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Annals of Physics

Green's function derivation of the method of approximate second quantization

Donald H. Kobe

Published Jun 1, 1963• 0 citations
Publisher
DOI
10.1016/0003-4916(63)90393-2

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In this chapter we introduce the fundamental concepts behind the Green Function Theory. We start from a description of the second quantization method and then, after introducing the ensemble average of an operator, we define the main object of the theory, the Green function. Further on, after obtaining the equation of motion for the Green function, we introduce the self-energy operator and we discuss the Hartree-Fock approximation, the second-Born approximation and the GW approximation to the self-energy.
Part 1 Fundamentals and examples: systems of identical particles second quantization for fermions second quantization for bosons unitary transformations and field operators example - the Hamiltonian of translationally invariant systems in second quantization density operators the Hartree-Fock approximation restricted Hartree-Fock approximation and the symmetry dilemma Hartree-Fock for translationally invariant systems the homogeneous electron gas in the Hartree-Fock approximation long-range correlations in the electron-gas - plasmons phonons superconductivity. Part 2 Green's functions: pictures the single-particle Green's function and the hierarchy of equations of motion. Part 3 Perturbation theory: time-dependent perturbation theory with adiabatic turning-on of the interaction particle and hole operators and Wick's theorem Feynman diagrams diagrammatic calculation of the vacuum amplitude an example - the Gell-Mann-Brueckner correlation energy of a dense electron gas diagrammatic calculation of the single-particle Green's function - Dyson's equation diagrammatic analysis of the Green's function G(kappa, omega) self-consistent perturbation theory, higher-order Hartree-Fock theory the quasi-particle concept diagrammatic calculation of the two-particle Green's function and the polarization propagator effective interaction and dressed vertices plasmons in higher order perturbation theory at finite temperatures. Part 4 Fermi liquid theory: introduction equilibrium properties transport equation and collective modes microscopic derivation of the Landau fermi liquid theory applications to the Kondo problem.
Using semiclassical approximations and graph-theoretical concepts, a path representation of the energy-dependent Green function in a one-dimensional multiple-well potential is derived. Applying uniform semiclassical methods, this representation is valid for energies close to the barrier maxima, where tunnelling and above-barrier reflection are of importance. Semiclassical quantization is discussed and a closed path representation of the density of states is derived. Applications to wavepacket dynamics and to the quantization of disordered systems are presented.