Simple Harmonic Oscillator (SHO): V = ½ kx2
Steven M. Pascal
Another "simple" potential is one experienced by a spring, the simple harmonic oscillator potential (SHO). To understand how a quantum particle behaves in such a potential, first we study how a classical particle, such as a mass on a spring, behaves. Then we change to using the TISE with the above potential. Solving this TISE is not a simple task. One way of solving a differential equation is to see if someone else has already solved it. Fortunately, a French mathematician named Hermite solved a related equation in the 19 th century. His solutions can be multiplied by a simple exponential function, and these modified Hermite polynomials can be shown to solve the TISE for the SHO. Interestingly, the resulting trapped particles have quantized energies that are evenly spaced. It is for this reason that bond vibrations, which can be modeled as springs on a mass, are found to be quantized in nearly evenly spaced energy levels, at least for relatively small vibrations. The SHO TISE also provides an opportunity to introduce two new operators: the creation and annihilation operators.
CRC Press eBooks•Jul 12, 2023•0 citations