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Oxford University Press eBooks

Spin Chains

Robert Alicki, M. Fannes

Published Jul 12, 2001• 0 citations
Publisher

Abstract

This chapter introduces quantum spin chains for two different purposes: prototypes of infinite quantum systems discretized in space, and general models of stochastic processes in discrete time on a discrete quantum state space. The algebra of local observables is constructed. The probability functionals, i.e. the states, are defined in terms of reduced density matrices with their compatibility relations. Several examples of shift-invariant states are discussed: product states, classical states, and limiting Gibbs states. The chapter concludes with the construction of nearest-neighbour dynamics and the need for an appropriate algebra of quasi-local observables.

DOI
10.1093/acprof:oso/9780198504009.003.0004

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This chapter introduces quantum spin chains for two different purposes: prototypes of infinite quantum systems discretized in space, and general models of stochastic processes in discrete time on a discrete quantum state space. The algebra of local observables is constructed. The probability functionals, i.e. the states, are defined in terms of reduced density matrices with their compatibility relations. Several examples of shift-invariant states are discussed: product states, classical states, and limiting Gibbs states. The chapter concludes with the construction of nearest-neighbour dynamics and the need for an appropriate algebra of quasi-local observables.
This chapter begins with the discussion of various meanings of the entropy: Boltzmann entropy, Shannon entropy, von Neumann entropy. It then presents the basic properties of the von Neumann entropy such as concavity, sub-additivity, strong sub-additivity, and continuity. It proves the existence of mean entropy for shift-invariant states on quantum spin chains, and then derives the expression for the mean entropy for quasi-free Fermions on a chain. The chapter defines the quantum relative entropy and presents its basic properties, including behaviour with respect to completely positive maps. The maximum entropy principle defines thermal equilibrium states (Gibbs states). This variational principle is illustrated by the Hartree–Fock approximation for a model of interacting Fermions. The entropy of an equilibrium state for a free quantum particle on a compact Riemannian manifold is also estimated. Finally, the notion of relative entropy is formulated in the algebraic setting using the relative modular operator.
Abstract This chapter is a review of the recently established quantum-classical correspondence for integrable systems based on the construction of the master T-operator. For integrable inhomogeneous quantum spin chains with gl(N)-invariant R-matrices in finite-dimensional representations, the master T-operator is a sort of generating function for the family of commuting quantum transfer matrices depending on an infinite number of parameters. Any eigenvalue of the master T-operator is the tau-function of the classical modified KP hierarchy. It is a polynomial in the spectral parameter which is identified with the 0th time of the hierarchy. This implies a remarkable relation between the quantum spin chains and classical many-body integrable systems of particles of the Ruijsenaars-Schneider type. As an outcome, a system of algebraic equations can be obtained for the spectrum of the spin chain Hamiltonians.
The spectral statistics and entanglement within the eigenstates of generic spin chain Hamiltonians are analysed. A class of random matrix ensembles is defined which include the most general nearest-neighbour qubit chain Hamiltonians. For these ensembles, and their generalisations, it is seen that the long chain limiting spectral density is a Gaussian and that this convergence holds on the level of individual Hamiltonians. The rate of this convergence is numerically seen to be slow. Higher eigenvalue correlation statistics are also considered, the canonical nearest-neighbour level spacing statistics being numerically observed and linked with ensemble symmetries. A heuristic argument is given for a conjectured form of the full joint probability density function for the eigenvalues of a wide class of such ensembles. This is numerically verified in a particular case. For many translationally-invariant nearest-neighbour qubit Hamiltonians it is shown that there exists a complete orthonormal set of eigenstates for which the entanglement present in a generic member, between a fixed length block of qubits and the rest of the chain, approaches its maximal value as the chain length increases. Many such Hamiltonians are seen to exhibit a simple spectrum so that their eigenstates are unique up to phase. The entanglement within the eigenstates contrasts the spectral density for such Hamiltonians, which is that seen for a non-interacting chain of qubits. For such non-interacting chains, their always exists a basis of eigenstates for which there is no entanglement present.
Random matrix ensembles are introduced that respect the local tensor structure of Hamiltonians describing a chain of nnn distinguishable spin-half particles with nearest-neighbour interactions. We prove a central limit theorem for the density of states when n→∞n \rightarrow\inftyn→∞, giving explicit bounds on the rate of approach to the limit. Universality within a class of probability measures and the extension to more general interaction geometries are established. The level spacing distributions of the Gaussian Orthogonal, Unitary and Symplectic Ensembles are observed numerically for the energy levels in these ensembles.
The entanglement-sharing properties of an infinite spin-chain are studied when the state of the chain is a pure, translation-invariant state with a matrix-product structure (Klümper A., Schadschneider A. and Zittartz J., J. Phys. A , 24 (1991) L955; Z. Phys. B , 87 (1992) 281; Europhys. Lett. , 24 (1993) 293). We study the entanglement properties of such states by means of their finitely correlated structure (Fannes M., Nachtergaele B. and Werner R. F., Comm. Math. Phys. , 144 (1992) 443; Europhys. Lett. , 10 (1989) 633; J. Phys. A , 24 (1991) L185). These states are recursively constructed by means of an auxiliary density matrix ρ on a matrix algebra ℬ and a completely positive map : ⊗ ℬ → ℬ, where is the spin 2 × 2 matrix algebra. General structural results for the infinite chain are therefore obtained by explicit calculations in (finite) matrix algebras. In particular, we study not only the entanglement shared by nearest-neighbours, but also, differently from previous works (Wootters W. K., Contemp. Math. , 305 (2002) 299) the entanglement shared between connected regions of the spin-chain. This range of possible applications is illustrated and the maximal concurrence = 1/√2 (Coffman V., Kundu J. and Wootters W. K., Phys. Rev. A , 61 (2000) 052306) for the entanglement of connected regions can actually be reached.