Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Journal of Mathematical Physics

A Model of Interacting Radiation and Matter. II

C. R. Willis

Published Dec 1, 1965• 10 citations
Publisher

Abstract

We extend the investigation of the long time behavior of a model consisting of N two-level atoms interacting with radiation to include dissipation, pumping, and center-of-mass motion. We show that when the effective expansion parameter γ̃Nγ̃ is small, the self-consistent field approximation remains the solution to lowest order in γ̃Nγ̃. The inclusion of the center-of-mass motion introduces another dimensionless parameter β into the theory. We show that when this parameter is small, the electromagnetic field amplitude varies slowly on the time scale of the center-of-mass motion. We solve the equations of motion in this slowly varying limit by an extension of the Bogoliuboff-Kryloff theory of quasilinearity to the problem of time-dependent integral kernals. We find the unique stable stationary state and show that in the slowly varying limit the stationary state is approached independent of initial conditions. We calculate the frequency shift to second order in β. The first-order frequency shift is the same as that calculated by Lamb. We compare our steady-state solution with recent experiments with lasers. We include the effect of collisions in the steady state.

DOI
10.1063/1.1704752

Related papers

A Model of Interacting Radiation and Matter

C. R. Willis

We investigate the long-time behavior of a model consisting of N two-level atoms in a lossless cavity. The Hamiltonian of our system contains the radiation oscillators in addition to the matter Hamiltonian and the usual ∫j·Adv interaction term. In order to treat the system perturbatively, it would be necessary to remove the tremendous degeneracy of the system. Since this is prohibitively difficult, and since we are interested in the long-time behavior of the system, we solve the quantum mechanical Liouville equation directly for a wide class of physically important initial distribution functions. We show the effective expansion parameter is γ̃Nγ̃ where γ̃ is a dimensionless atomic dipole moment and N is the number of atoms. In the lowest order we find the self-consistent field approximation. In the next order, particle-field correlations appear. We explicitly solve the equations of motion for the particle-field correlations in terms of the average quantities that appear in the self-consistent field approximation. We show the self-consistent field approximation consists of five first-order differential equations. Next we show the equations of motion for the density matrix of the system correct to order (γ̃Nγ̃)2 are equivalent to eight first-order differential equations. The three additional equations are needed to describe the three second moments of the density matrix of the electromagnetic field that appear in second order. Our lowest-order microscopic equations are equivalent to semiphenomenological theories and our higher-order equations contain only the measurable second-order moments of the electromagnetic field in addition to the variables that appear in semi-phenomenological theories.

Journal of Mathematical Physics•Sep 1, 1964•26 citations

Model of Interacting Radiation and Matter. III. Multimode Gas Lasers

C. R. Willis

We extend the investigation of the long-time behavior of a model consisting of N two-level atoms interacting with a single electromagnetic cavity mode to include interaction with many cavity modes. We show that, as a consequence of the coupling between radiation modes produced by spatial density variations of the population inversion, there is no strictly stationary state possible for multimode behavior. However we obtain a stationary state by neglecting the rapidly oscillating terms. The steady-state population inversion is then a solution of an eigenvalue problem. The eigenvalue determinate is a function of the number of modes and the coupling between modes in addition to the usual dependence on frequencies and relaxation times. We explicitly solve for the unique eigenvalue in special cases. The corresponding eigenvector gives the steady-state mode intensity ratios. The absolute values of the steady-state intensities are determined by the energy conservation equation generalized to include pumping and dissipation. We also calculate the steady-state frequency shifts for each mode. The mode frequency shifts are practically independent of each other and have the same functional form as the single-mode frequency shifts.

Journal of Mathematical Physics•Feb 1, 1966•3 citations

Quantum Theory of a Laser Model

C. R. Willis

We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix $R$ to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where $\mathfrak{N}$ is the number of two-level systems per unit volume, ${r}_{0}$ is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.

Physical Review•Jul 8, 1966•22 citations

Long-Term Solution in Semiclassical Radiation Theory

Carlos R. Stroud, E. T. Jaynes

An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single two-level atom interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein $A$ coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.

Physical Review A•Oct 1, 1970•31 citations

Long-Term Solutions in Semiclassical Radiation Theory

Carlos R. Stroud, E. T. Jaynes

An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single "two-level atom" interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein $A$ coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.

Physical Review A•Jan 1, 1970•169 citations

Quantum Theory of a Gas Laser

C. R. Willis

We derive the equation of motion for the quantum-mechanical radiation density matrix of a gas laser to lowest order in the dimensionless coupling constant. Our derivation is fully quantum mechanical and we can calculate the coherence properties from the radiation density matrix. Our model consists of $N$ two-level systems interacting with radiation in a cavity in the presence of dissipation, pumping, and collisions. The method we use is a generalization of the Bogoliubov derivation of the kinetic equation for a small parameter. Our derivation holds for any physically realizable pump power, and near threshold reduces to Lamb's near-threshold theory. With the equation of motion for the radiation density matrix, we obtain solutions both for when the average field is nonzero and for when it is zero. The steady-state electromagnetic density is the same in both cases except for a small spontaneous-emission term. We show that the reason gas lasers do not satisfy rate equations is the existence of zeroth-order correlations between the internal atomic variables and atomic center-of-mass variables. It is these same zeroth-order correlations which are responsible for the Lamb dip. Our derivation includes collisions and reduces the calculations of their effect to quadrature.

