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CRC Press eBooks

Quantum Continuous Time Random Walk Model

Sushanta Dattagupta

Published Nov 12, 2013• 0 citations
Publisher

Abstract

The continuous time random walk (CTRW) framework (Montroll and Weiss 1965, Montroll and Scher 1973) was described in our earlier Chapters 6 through 9. The CTRW scheme is conceptually appealing and at the same time mathematically flexible to facilitate incorporation of various generalizations. Thus, although CTRW is usually set in the context of a Poisson processdriven pulse sequence leading to stationary Markov systems, incorporation of non-Poissonian pulsing with concomitant waiting-time distributions was seen in Chapter 7 to yield anomalous diffusion.

DOI
10.1201/b16008-18

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The continuous time random walk (CTRW) framework (Montroll and Weiss 1965, Montroll and Scher 1973) was described in our earlier Chapters 6 through 9. The CTRW scheme is conceptually appealing and at the same time mathematically flexible to facilitate incorporation of various generalizations. Thus, although CTRW is usually set in the context of a Poisson processdriven pulse sequence leading to stationary Markov systems, incorporation of non-Poissonian pulsing with concomitant waiting-time distributions was seen in Chapter 7 to yield anomalous diffusion.
Initially developed in the framework of quantum stochastic calculus, the main equations of quantum stochastic filtering were later on derived as the limits of Markov models of discrete measurements under appropriate scaling. In many branches of modern physics it became popular to extend random walk modeling to the continuous time random walk (CTRW) modeling, where the time between discrete events is taken to be non-exponential. In the present paper we apply the CTRW modeling to the continuous quantum measurements yielding the new fractional in time evolution equations of quantum filtering and thus new fractional equations of quantum mechanics of open systems. The related quantum control problems and games turn out to be described by the fractional Hamilton-Jacobi-Bellman (HJB) equations on Riemannian manifolds. By-passing we provide a full derivation of the standard quantum filtering equations, in a modified way as compared with existing texts, which (i) provides explicit rates of convergence (that are not available via the tightness of martingales approach developed previously) and (ii) allows for the direct applications of the basic results of CTRWs to deduce the final fractional filtering equations.
It is shown in this paper that the quantum master equation can be mapped to a modified continuous time random walk (CTRW) if the relaxation term is composed of transitions over a set of states. When the Hamiltonian is time-independent and transitions are between its eigenlevels, such a modified CTRW reduces to the Markovian walk equivalent to the Pauli master equation. On the other hand, the memory in such a modified CTRW is composed of a temporal factor and the probability determined by the Liouville flow when the relaxation term is reduced as a special dephasing term.
Recent findings suggest that processes such as the excitonic energy transfer through the photosynthetic antenna display quantal features, aspects known from the dynamics of charge carriers along polymer backbones. Hence, in modeling energy transfer one has to leave the classical, master-equation-type formalism and advance towards an increasingly quantum-mechanical picture, while still retaining a local description of the complex network of molecules involved in the transport, say through a tight-binding approach. Interestingly, the continuous time random walk (CTRW) picture, widely employed in describing transport in random environments, can be mathematically reformulated to yield a quantum-mechanical Hamiltonian of tight-binding type; the procedure uses the mathematical analogies between time-evolution operators in statistical and in quantum mechanics: The result are continuous-time quantum walks (CTQWs). However, beyond these formal analogies, CTRWs and CTQWs display vastly different physical properties. In particular, here we focus on trapping processes on a ring and show, both analytically and numerically, that distinct configurations of traps (ranging from periodical to random) yield strongly different behaviors for the quantal mean survival probability, while classically (under ordered conditions) we always find an exponential decay at long times.
Recent findings suggest that processes such as the electronic energy transfer through the photosynthetic antenna display quantal features, aspects known from the dynamics of charge carriers along polymer backbones. Hence, in modeling energy transfer one has to leave the classical, masterequation-type formalism and advance towards an increasingly quantum-mechanical picture, while still retaining a local description of the complex network of molecules involved in the transport, say through a tight-binding approach. Interestingly, the continuous time random walk (CTRW) picture, widely employed in describing transport in random environments, can be mathematically reformulated to yield a quantummechanical Hamiltonian of tight-binding type; the procedure uses the mathematical analogies between time-evolution operators in statistical and in quantum mechanics: The result are continuoustime quantum walks (CTQWs). However, beyond these formal analogies, CTRWs and CTQWs display vastly different physical properties. In particular, here we focus on trapping processes on a ring and show, both analytically and numerically, that distinct configurations of traps (ranging from periodical to random) yield strongly different behaviours for the quantal mean survival probability, while classically (under ordered conditions) we always find an exponential decay at long times.
Continuous time quantum walks (CTQWs) do not necessarily perform better than their classical counterparts, the continuous time random walks (CTRWs). For one special graph, where a recent analysis showed that in a particular direction of propagation the penetration of the graph is faster by CTQWs than by CTRWs, we demonstrate that in another direction of propagation the opposite is true. In this case a CTQW initially localized at one site displays a slow transport. We furthermore show that when the CTQW's initial condition is a totally symmetric superposition of states of equivalent sites, the transport gets to be much more rapid.