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Quantum statistics

Ian R. Kenyon

Published Sep 10, 2019• 0 citations
Publisher

Abstract

Abstract Indistinguishability of like particles, and the fermion and boson exchange symmetries discussed.Pauli exclusion principle and features of multi-electron atoms, including selection rules are discussed. Degeneracy pressure and the formation of compact stellar objects is analysed. Quantum exchange force between electrons and its contribution to ferromagnetism is outlined. Fermi-Dirac and Bose-Einstein statistics, includng the chemical potential are derived. The conditions for Bose-Einstein condensation are deduced; condensates and their stability are considered.

DOI
10.1093/oso/9780198808350.003.0003

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Abstract Indistinguishability of like particles, and the fermion and boson exchange symmetries discussed.Pauli exclusion principle and features of multi-electron atoms, including selection rules are discussed. Degeneracy pressure and the formation of compact stellar objects is analysed. Quantum exchange force between electrons and its contribution to ferromagnetism is outlined. Fermi-Dirac and Bose-Einstein statistics, includng the chemical potential are derived. The conditions for Bose-Einstein condensation are deduced; condensates and their stability are considered.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
Quantum statistical mechanics is the arithmetic of indistinguishable particles: bosons that pile into a single state and fermions that refuse to share---statistics whose consequences range from the Bose-Einstein condensate, a macroscopic quantum state, to the Fermi gas's pressure that holds white dwarfs against collapse. This article presents a narrative review of the primary literature of that statistics, from Bose's Planck's law and the light quantum hypothesis and Einstein's quantum theory of the monatomic ideal gas with its 1925 second paper predicting the condensation, through Fermi's quantization of the monatomic perfect gas and Dirac's theory of quantum mechanics, which independently founded the Fermi-Dirac statistics, London's identification of the lambda-phenomenon of liquid helium with the Bose-Einstein degeneracy, the experimental vindication of Anderson, Ensher, Matthews, Wieman, and Cornell's observation of Bose-Einstein condensation in a dilute atomic vapor and Davis and colleagues' sodium condensate, DeMarco and Jin's onset of Fermi degeneracy in a trapped atomic gas, and the syntheses of Leggett's fundamental concepts, Pitaevskii and Stringari's Bose-Einstein condensation, and Bloch, Dalibard, and Zwerger's many-body physics with ultracold gases. The synthesis is organized around three themes: the statistics' invention, in which indistinguishability's consequences were computed before any condensate existed; the condensate's realization, in which the dilute atomic vapors delivered Einstein's sixty-year-old prediction; and the many-body era, in which the ultracold gases became quantum simulators of matter's collective behavior. It is concluded that quantum statistics is the theory whose consequences were verified in reverse---predicted abstractly, found in liquid helium, created in atomic vapors---and that its bosons and fermions remain the universe's two grammars.
As a preliminary to discussing the properties of Bose–Einstein and Fermi–Dirac gases, this chapter presents the basic quantum equations that underlie both. The process of building N-body states from single-particle states is described, along with notation necessary to simplify the problem. The average number of particles in a given energy state and chemical potential is derived for fermions and bosons. Although all atoms are either bosons or fermions, and therefore indistinguishable, there are nevertheless real systems that are composed of distinguishable particles. Although all atoms are either bosons or fermions, and therefore indistinguishable, there are nevertheless real systems that are composed of distinguishable particles.
Abstract Two concepts, of fundamental importance to quantum mechanics, will be discussed in this chapter. The first is that of symmetry. Even though the concept of symmetry is familiar in a wide range of natural sciences, the way symmetry constrains the consequences of quantum mechanics is rather subtle and, at the same time, far-reaching. The second is the symmetry property of the states under the exchange of two identical particles. Identical particles with a half-integer spin (fermions) obey the Fermi–Dirac statistics: the wave functions are totally antisymmetric under the exchange of the particles. Identical particles with an integer spin (bosons) are instead subject to the Bose–Einstein statistics. Their wave functions are totally symmetric.
Abstract This chapter starts with a discussion of the symmetry conditions which have to be imposed on the wave function of a many-particle system, and the distinction between bosons and fermions. It then examines the consequences of these conditions for simple systems of non-interacting particles (Fermi-Dirac and Bose-Einstein statistics), and in particular, introduces the phenomenon of Bose-Einstein condensation (BEC) in a noninteracting Bose gas. The phenomenon of Cooper pairing of interacting fermions is introduced by a thought-experiment in which one starts from a BEC of tightly bound diatomic molecules made of fermion atoms and gradually weakens the binding. The chapter closes with a description of the various physical systems to be treated in the book, and an account of the phenomenology of superfluidity and superconductivity. An appendix treats the statistical mechanics of a rotating system.