Physical Review•Apr 10, 1967•14 citations
We extend the investigation of the long time behavior of a model consisting of N two-level atoms interacting with radiation to include dissipation, pumping, and center-of-mass motion. We show that when the effective expansion parameter γ̃Nγ̃ is small, the self-consistent field approximation remains the solution to lowest order in γ̃Nγ̃. The inclusion of the center-of-mass motion introduces another dimensionless parameter β into the theory. We show that when this parameter is small, the electromagnetic field amplitude varies slowly on the time scale of the center-of-mass motion. We solve the equations of motion in this slowly varying limit by an extension of the Bogoliuboff-Kryloff theory of quasilinearity to the problem of time-dependent integral kernals. We find the unique stable stationary state and show that in the slowly varying limit the stationary state is approached independent of initial conditions. We calculate the frequency shift to second order in β. The first-order frequency shift is the same as that calculated by Lamb. We compare our steady-state solution with recent experiments with lasers. We include the effect of collisions in the steady state.
We investigate the long-time behavior of a model consisting of N two-level atoms in a lossless cavity. The Hamiltonian of our system contains the radiation oscillators in addition to the matter Hamiltonian and the usual ∫j·Adv interaction term. In order to treat the system perturbatively, it would be necessary to remove the tremendous degeneracy of the system. Since this is prohibitively difficult, and since we are interested in the long-time behavior of the system, we solve the quantum mechanical Liouville equation directly for a wide class of physically important initial distribution functions. We show the effective expansion parameter is γ̃Nγ̃ where γ̃ is a dimensionless atomic dipole moment and N is the number of atoms. In the lowest order we find the self-consistent field approximation. In the next order, particle-field correlations appear. We explicitly solve the equations of motion for the particle-field correlations in terms of the average quantities that appear in the self-consistent field approximation. We show the self-consistent field approximation consists of five first-order differential equations. Next we show the equations of motion for the density matrix of the system correct to order (γ̃Nγ̃)2 are equivalent to eight first-order differential equations. The three additional equations are needed to describe the three second moments of the density matrix of the electromagnetic field that appear in second order. Our lowest-order microscopic equations are equivalent to semiphenomenological theories and our higher-order equations contain only the measurable second-order moments of the electromagnetic field in addition to the variables that appear in semi-phenomenological theories.
We extend the investigation of the long-time behavior of a model consisting of N two-level atoms interacting with a single electromagnetic cavity mode to include interaction with many cavity modes. We show that, as a consequence of the coupling between radiation modes produced by spatial density variations of the population inversion, there is no strictly stationary state possible for multimode behavior. However we obtain a stationary state by neglecting the rapidly oscillating terms. The steady-state population inversion is then a solution of an eigenvalue problem. The eigenvalue determinate is a function of the number of modes and the coupling between modes in addition to the usual dependence on frequencies and relaxation times. We explicitly solve for the unique eigenvalue in special cases. The corresponding eigenvector gives the steady-state mode intensity ratios. The absolute values of the steady-state intensities are determined by the energy conservation equation generalized to include pumping and dissipation. We also calculate the steady-state frequency shifts for each mode. The mode frequency shifts are practically independent of each other and have the same functional form as the single-mode frequency shifts.
We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix RRR to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where N\mathfrak{N}N is the number of two-level systems per unit volume, r0{r}_{0}r0​ is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.
An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single two-level atom interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein AAA coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.
An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single "two-level atom" interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein AAA coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.
We derive the equation of motion for the quantum-mechanical radiation density matrix of a gas laser to lowest order in the dimensionless coupling constant. Our derivation is fully quantum mechanical and we can calculate the coherence properties from the radiation density matrix. Our model consists of NNN two-level systems interacting with radiation in a cavity in the presence of dissipation, pumping, and collisions. The method we use is a generalization of the Bogoliubov derivation of the kinetic equation for a small parameter. Our derivation holds for any physically realizable pump power, and near threshold reduces to Lamb's near-threshold theory. With the equation of motion for the radiation density matrix, we obtain solutions both for when the average field is nonzero and for when it is zero. The steady-state electromagnetic density is the same in both cases except for a small spontaneous-emission term. We show that the reason gas lasers do not satisfy rate equations is the existence of zeroth-order correlations between the internal atomic variables and atomic center-of-mass variables. It is these same zeroth-order correlations which are responsible for the Lamb dip. Our derivation includes collisions and reduces the calculations of their effect to quadrature.