Pan Stanford eBooks

Interaction Representation

David K. Ferry

Published Dec 14, 2017• 2 citations

Abstract

At the end of the last chapter, we considered the electron-electron interaction. Here, we found two terms: the Hartree energy and the exchange energy. These work fine if we can solve for the energy exactly. However, as was remarked, this can only be done for a few electron systems. For more meaningful systems, we need to develop an approximation technique for the interacting Green’s functions. The standard approach to this is via the interaction representation, which gives us a prescription for developing the perturbation series. As one might infer from our previous discussion, this will lead to multiple, messy integrals. Fortunately, the Feynman diagrams give us an elegant and pictorial method of looking at the various terms in the perturbation series. As a result, they also give us a much more intuitive method of examining the various terms.

DOI: 10.1201/9781315206226-4

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