We have discussed the possibilities of correlation spectroscopy (light beating spectroscopy) technique if squeezed light is used as a probe radiation for medium monitoring. The dispersion of the fluctuation of photocurrent spectrum measured in this method is expressed in terms of fourth order photocurrent correlation function. This correlation function is considered and evaluated in assumptions of photodetection theory developed by Glauber in first nonvanishing orders in interaction of probe light with the atoms of a photodetector. We show that fourth order correlation function is determined by all field TN-ordered amplitude correlation functions up to the fourth order. In case of heterodyne detection, when the light incident on photodetector surface is the mix of strong coherent modes of local oscillator wave and weak non-coherent (squeezed) modes, the observable (photocurrent spectrum) as well as its fluctuation (noise of photocurrent spectrum) is expressed in terms of spectrum-dependent Mandel parameter. We have discussed possible improvement of sensitivity limit for correlation spectroscopy in this case.
Cavity-enhanced spectroscopy is a widely used experimental technique. We show that detuning the cavity frequency from the transition of interest can enhance the precision for dipole moment estimation by up to two orders of magnitude beyond the improvement when the cavity is resonant with the transition. We show this for both classical continuous-wave (CW) and pulsed single-photon probes, even in the presence of losses. We trace this enhancement to a detuning-controlled redistribution of information between the light- and matter-like polaritons, with losses determining the optimal branch. We show that this enhancement remains accessible using conventional photodetection and time-correlated single-photon counting.
Photon emission correlation spectroscopy is an indispensable tool for the study of atoms, molecules, and, more recently, solid-state quantum defects. In solid-state systems, its most common use is as an indicator of single-photon emission, a key property for quantum technology. Beyond an emitter's single-photon purity, however, photon correlation measurements can provide a wealth of information that can reveal details about its electronic structure and optical dynamics that are hidden by other spectroscopy techniques. This tutorial presents a standardized framework for using photon emission correlation spectroscopy to study quantum emitters, including discussion of theoretical background, considerations for data acquisition and statistical analysis, and interpretation. We highlight important nuances and best practices regarding the commonly-used
g(2)(tau=0)<0.5 test for single-photon emission. Finally, we illustrate how this experimental technique can be paired with optical dynamics simulations to formulate an electronic model for unknown quantum emitters, enabling the design of quantum control protocols and assessment of their suitability for quantum information science applications.