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International Journal of Quantum Chemistry

Generalized dirac identities and explicit relations between the permutational symmetry and the spin operators for systems of identical particles

Jacob Katriel, Josef Paldus, Reuben Pauncz

Published Jan 1, 1986• 1 citation
Publisher
DOI
10.1002/qua.560290117

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Generalized Dirac identities and explicit relations between the permutational symmetry and the spin operators for systems of identical particles

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Abstract The well known one‐to‐one correspondence between the eigenstates of the total spin for a system of spin‐½ particles and irreducible representations of the symmetric group with up to two rows in the Young shape is the basis of interesting formal developments in quantum chemistry and in the theory of magnetism. As an explicit manifestation of this correspondence the class operators of the symmetric group are demonstrated to be expressible in terms of the total spin operator. This correspondence does not hold for higher elementary spins. The extension to arbitrary spin is investigated using Schrödinger's generalization of the Dirac identity, which expresses the transpositions in terms of two‐particle spin operators. It is shown that additional operators, which for σ = ½ reduce to the total spin operator, are needed for a complete classification. Some aspects of the formalism are developed in detail for σ = 1. In this case a classification identical with that provided by the irreducible representations of the symmetric group is obtained in terms of the eigenstates of two commuting operators, one of which is the total spin operator.

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This study discussed Dirac's bra-ket formalism for the identical particles system based on the rigged Hilbert space reformulated by R. Madrid [J. Phys A:Math. Gen. 37, 8129 (2004)]. The bra and ket vectors for a composite system that form the basis of an identical particle system are described in dual and anti-dual spaces for the tensor product of rigged Hilbert spaces. The permutation operator that characterizes the symmetry of identical particles is constructed as the operator on such dual spaces. We also show that the nuclear spectral theorem in the tensor product of rigged Hilbert spaces endows the spectral expansion of the self-adjoint operator in the dual and anti-dual spaces and the expansion is consistent with the identicle particle system when the permutation operator commutes the self-adjoint operator.

arXiv:2403.00234•Mar 1, 2024•1 citation
Abstract The well known one‐to‐one correspondence between the eigenstates of the total spin for a system of spin‐½ particles and irreducible representations of the symmetric group with up to two rows in the Young shape is the basis of interesting formal developments in quantum chemistry and in the theory of magnetism. As an explicit manifestation of this correspondence the class operators of the symmetric group are demonstrated to be expressible in terms of the total spin operator. This correspondence does not hold for higher elementary spins. The extension to arbitrary spin is investigated using Schrödinger's generalization of the Dirac identity, which expresses the transpositions in terms of two‐particle spin operators. It is shown that additional operators, which for σ = ½ reduce to the total spin operator, are needed for a complete classification. Some aspects of the formalism are developed in detail for σ = 1. In this case a classification identical with that provided by the irreducible representations of the symmetric group is obtained in terms of the eigenstates of two commuting operators, one of which is the total spin operator.
This study discussed Dirac's bra-ket formalism for the identical particles system based on the rigged Hilbert space reformulated by R. Madrid [J. Phys A:Math. Gen. 37, 8129 (2004)]. The bra and ket vectors for a composite system that form the basis of an identical particle system are described in dual and anti-dual spaces for the tensor product of rigged Hilbert spaces. The permutation operator that characterizes the symmetry of identical particles is constructed as the operator on such dual spaces. We also show that the nuclear spectral theorem in the tensor product of rigged Hilbert spaces endows the spectral expansion of the self-adjoint operator in the dual and anti-dual spaces and the expansion is consistent with the identicle particle system when the permutation operator commutes the self-adjoint operator.