A proposed definition of resonant states
Arturo Cisneros, Harold V. McIntosh
Abstract The widely cited definition of quantization in terms of square‐integrable wave functions does not apply to continuum wave functions, to such phenomena as metastable states, or many‐body resonances. A better philosophical foundation for quantum mechanics separates the probabilistic aspects based on square integrable Hilbert space functions from the dynamical aspects based upon the solutions of Shroedinger's (or Dirac's) equation. A Hilbert space may have a non‐Hilbert space basis, which may be described by Stieltjes integrals and a spectrum measure. This viewpoint is expounded by reference to a very detailed analysis of a simple model, through which a precise definition of a Bohr–Feshbach resonance can be given. We propose a definition of a “metastable state,” showing that it is consistent with accepted usage, and that it overcomes a series of objections which have been catalogued by Simon. Its rate of decay is given by the Fourier–Stieltjes transform of the spectral density function; it is moreover the longest‐lived initially localized state which can be formed from a small span of energy eigenfunctions near its mean energy.
International Journal of Quantum Chemistry•Jul 1, 1985•1 citation