Quantum mechanics of one particle In quantum mechanics the physical state of a particle is described in terms of a ket |Ψ〉. This ket belongs to a Hilbert space which is nothing but a vector space endowed with an inner product. The dimension of the Hilbert space is essentially fixed by our physical intuition; it is we who decide which kets are relevant for the description of the particle. For instance, if we want to describe how a laser works we can choose those energy eigenkets that get populated and depopulated and discard the rest. This selection of states leads to the well-known description of a laser in terms of a three-level system, four-level system, etc. A fundamental property following from the vector nature of the Hilbert space is that any linear superposition of kets is another ket in the Hilbert space. In other words we can make a linear superposition of physical states and the result is another physical state. In quantum mechanics, however, it is only the “direction” of the ket that matters, so |Ψ〉 and C |Ψ〉 represent the same physical state for all complex numbers C . This redundancy prompts us to work with normalized kets. What do we mean by that? We said before that there is an inner product in the Hilbert space.
Quantum mechanics of one particle In quantum mechanics the physical state of a particle is described in terms of a ket |Ψ〉. This ket belongs to a Hilbert space which is nothing but a vector space endowed with an inner product. The dimension of the Hilbert space is essentially fixed by our physical intuition; it is we who decide which kets are relevant for the description of the particle. For instance, if we want to describe how a laser works we can choose those energy eigenkets that get populated and depopulated and discard the rest. This selection of states leads to the well-known description of a laser in terms of a three-level system, four-level system, etc. A fundamental property following from the vector nature of the Hilbert space is that any linear superposition of kets is another ket in the Hilbert space. In other words we can make a linear superposition of physical states and the result is another physical state. In quantum mechanics, however, it is only the “direction” of the ket that matters, so |Ψ〉 and C |Ψ〉 represent the same physical state for all complex numbers C . This redundancy prompts us to work with normalized kets. What do we mean by that? We said before that there is an inner product in the Hilbert space.
We summarize below some of the postulates and definitions basic to our formalism, and present some important results based on these postulates. The formalism is purely mathematical in nature with very little physics input, but it provides the structure within which the physical concepts that will be discussed in the later chapters will be framed. State vectors It is important to realize that the Quantum Theory is a linear theory in which the physical state of a system is described by a vector in a complex, linear vector space. This vector may represent a free particle or a particle bound in an atom or a particle interacting with other particles or with external fields. It is much like a vector in ordinary three-dimensional space, following many of the same rules, except that it describes a very complicated physical system. We will be elaborating further on this in the following. The mathematical structure of a quantum mechanical system will be presented in terms of the notations developed by Dirac. A physical state in this notation is described by a “ket” vector, |〉, designated variously as |α〉 or |ψ〉 or a ket with other appropriate symbols depending on the specific problem at hand. The kets can be complex. Their complex conjugates, |〉 * , are designated by 〈| which are called “bra” vectors. Thus, corresponding to every ket vector there is a bra vector. These vectors are abstract quantities whose physical interpretation is derived through their so-called “representatives” in the coordinate or momentum space or in a space appropriate to the problem under consideration.
Hilbert space and inner product In Ch. 2 it was noted that quantum wave functions form a linear space in the sense that multiplying a function by a complex number or adding two wave functions together produces another wave function. It was also pointed out that a particular quantum state can be represented either by a wave function ψ( x ) which depends upon the position variable x , or by an alternative function ψ( p ) of the momentum variable p . It is convenient to employ the Dirac symbol |ψ〉, known as a “ket”, to denote a quantum state without referring to the particular function used to represent it. The kets, which we shall also refer to as vectors to distinguish them from scalars , which are complex numbers, are the elements of the quantum Hilbert space H . (The real numbers form a subset of the complex numbers, so that when a scalar is referred to as a “complex number”, this includes the possibility that it might be a real number.) If α is any scalar (complex number), the ket corresponding to the wave function ɑψ( x ) is denoted by α|ψ〉, or sometimes by |ψ〉α, and the ket corresponding to ø( x )+ψ( x ) is denoted by |ø〉+|ψ〉 or |ψ〉+|ø〉, and so forth. This correspondence could equally well be expressed using momentum wave functions, because the Fourier transform, (2.15) or (2.16), is a linear relationship between ψ( x ) and ( p ), so that αø( x )+βψ( x ) and αϕ( p ) + βψ( p ) correspond to the same quantum state α|ψ〉+β|ø〉.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
Quantum mechanics describes the physical state of a microscopic system using vectors in a complex Hilbert space rather than deterministic numerical variables. This mathematical formulation provides a rigorous framework for understanding quantum superposition, probability, and measurement. The Hilbert space structure allows quantum states to be represented as normalized vectors, while inner products define transition probabilities through the Born rule. Linear operators acting on these vectors correspond to measurable physical observables such as position, momentum, and energy. This paper presents a concise mathematical treatment of quantum states in Hilbert space, emphasizing vector representation, superposition, normalization, and projection-based measurement. In addition, the mathematical formulation underlying the concept of quantum immortality is briefly discussed from the perspective of the Many-Worlds Interpretation. The study demonstrates how linear algebra serves as the fundamental language of modern quantum mechanics and provides the theoretical basis for advanced areas including quantum computation, quantum information theory, and quantum communication.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation: There are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be the subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. This latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system.
I start by briefly overviewing quantum mechanics as it is standardly formulated and by discussing the question of whether this standard formulation needs to be supplemented by an interpretation. The overview is based mainly on Von Neumann (1932, 1955) and its aim is not to give the reader a crash course in quantum mechanics, but to present those parts of the standard formalism which I use in this book. For a more complete treatment, the reader may consult the standard textbooks on quantum mechanics or, for instance, Sudbery (1986) or Redhead (1987). The standard formulation The standard formulation of quantum mechanics can be introduced in four steps. The first step is that in quantum mechanics one describesthe physics of a system by means of a Hilbert space ℋ. This Hilbert space is a complex linear vector space on which an inner product is defined. Let's adopt the convention (please consult the Glossary at the end of the book for notational conventions) that α refers to a system and that is the Hilbert space that is associated with this system. Let ∣ℋ α 〉 denote a vector in ℋ α and let 〈ψ α ∣φ α 〉 be the inner product between the vectors ∣ψ α 〉 and ∣φ α 〉.