In this chapter we shall consider some aspects of quantum mechanics. The aim will be to outline the parts of quantum mechanics that are needed for an understanding of particle physics. We shall explore two experiments and their interpretation. The version of quantum mechanics that we shall develop (and there are many) will be that of Richard Feynman as this is the most appropriate for understanding the fundamental forces.
In this chapter we shall consider some aspects of quantum mechanics. The aim will be to outline the parts of quantum mechanics that are needed for an understanding of particle physics. We shall explore two experiments and their interpretation. The version of quantum mechanics that we shall develop (and there are many) will be that of Richard Feynman as this is the most appropriate for understanding the fundamental forces.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
In this monograph I present the basic structure of an interpretation of quantum mechanics. Chapter 1 outlines the central ideas behind the interpretation and illustrates them by means of examples: Subsequent chapters fill in the details of the interpretation. But it is important to begin by explaining what I take an interpretation of quantum mechanics to be, and why any further interpretation needs to be offered. After all, quantum mechanics (in some form) is by now both a foundation for much of contemporary physics and a veteran of more than sixty years of intermittent but sometimes intense reflection on its content and meaning. What more can be, or should be, said about the interpretation of this theory? Many physicists believe that no more needs to be said: that there is basically only one way of understanding quantum mechanics, due to Bohr, Heisenberg, Pauli, and others, and that the only remaining interpretative task is that of the physics teacher, who seeks to perfect ways of conveying this understanding to new generations of students. Sir Rudolf Peierls, one of the more lucid and distinguished of these physicists, even objects to the use of the familiar term ‘Copenhagen interpretation’ to refer to the way of understanding quantum mechanics due to Bohr, Heisenberg, Pauli, and others. Because this sounds as if there were several interpretations of quantum mechanics. There is only one. There is only one way in which you can understand quantum mechanics.[…]
The difficulties of the old quantum theory were largely dispelled by the development of quantum mechanics in the 1920s. First Heisenberg (1925) developed the rather abstract matrix mechanics and soon after Schro¨dinger (1926; see also Eckart, 1926) developed the physically more appealing wave mechanics. Subsequently he showed them to be mathematically equivalent. The physicists were greatly relieved; now they had once again a mathematical formalism that enabled the results of experiments to be calculated. It was possible to move forward. It is certainly a very elegant and indeed beautiful formalism, and does enable the results of many physical measurements to be calculated with great accuracy. It is used daily by atomic and nuclear physicists; there is no other way to make calculations. From the earliest days there has been intense debate about the interpretation of quantum mechanics, and it shows no signs of being settled; if anything it is becoming more intense over the years. As Penrose has remarked, no one understands quantum mechanics. Feynman (1967; see also Sykes, 1994) also admitted that ‘nobody understands quantum mechanics’, and Einstein once remarked: ‘I have thought a hundred times as much about the quantum problems as I have about general relativity theory’ (Pais, 1994, p. 57). It should therefore be evident that the most that can be done here is to try to show where the real difficulties lie, and how the failure to recognize that quantum mechanics is an essentially statistical theory has led to a series of confusing quantum paradoxes. It is just these paradoxes that have often been used to support theological speculations. It is useful to ask what ‘understanding quantum mechanics’ actually means. Certainly it means being able to calculate the results of many measurements. The same applies to Newton’s theory of gravitation, which we understand in the sense that we can use it as a basis of calculation, although we do not really understand the gravitational force itself. Very often, especially in modern physics, the mathematical formalism does not give us the sort of intuitive physical feeling for what is going on that we often obtain from classical mechanics. Perhaps we can never achieve more than this for quantum mechanics. In classical mechanics we can assume that a property that is measured objectively exists prior to the interaction of the measuring apparatus with the observed system. Quantum mechanics, however, ‘is incompatible with the proposition that measurement discovers some unknown but pre-existing property’ (Peres, 1997, p. 14). There is an important distinction between mysteries and absurdities. We may be forced to live with mysteries, but there is no reason why we should put up with absurdities such as the wave-particle duality, tunnelling through potential barriers, acausal events and the collapse of the wave function. These are the quantum paradoxes that will be discussed later on. They arise within the Copenhagen interpretation of quantum mechanics and are solved by other interpretations. These alternative interpretations enable us to make conjectures about what is going on, even though we cannot understand it in detail. This is acceptable and a stimulus to further research. It is certainly difficult enough to understand quantum mechanics, but there is no need to try to visualize logical absurdities in the effort to do so. Quantum mechanics is a mathematical formalism that makes it possible to calculate the results of some experiments. Anything more than this, such as questions about the interpretation of what is measured and whether it tells us what is actually going on in the system being studied, belongs to philosophy. Thus we are concerned here with what is essentially a philosophical debate; if it were just a matter of physics the debate would have been settled long ago. One of the difficulties is that it invokes the results of experiments and uses the language of quantum mechanics. Inevitably this language uses philosophical terms and then it is easy to give the impression that the philosophical propositions are in some way entailed by the physical results. These in turn can influence theological thinking. In order to be quite clear which arguments are justified and which are not, it is essential to separate the three levels of discourse: physical, philosophical and theological. Our task is to relate these together, and this immediately raises the traditional problems of the philosophy of science, including the relation of experiment to theory, and of theory to explanation. We begin by discussing experiments, distinguishing between those that are real and those that are imaginary.
To obtain a basic understanding of how and why quantum computing works, one needs to understand quantum theory. In this book we treat quantum mechanics as an axiomatic theory, with some interpretations where possible. The implications of quantum mechanics are often counter intuitive, or rather, beyond intuition, since we have no direct experience of the quantum world as we do the classical. We assume no prior knowledge of quantum mechanics, and will develop all the basic tools and ideas necessary for a sound grasp of the fundamentals of the theory, especially what is relevant for two-state systems that we’ll use as qubits. For a more detailed picture, the reader is referred to standard texts on quantum mechanics, such as the books by J. J. Sakurai [60], R. Shankar [62], C. Cohen-Tannoudji [20], E. Merzbacher [49] etc. or the Feynman Lectures on Physics Vol III [34].
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
This authoritative, advanced introduction provides a complete, modern perspective on quantum mechanics. It clarifies many common misconceptions regarding wave/particle duality and the correct interpretation of measurements. The author develops the text from the ground up, starting from the fundamentals and presenting information at an elementary level, avoiding unnecessarily detailed and complex derivations in favor of simple, clear explanations. He begins in the simplest context of a two-state system and shows why quantum mechanics is inevitable, and what its relationship is to classical mechanics. He also outlines the decoherence approach to interpreting quantum mechanics. Distinguishing features: Provides a thorough grounding in the principles and practice of quantum mechanics, including a core understanding of the behavior of atoms, molecules, solids, and light. Utilizes easy-to-follow examples and analogies to illustrate important concepts. Helps develop an intuitive sense for the field, by guiding the reader to understand how the correct formulas reduce to the non-relativistic ones. Includes numerous worked examples and problems for each chapter.