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Angular Momentum and Spin

Gennaro Auletta, Shang-Yung Wang

Published Jun 20, 2014• 1 citation
Publisher

Abstract

In this chapter we shall treat two of the most important observables of quantum mechanical systems: angular momentum and spin. We shall argue that angular momentum is the generator of rotations. In quantummechanics, angular momentum is quantized in units of the reduced Planck constant. The quantization of angular momentum is dealt with by finding the angular momentum eigenvalues and eigenstates. We shall then apply the theory of angular momentum to study the hydrogen atom. Spin is an intrinsic angular momentum of subatomic particles and therefore corresponds to an important intrinsic degree of freedom. We shall discuss briefly how spin was discovered and many of its important properties. Finally, we shall also explore here some further subtleties of quantum theory.a When we consider quantum systems in two or three spatial dimensions, we need to take into account also the effect of rotations. In this case, we need to introduce a physical quantity called the angular momentum, that is, themomentum induced by or connected with rotations. In classical physics the angular momentum of a particle about a given origin is defined by [see Fig. 8.1]

DOI
10.1201/b17083-14

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In this chapter we shall treat two of the most important observables of quantum mechanical systems: angular momentum and spin. We shall argue that angular momentum is the generator of rotations. In quantummechanics, angular momentum is quantized in units of the reduced Planck constant. The quantization of angular momentum is dealt with by finding the angular momentum eigenvalues and eigenstates. We shall then apply the theory of angular momentum to study the hydrogen atom. Spin is an intrinsic angular momentum of subatomic particles and therefore corresponds to an important intrinsic degree of freedom. We shall discuss briefly how spin was discovered and many of its important properties. Finally, we shall also explore here some further subtleties of quantum theory.a When we consider quantum systems in two or three spatial dimensions, we need to take into account also the effect of rotations. In this case, we need to introduce a physical quantity called the angular momentum, that is, themomentum induced by or connected with rotations. In classical physics the angular momentum of a particle about a given origin is defined by [see Fig. 8.1]
Spin-s systems Angular momentum is one of the fundamental quantities of Newtonian physics, and in quantum physics its importance is at least as great. In quantum mechanics we often distinguish between two types of angular momentum: orbital angular momentum , which a system of particles possesses due to particle motion through space; and spin angular momentum , which is an intrinsic property of a particle. The distinction will be important later, but for now we will ignore it. We will here refer to angular momentum of any sort as “spin” and develop general-purpose mathematical tools for its description. We have already dealt with spin systems, particularly the example of a spin-½ particle. Our approach began with the empirical observation that a measurement of any spin component of a spin-½ particle could yield only the results +ħ/2 or −ħ/2. We introduced the basis states | z ±〉 for the two-dimensional Hilbert space ℋ. We also gave other basis states such as {| x ±〉} and {| y ±〉} in terms of the | z ±〉 states. From basis states and measurement values we constructed operators for the spin components S x , S y , and S z . With the operators in hand, we could then examine the algebraic relations between them (such as the commutation relation in Exercise 3.56). Our job here is to generalize our analysis to systems of arbitrary spin. To do this, we will reverse our chain of logic.
In this chapter, we develop the background needed to move our quantum mechanical formalism fully into three dimensions. We discuss angular momentum, which is the motional complement to spin angular momentum, that we developed earlier. There are some critical differences between orbital and spin angular momentum, and we need to carefully discuss how they relate and how they differ. Why is angular momentum so important? Because in problems where we have central forces (forces that depend only on the distance between two particles and act along the line connecting the two particles), the angular momentum is conserved. So, it becomes an integral part of how we solve the problem. The most important problem we have to solve, the hydrogen atom, is a central force problem; hence, we need this work before we can move forward to some really interesting physics that will come in Chap. 11 . We cover the angular momentum operators, eigenvalues, and eigenstates, their matrix representations, how to combine angular momentum, and spherical harmonics. We revisit the EPR experiment using our new formalism. We also discuss some unique representations of angular momentum by mapping to two-dimensional harmonic oscillators, as developed by Schwinger.
Spin is well known to be an intrinsically relativistic property of particles. Nonetheless its effects are seen in many physical situations which are not obviously relativistic, perhaps the most obvious examples being magnets and the quantum mechanically permitted electronic configurations of the elements in the periodic table. The view of spin adopted in these and other problems is that the electron has a quantized spin ( s = 1/2) and that is a fundamental tenet of the theory, rather than something that has to be explained. In this chapter we are going to discuss the behaviour of spin-1/2 particles (electrons, protons and neutrons for example) without much direct reference to relativistic quantum theory and the origins of spin. This chapter should be instructive in its own right and as a guide to understanding spin when we come to discuss it in a fully relativistic context at various stages throughout this book. Unless otherwise specified, we will refer to electrons, but it should be borne in mind that the theory is equally applicable to any spin-1/2 particle. Students of quantum theory cannot delve very deeply into the subject without coming across the quantization of angular momentum. The orbital angular momentum usually surfaces in the theory leading up to the quantum description of the hydrogen atom.
Chapter 11 is devoted to the quantum theory of angular momentum. As in classical mechanics, working with angular momentum requires leaving the one-dimensional space, with all the complications that this entails. The importance of angular momentum resides in at least three facts: i) central problems are of particular interest; (ii) many particles have an intrinsic angular momentum (the spin); and iii) the physics of angular momentum involves features such as the so-called space quantization. The first part of the chapter deals with the orbital angular momentum and its eigenfunctions, the spherical harmonics. Its algebraic properties, embodied in the matrix representation, allow for an extension of the theory to half-integer angular momentum in terms of Pauli matrices, as well as the addition of angular momenta.
One of the most important applications of the quantum mechanical formalism developed in the previous chapter is to angular momentum. This is because many microsystems are spherically symmetric, or approximately so, and angular momentum is therefore conserved. This chapter discusses that a careful study of quantized angular momentum leads to a completely new physical phenomenon – intrinsic spin. The fact that the angular momentum vector of a quantum particle must point in certain restricted directions is a bizarre quantum property. In some respects the abstract idea of an internal angular momentum is reminiscent of the classical concept of a spinning body. In classical mechanics angular momentum is added vectorially but in the quantum case the issue is more subtle. The procedure will be illustrated by the example of the addition of two spins. As in classical mechanics a charged quantum system with angular momentum possesses a magnetic moment μ.
Angular momentum is a very important and revealing property of many physical systems. In classical mechanics the principle of conservation of angular momentum is a powerful aid to the solution of such problems as the orbits of planets and satellites and the behaviour of gyroscopes and tops. The role of angular momentum in quantum mechanics is probably even more important and this will be the subject of the present chapter and the next. We shall find that the operators representing the components of angular momentum do not commute with each other, although they all commute with the operator representing the total angular momentum. It follows that no pair of these components can be measured compatibly and we shall therefore look for a set of eigenfunctions that are common to the operators representing the total angular momentum and one of its components. We shall find that the angular momentum eigenvalues always form a discrete set and that, in the case of a central field, the operators commute with the Hamiltonian, implying that the total angular momentum and one component can be measured compatibly with the energy in this case, so that their values, once measured, remain constant in time. Consideration of angular momentum will also enable us to make predictions about the behaviour of atoms in magnetic fields, and we shall find that these are in agreement with experiment only if we assume that the electron (in common with many other fundamental particles) has an intrinsic “spin” angular momentum in addition to the “orbital” angular momentum associated with its motion. The interaction between spin and orbital angular momenta leads to detailed features of the atomic spectra which are known as “fine structure.” We shall also use the measurement of angular momentum to illustrate the quantum theory of measurement discussed in the previous chapter.