The large-N limit of a nearest-neighbor SU(N) antiferromagnet on a bipartite lattice exhibits in dimensions d\ensuremath{\ge}2 a zero-temperature phase transition between a N\'eel ordered state and a resonating-valence-bond state. Here it is shown in d=1,2 that topological effects produce spin-Peierls or valence-bond-solid order in the non-N\'eel phase with a ground-state degeneracy which varies periodically with ``spin'' for fixed N with periodicity given by the coordination number of the lattice. Thus a non-N\'eel phase of the spin-(1/2 Heisenberg model on a square lattice would be a spin-Peierls state with a fourfold degeneracy due to broken lattice rotational symmetry.
We examine large-N limits of the nearest-neighbor SU(N) quantum antiferromagnets on bipartite lattices in d=1,2. In d=2 the model displays a transition from a N\'eel to a disordered phase. The properties of the disordered phase close to the phase boundary are crucially dependent upon the nature of ``hedgehog''-like instanton tunneling events. We calculate the Berry phases of the instantons and show that, at scales larger than the spin-correlation length, the system can be described by a Coulomb plasma of instantons with complex fugacities. The properties of the Coulomb plasma vary periodically with the ``spin''
nc of the states at each site, with periodicity given by the coordination number Z of the lattice [
nc=2S for SU(2)]. For
nc\ensuremath{\ne}0 (mod Z) the disordered phase has a broken lattice symmetry with spin-Peierls order, while for
nc=0 (mod Z), the ground state is a valence-bond solid state with no broken symmetry. Related topological effects for the d=1 chain lead to spin-Peierls order for odd
nc. These results are for a class of models which have, at sites of the A sublattice, representations of SU(N) described by a Young tableau with a single row, and the conjugate on the B sublattice. Similar results are also obtained for representations with m rows, using U(m) gauge theory.