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CRC Press eBooks

The Density Matrix

Published Sep 18, 2015• 0 citations
Publisher

Abstract

The density matrix is a useful concept which will allow one to deal with a large collection of spinors with a statistical distribution at time t = 0 and follow their time evolution by tracking the time evolution of a new operator (the density matrix). This will require the extension of the Bloch sphere to the Bloch ball concept, in which the vector representing the collection of spinors will be able to reach points in the interior of the Bloch sphere as a function of time. This requires the inclusion of damping and scattering mechanisms representing interactions among spinors, and also their interactions with the environment. The phenomenological equations allowing a description of these relaxation mechanisms are known as Bloch’s equations. They are introduced here through a connection to the Bloch sphere and Bloch ball concepts. The longitudinal and transverse relaxation times, T1 and T2, respectively, are also introduced and some numerical examples (results of Monte-Carlo simulations) are presented to illustrate their physical meaning.

DOI
10.1201/b19103-9

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The density matrix is a useful concept which will allow one to deal with a large collection of spinors with a statistical distribution at time t = 0 and follow their time evolution by tracking the time evolution of a new operator (the density matrix). This will require the extension of the Bloch sphere to the Bloch ball concept, in which the vector representing the collection of spinors will be able to reach points in the interior of the Bloch sphere as a function of time. This requires the inclusion of damping and scattering mechanisms representing interactions among spinors, and also their interactions with the environment. The phenomenological equations allowing a description of these relaxation mechanisms are known as Bloch’s equations. They are introduced here through a connection to the Bloch sphere and Bloch ball concepts. The longitudinal and transverse relaxation times, T1 and T2, respectively, are also introduced and some numerical examples (results of Monte-Carlo simulations) are presented to illustrate their physical meaning.
The density matrix is a useful concept which will allow one to deal with a large collection of spinors with a statistical distribution at time t = 0 and follow their time evolution by tracking the time evolution of a new operator (the density matrix). This will require the extension of the Bloch sphere to the Bloch ball concept, in which the vector representing the collection of spinors will be able to reach points in the interior of the Bloch sphere as a function of time. This requires the inclusion of damping and scattering mechanisms representing interactions among spinors, and also their interactions with the environment. The phenomenological equations allowing a description of these relaxation mechanisms are known as Bloch’s equations. They are introduced here through a connection to the Bloch sphere and Bloch ball concepts. The longitudinal and transverse relaxation times, T1 and T2, respectively, are also introduced and some numerical examples (results of Monte-Carlo simulations) are presented to illustrate their physical meaning.
The arguments of Chapter 2, as well as of those of subsequent chapters, have as their foundation the formalism based on the state vector of a system of which the evolution is described by the Schrödinger equation. In fact, such an approach is badly suited to the case in which the coupling between an atom and its environment (for example through collisions with other atoms or spontaneous emission into formerly empty modes of the electromagnetic field) cannot be neglected. If the correlations induced by these interactions between the atom and its environment do not concern us and we are only interested in the evolution of the atom, the formalism of the density matrix must be employed. This provides a description at all times of the state of the atom, although a state vector for the atom alone cannot be defined. In this formalism the effect of the environment on the atom is accounted for by the introduction of suitable relaxation terms (Section 2C.1) in the equation of evolution of the density matrix. An important application of the density matrix is to the case of a two-level atomic system for which the relaxation terms lead to its deexcitation to a level of lower energy. We shall show that in this case the density matrix can be represented by a vector, known as the Bloch vector , which will allow us to give simple geometrical pictures of the evolution of the system.
The Bloch sphere concept is a useful tool to represent the actions of various quantum-mechanical operators on a spinor. Most importantly, it provides a link between the rather abstract concept of a spinor and the more intuitive way (although not rigorous) of thinking of the spin of an electron as being associated with a magnetic moment along the axis of self rotation. The Bloch sphere is particularly useful when describing the action of a spatially uniform external (including time-dependent) magnetic field on the spin [1]. This will be illustrated in the next chapter through the derivation of the Rabi formula. Bloch sphere concepts are also frequently invoked in discussions of spin-based quantum computing, so that a sound understanding of this notion is imperative to comprehend the literature in that field.
The Bloch sphere concept is a useful tool to represent the actions of various quantum-mechanical operators on a spinor. Most important, it provides a link between the rather abstract concept of a spinor and the more intuitive way (although not rigorous) of thinking of the spin of an electron as being associated with a magnetic moment along the axis of self-rotation. The Bloch sphere is particularly useful when describing the action of a spatially uniform external (including time-dependent) magnetic field on the spin [1]. This will be illustrated in the next chapter through the derivation of the Rabi formula. Bloch sphere concepts are also frequently invoked in discussions of spin-based quantum computing, so that a sound understanding of this notion is imperative to comprehend the literature in that field.
Abstract This chapter introduces the density operator and the Liouville equation and outlines how reduced dynamical description of open quantum systems naturally leads to the appearance of relaxation processes. (1) The density operator and the quantum Liouville equation (the density matrix for a pure system, statistical mixtures, representations, coherences, thermodynamic equilibrium). (2) An example: The time evolution of a two-level system in the density matrix formalism. (3) Reduced descriptions. (4) Time evolution equations for reduced density operators: The quantum master equation (projection operators, The Nakajima–Zwanzig equation, Derivation of the quantum master equation using the thermal projector, The quantum master equation in the interaction representation, The Markovian limit—the Redfield equation, The secular approximation and the Lindblad equation). (5) The Lindblad equation in the ‘Heisenberg representation’. (6) Relaxation of a two-level system and a harmonic oscillator revisited. (7) The optically driven two-level system in a thermal environment—the Bloch equations. (8) The oscillating dipole model of a two-level molecule. (9) Analogy of a coupled two-level system to a spin ½ system in a magnetic field.
Extracting macroscopic properties of a system from microscopic interactions has always been an interesting topic with the most diverse applications. Here, we use the quantum Boltzmann equation to investigate the density matrix evolution of a system of nucleons. Using the quantum field theory tools for constructing the density matrix operators and calculating the interactions is the main advantage of this equation. The right-hand side of this equation involves forward scattering and usual collision terms. As examples of application, we calculate the standard Bloch equations for the nucleon system in the presence of a constant and an oscillating magnetic field from the forward scattering term. We find the longitudinal and transverse relaxation times from the collision term by considering the nucleon-nucleon scattering.