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Chapman & Hall/CRC eBooks

Time Evolution

Tilak Sinha

Published Jun 18, 2021• 0 citations
Publisher

Abstract

In this chapter, we finally introduce time evolution. The development is carried out for finite, enumerable systems (i.e., systems whose states live in a finite dimensional, inner product space) which, of course, allows a straight forward extension to the continuum and infinite dimensional state spaces. The necessary mathematical background of unitary operators, and their properties relevant to quantum mechanics are first introduced. In particular, the fact that preservation of norm under the action of an operator implies unitarity, and that every unitary operator can be expressed as the exponential of i timesa Hermitian operator are introduced. Time evolution is then introduced in its integral form through the time evolution operator, and the Hamiltonian operator is introduced in this context. This approach, however, necessitates the restriction to conservative systems. Next, the differential form of the law of time evolution, i.e., Schrodinger equation, is derived from the time evolution operator, and this is postulated to be the general law of time evolution. We then demonstrate how, for conservative systems, the solution of the Schrodinger equation essentially reduces to solving the eigenvalue problem of the Hamiltonian. Constants of motion and Heisenberg picture have been relegated to the problem section.

DOI
10.1201/9781003090335-6

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In this chapter, we finally introduce time evolution. The development is carried out for finite, enumerable systems (i.e., systems whose states live in a finite dimensional, inner product space) which, of course, allows a straight forward extension to the continuum and infinite dimensional state spaces. The necessary mathematical background of unitary operators, and their properties relevant to quantum mechanics are first introduced. In particular, the fact that preservation of norm under the action of an operator implies unitarity, and that every unitary operator can be expressed as the exponential of i timesa Hermitian operator are introduced. Time evolution is then introduced in its integral form through the time evolution operator, and the Hamiltonian operator is introduced in this context. This approach, however, necessitates the restriction to conservative systems. Next, the differential form of the law of time evolution, i.e., Schrodinger equation, is derived from the time evolution operator, and this is postulated to be the general law of time evolution. We then demonstrate how, for conservative systems, the solution of the Schrodinger equation essentially reduces to solving the eigenvalue problem of the Hamiltonian. Constants of motion and Heisenberg picture have been relegated to the problem section.
Explicitly time-dependent Hamiltonians are ubiquitous in applications of quantum theory. It is therefore necessary to solve the time-dependent Schrödinger equation directly. The system’s dynamics is associated with a unitary time-evolution operator (a propagator), formally given as an infinite Dyson series. Time-dependent observables are invariant under unitary time-dependent transformations, where it is sometimes useful to transform the time-evolution from the states into the corresponding operators. This is carried out in part (in full) by transforming to the interaction (Heisenberg) picture. The corresponding equations of motion for the time-dependent operators are introduced. For quadratic potential energy functions, the time evolution of quantum expectation values coincides with the corresponding classical dynamics. This is demonstrated and analyzed in detail for Gaussian wave packets and a coherent state. Finally, we derive exact and approximate expressions for time-dependent transition probabilities and transition rates between quantum states. The validity of time-dependent perturbation theory is analyzed by comparison to exact dynamics.
ABSTRACT: The main aim of this article is to present the time-evolution as the unitary and self-adjoint operators on Hilbert spaces and to describe its application in the development of quantum mechanics. The initial value problems associated with the quantum mechanical Schrodinger equation, ( ) = ( ) in the Hilbert space is solved by the use of timeevolution. The importance of time-evolution is also seen as the operation of turning machine in quantum mechanics, which is regarded as the time-evolution of the machine control state. Time-evolution of a quantum mechanical system is observed to be unitary and self-adjoint operators of Hilbert space, since it corresponds to an observable, specifically energy position and momentum. It was observed that time-evolution of a quantum mechanical system is generated by a self-adjoint operator, called Hamiltonian, V K H ˆ ˆ ˆ   , expressed by the Schrodinger equation, above.
Abstract The second chapter introduces the notion of wave functions and their equation of motion proposed by Erwin Schrödinger. The interpretation and normalization of the wave function are discussed, leading to the continuity equation. The chapter also introduces basic mathematical operations that can be carried out for wave functions and operators, describing e.g., how to calculate scalar products and commutators, as well as expectation values and variances of observables. With these tools at hand, Heisenberg’s uncertainty principle is re-examined, focusing on the example of a Gaussian wave packet, which is studied both in position space and momentum space. We also discuss the time evolution of general states and of the exemplary wave packet. Finally, we will see how classical physics is recovered as a limiting case of the quantum-mechanical description
The postulates of quantum mechanics associate the time-evolution of a system with its time-dependent Schrödinger equation. We start by examining different solutions to this equation for a particle, represented in terms of a Gaussian wave packet, in different scenarios: free, scattered from a potential energy barrier, or trapped in a potential energy well. In some cases, we encounter stationary solutions, in which the probability density does not change in time (a standing wave). These solutions are identified as eigenfunctions of a system Hamiltonian. The properties of the Hamiltonian as a Hermitian operator are introduced, and particularly, the fact that its proper eigenfunctions can compose an orthonormal set, and that the corresponding eigenvalues are real-valued. Learning that all operators that relate to measurables are Hermitian, and that their eigenvalues relate to the measured values, we conclude that the eigenvalues of the energy operator (Hamiltonian) are the energy levels of the quantum system.
Abstract Chapter 9 begins laying a foundation for quantum statistical mechanics with a discussion of relevant topics in quantum mechanics. The fundamental postulates of quantum mechanics are reviewed, beginning with the definition of a quantum state and the introduction of the concept of a state vector in a Hilbert space. The representation of observables as Hermitian operators on Hilbert space vectors is described; it is shown that the eigenvalues of Hermitian operators are real and, therefore, constitute possible outcomes of measurements made on these observables. The notions compatible and non-compatible observables and implication for the measurement problem are presented. The time-dependent Schrödinger equation is introduced as generating the time-evolution of the state vector, and it is shown how to cast the Schrödinger equation into a coordinate basis to yield the wave equation of quantum mechanics. Coordinate and momentum bases and their properties are desribed. Several analytically solvable quantum systems are presented as illustrative examples. The chapter concludes with a discussion of spin and the treatment identical particles
With the postulates already formulated in the language of an abstract inner product spaces, this chapter shows how an observable can be naturally expressed as a linear Hermitian operator acting on the inner product space where the states live. We start by introducing linear operators acting on vector spaces and their representations. Next, we discuss the systems of eigenvalues and eigenvectors associated with such operators. The important case of Hermitian operator and the properties of their eigenvalues and eigenvectors, relevant to quantum mechanics, are introduced. After developing the necessary background in linear algebra, the connection of Hermitian operators with quantum observables is established. We then proceed to explain what this connection actually accomplishes. In particular, we show how it translates the target questions of quantum mechanics into an eigenvalue problem. This makes it evident what the nature of the input to a quantum theory should be. This input enters the formalism through what are known as “quantization rules”. I discuss this in the last section of this chapter. An illustration using a disguised spin-half system winds up the chapter.