxial result, which contradicts the experience. It can be traced back to the von Neumann equation, which in principle describes reversible processes and hence is unsuitable for calculating the irreversible evolution of the entropy S in time t. Each irreversible process is accompanied by a positive entropy production P = dS/dt ≥ 0 inside the system, which only vanishes in case of the equilibrium state. In order to overcome the above mentioned difficulties, we assign an operator P to the entropy production P, which is defined by the eigenvalue equation P |u〉 = P|u〉 with the state vector |u〉 of the N-particle system. There was an extensive discussion about the relation between the production of entropy P on one hand and the progression of time t on the other. Making use of this concept, we combine the operator of entropy production P with the time-development operator U (t, t 0) of the system and finally deduce the infinitesimal unitary operator U (t+τ,t) = 1 + (i/k)τ P by means of very general assumptions. Here P means the generator of the infinitesimal progression of time τ = t − t 0 and k the Boltzmann constant, representing the atomic entropy unit. Similarly to P we also treat the time t as an observable, defined by t |u〉 = t|u〉. We apply the infinitesimal time-evolution operator U (t+τ,t) to the operator of time t and finally obtain the P – t commutation relation i[ P , t ] = k, which is independent of τ. It shows that the operators P and t do not commute, and hence P and t are not sharply defined simultaneously. Instead we have uncertainties ΔP and Δt on measuring P and t, which are given by the P–t uncertainty relation ΔPΔt ≥ k/2. It readily allows a discussion of the evolution of the entropy S of the isolated system in time t from S′ to S max. Now, the irreversible steps are correctly described by the entropy production P = dS/dt > 0, while the thermal equilibrium is given by P = 0, ΔP = 0, and thus the lifetime of the equilibrium state Δt = ∞. According to the P–t uncertainty relation, the Boltzmann constant k is similarly important to the quantum thermodynamics of irreversible processes like Planck′s constant h to usual quantum mechanics.