We report the sympathetic cooling and Coulomb crystallization of molecular ions above the surface of an ion-trap chip. ${\mathrm{N}}_{2}^{+}$ and ${\mathrm{CaH}}^{+}$ ions were confined in a surface-electrode radio-frequency (rf) ion trap and cooled by the interaction with laser-cooled ${\mathrm{Ca}}^{+}$ ions to secular translational temperatures in the millikelvin range. The configuration of trapping potentials generated by the surface electrodes enabled the formation of planar bicomponent Coulomb crystals and the spatial separation of the molecular from the atomic ions on the chip. The structural and thermal properties of the Coulomb crystals were characterized using molecular dynamics simulations. The present study extends chip-based trapping techniques to cold molecular ions with potential applications in mass spectrometry, chemistry, quantum information science, and spectroscopy.We report the sympathetic cooling and Coulomb crystallization of molecular ions above the surface of an ion-trap chip. ${\mathrm{N}}_{2}^{+}$ and ${\mathrm{CaH}}^{+}$ ions were confined in a surface-electrode radio-frequency (rf) ion trap and cooled by the interaction with laser-cooled ${\mathrm{Ca}}^{+}$ ions to secular translational temperatures in the millikelvin range. The configuration of trapping potentials generated by the surface electrodes enabled the formation of planar bicomponent Coulomb crystals and the spatial separation of the molecular from the atomic ions on the chip. The structural and thermal properties of the Coulomb crystals were characterized using molecular dynamics simulations. The present study extends chip-based trapping techniques to cold molecular ions with potential applications in mass spectrometry, chemistry, quantum information science, and spectroscopy.

arXiv:1404.4292Physical Review AAug 4, 201410 citations

Structural phase transitions and topological defects in ion Coulomb crystals

Heather L. Partner, Ramil Nigmatullin, T. Burgermeister +7 more

arXiv:1411.5365Physica B Condensed MatterDec 8, 201419 citations

Prospects of a thousand-ion Sn2+ Coulomb-crystal clock with sub-10−19 inaccuracy

David R. Leibrandt, S. G. Porsev, Charles Cheung +1 more

Abstract Optical atomic clocks are the most accurate and precise measurement devices of any kind, enabling advances in international timekeeping, Earth science, fundamental physics, and more. However, there is a fundamental tradeoff between accuracy and precision, where higher precision is achieved by using more atoms, but this comes at the cost of larger interactions between the atoms that limit the accuracy. Here, we propose a many-ion optical atomic clock based on three-dimensional Coulomb crystals of order one thousand Sn2+ ions confined in a linear RF Paul trap with the potential to overcome this limitation. Sn2+ has a unique combination of features that is not available in previously considered ions: a 1S0 ↔ 3P0 clock transition between two states with zero electronic and nuclear angular momentum (I = J = F = 0) making it immune to nonscalar perturbations, a negative differential polarizability making it possible to operate the trap in a manner such that the two dominant shifts for three-dimensional ion crystals cancel each other, and a laser-accessible transition suitable for direct laser cooling and state readout. We present calculations of the differential polarizability, other relevant atomic properties, and the motion of ions in large Coulomb crystals, in order to estimate the achievable accuracy and precision of Sn2+ Coulomb-crystal clocks.Abstract Optical atomic clocks are the most accurate and precise measurement devices of any kind, enabling advances in international timekeeping, Earth science, fundamental physics, and more. However, there is a fundamental tradeoff between accuracy and precision, where higher precision is achieved by using more atoms, but this comes at the cost of larger interactions between the atoms that limit the accuracy. Here, we propose a many-ion optical atomic clock based on three-dimensional Coulomb crystals of order one thousand Sn2+ ions confined in a linear RF Paul trap with the potential to overcome this limitation. Sn2+ has a unique combination of features that is not available in previously considered ions: a 1S0 ↔ 3P0 clock transition between two states with zero electronic and nuclear angular momentum (I = J = F = 0) making it immune to nonscalar perturbations, a negative differential polarizability making it possible to operate the trap in a manner such that the two dominant shifts for three-dimensional ion crystals cancel each other, and a laser-accessible transition suitable for direct laser cooling and state readout. We present calculations of the differential polarizability, other relevant atomic properties, and the motion of ions in large Coulomb crystals, in order to estimate the achievable accuracy and precision of Sn2+ Coulomb-crystal clocks.

arXiv:2205.15484Nature CommunicationsJul 5, 202424 citations

Trapping Single Ions and Coulomb Crystals with Light Fields

Leon Karpa

arXiv:1910.00360SpringerBriefs in physicsJan 1, 201911 citations

We report the sympathetic cooling and Coulomb crystallization of molecular ions above the surface of an ion-trap chip.

{\mathrm{N}}_{2}^{+}

and

{\mathrm{CaH}}^{+}

ions were confined in a surface-electrode radio-frequency (rf) ion trap and cooled by the interaction with laser-cooled

{\mathrm{Ca}}^{+}

ions to secular translational temperatures in the millikelvin range. The configuration of trapping potentials generated by the surface electrodes enabled the formation of planar bicomponent Coulomb crystals and the spatial separation of the molecular from the atomic ions on the chip. The structural and thermal properties of the Coulomb crystals were characterized using molecular dynamics simulations. The present study extends chip-based trapping techniques to cold molecular ions with potential applications in mass spectrometry, chemistry, quantum information science, and spectroscopy.