It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).
It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).
Introductory Remarks The concepts and techniques of angular momentum theory are by now all but ubiquitous in present-day quantum physics; there is scarcely a single issue of a physics journal that does not in some article directly use angular momentum constructs. It would accordingly be rather fatuous, if not indeed quite impossible, to attempt any definitive (or even very detailed) survey of applications. The purpose of this chapter is therefore rather more modest; we shall focus attention on several typical applications of the theory, in widely different contexts, with an emphasis toward illustrating the basic principles. In discussing any particular field of application, however, we have attempted not to be extensive, but instead have chosen to present a novel, or, at least, unfamiliar, aspect of the subject in some detail. (The discussion in Section 6g – of a result due to Casimir – provides a good example of our intentions.) Basic Principles Underlying the Applications Before turning to specific examples, it will be useful to review briefly the principles underlying the applications. We have seen that a symmetry in quantum physics is a transformation on state vectors (active view – vectors in Hilbert space are transformed and operators are kept fixed) and on observables (passive view – vectors in Hilbert space are kept fixed and operators are transformed) such that all probabilities are preserved (Chapter 3, Section 14). Using the Wigner theorem, we found that this led to either a unitary, or an antiunitary, realization of the symmetry by operators.
This is the most complete handbook on the quantum theory of angular momentum. Containing basic definitions and theorems as well as relations, tables of formula and numerical tables which are essential for applications to many physical problems, the book is useful for specialists in nuclear and particle physics, atomic and molecular spectroscopy, plasma physics, collision and reaction theory, quantum chemistry, etc. The authors take pains to write many formulae in different coordinate systems thus providing users with added ease in consulting this book. Each chapter opens with a comprehensive list of its contents to ease the search for any information needed later. New results relating to different aspects of the angular momentum thoery are also included. Containing close to 500 pages this book also gathers together many useful formulae besides those related to angular momentum. The book also compares different notations used by previous authors.
Abstract This book introduces the quantum theory of angular momentum to students who are unfamiliar with it and develops it to a stage useful for research. The first part contains the basic theory of rotations and angular momentum. As the book aims to emphasize applications, mathematical details are avoided and difficult theorems stated without proof. The second part contains examples of applications to a wide range of physical phenomena and presents a collection of results helpful in solving problems.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.
THE QUANTUM THEORY OF ANGULAR MOMENTUM began with Bohr’s enunciation of the rules for the quantization of orbital angular momentum in 1913, and the refinement of these rules by Sommerfeld [ 1 ] and Landé [ 2 ] within the framework of the old quantum theory. A basic result for angular momentum in modern quantum theory, which we call The First Fundamental Result, was given in the third foundational paper in 1926 by Born, Heisenberg, and Jordan [ 3 ], who not only gave the basic commutation relations for the components of the total angular momentum J, but all finite-dimensional Hermitian matrix representations of these components. Dirac [ 4 ] simultaneously deduced these basic commutation relations using his algebraic approach to quantum mechanics, and later gave a marvelously brief derivation of their matrix representations in his book [ 5 ]. Further developments, including the famous Pauli matrices and results relating to angular momentum selection rules for transitions in atomic systems, are given in the papers by Heisenberg and Jordan [ 6 ], Pauli [ 7 ], and Güttinger and Pauli [ 8 ]. These works, and the books by Born and Jordan [ 9 ] and Condon and Shortley [ 10 ], fixed the framework for much of the developments in angular momentum theory, which was hardly distinguishable from the general quantum theory in the context of which it was developed for the purpose of giving a consistent description of the spectra of atoms. Little emphasis was given to the universal and distinctive role of symmetry.