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Contemporary Physics

Trapped ions

Günther Werth

Published Jan 1, 1985• 12 citations
Publisher

Abstract

Charged particles can be confined by electromagnetic fields to a finite volume in space for extended periods of time. The extremely long observation time along with the nearly perturbation-free environment under ultra-high vacuum conditions opens new regions of spectroscopy, which are not accessible by other methods. In microwave spectroscopy resonance lines as narrow as Δv/v = 3 × 10−12 have been obtained, which leads directly to the possible development of a new type of frequency standard. Lifetimes of metastable levels in the region of many seconds can be observed, as well as rare collision processes between ions and molecules, which are important for the formation of larger molecules in interstellar space. Finally, phenomena like crystallisation in a non-neutral plasma may be investigated at sub-Kelvin temperafures. accessible by the new technique of laser cooling of ions.

DOI
10.1080/00107518508223684

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Ultracold neutral plasmas (UNPs) are highly correlated, charged-particle systems studied in standard atomic-molecular optical physics laboratories. Advances in ultracold physics techniques have led to the development of magneto-optical traps that permit the localization of micro-Kelvin temperature atomic samples (10⁸ - 10¹⁰ cm -³ that can be photoionized with a defined excess laser energy. Magneto-optical trapping of molecules proves difficult, and to date, lags in reaching conditions attainable for atoms. Molecules possess additional degrees of freedom where energy can flow during laser trapping and cooling. Alternatively, elastic collisions with inert gases offer another route to low temperatures. Super-sonic expansions of target molecules seeded in a noble gas can reduced the translational temperature to values as low as 0.1 K. Here I report on the formation of a molecular ultracold plasma in a molecular beam of nitric oxide seeded in an inert gas. Our method does not directly form a plasma, but instead, I create a Rydberg gas that spontaneously evolves to a plasma. I have verified the transition to a collective plasma state by applying pulsed-fields to the field-free flight region, and observe a signal that persists well beyond classical field amplitudes required to ionize individual Rydberg states. Electric field screening is a collective effect occurring over a characteristic distance, quantified by the Debye length, λ_D. Molecular ultracold plasmas described here exhibit Debye lengths smaller than the overall size, λ_D<<σ. Plasmas of this nature offer an exotic environment for which to study fundamental phenomena. While plasmas are generally thought of as hot, UNPs exist at low enough temperatures that electrostatic interaction energy between particles is greater than their kinetic energy. At this point, charged particles begin to find themselves in local potential energy minima. Over the entire sample this translates to long-range order, or correlation. It is of great interest for researchers studying UNPs to maximize particle correlation, which requires UNPs to remain very cold, and dense through their lifetime.

•Jan 1, 2013•0 citations
Charged particles can be confined by electromagnetic fields to a finite volume in space for extended periods of time. The extremely long observation time along with the nearly perturbation-free environment under ultra-high vacuum conditions opens new regions of spectroscopy, which are not accessible by other methods. In microwave spectroscopy resonance lines as narrow as Δv/v = 3 × 10−12 have been obtained, which leads directly to the possible development of a new type of frequency standard. Lifetimes of metastable levels in the region of many seconds can be observed, as well as rare collision processes between ions and molecules, which are important for the formation of larger molecules in interstellar space. Finally, phenomena like crystallisation in a non-neutral plasma may be investigated at sub-Kelvin temperafures. accessible by the new technique of laser cooling of ions.
One of the current themes in quantum physics is the creation of cold ( 1 K) molecules to study molecule-molecule, molecule-atom, and molecule-radiation interactions under these novel low-temperature conditions. This book highlights the field of cold trapped molecular ions. In particular, the development of a novel, universal cooling method for charged particles, sympathetic cooling using laser-cooled atoms, together with the experimental and computational techniques required are extensively reviewed. The book also reviews first spectacular applications of the cold ion ensembles produced: the study of the properties of cold non-neutral plasmas, the study of ion-neutral chemical reactions and of photodissociation processes, and high-resolution rotational overtone spectroscopy of cold hydrogen molecular ions with unprecedented spectral resolution. The large potential of this field of research and its possible impact to other fields of physics, chemistry, and biology are highlighted. The book summarizes the main lines of research in cold trapped molecular ion physics, thus, making it useful as an introduction for advanced students and experienced researchers.
In an iontrap,laser-cooled ions can be confined in a small space in an ultra-high vacuum so that collisions rarely happen and the ions are well isolated from the environment. Since these conditions enable high-resolution spectroscopy of single ions, laser-cooled ions are suitable for use in developing frequency standards. The ions can be cooled to the motional ground state to give a well-defined initial quantum state for quantum state manipulation and quantum computing. In this review, principles of ion traps and laser cooling, and recent progress in optical frequency standards and quantum computing with trapped ions are described.
We have constructed a compact purely electrostatic ion-beam trap, ConeTrap, which we have mounted inside a double-walled vacuum chamber. In the inner vacuum chamber, we can obtain ultra-high vacuum (UHV) conditions and reach thermal equilibrium at well controlled temperatures down to 10 K. The chamber was constructed partly with the purpose of making high-precision measurements in ConeTrap, but also as a test-chamber for testing components (such as the detector-assembly tested and described in this thesis and paper III) to be used in the DESIREE (Double ElectroStatic Ion Ring ExpEriment) facility. The latter is a double electrostatic ion storage-ring being constructed at Stockholm University, in which the conditions are meant to mimic the environment in the interstellar medium. The interaction between two oppositely charged ions at very low relative velocities (controlled collision energies down to 10 meV) may then be studied in a section of the storage device where the two ion beams merge. The lifetime of loosely bound electronic systems, for example He-, is, at room temperature (and even at much lower temperatures), significantly affected by photons from blackbody radiation from the experimental device and its surroundings. The cryogenic temperature and low pressure obtained in the test chamber have made it possible to use ConeTrap to make the first correction-free lifetime measurement of the long-lived J=5/2 fine-structure level of the metastable 1s2s2p 4Po state of He-. Under the assumption of a statistical population of the fine-structure levels, at the time when the ions are created, we have also deduced the lifetimes of the short-lived J=1/2 and J=3/2 fine-structure levels. Furthermore, we have used ConeTrap to measure the pressure dependent storage lifetimes of He+ and Ar+ ions over wide ranges of temperatures and pressures, and we have thus been able to store positive ions with storage lifetimes of tens of seconds.
Ultracold neutral plasmas (UNPs) are highly correlated, charged-particle systems studied in standard atomic-molecular optical physics laboratories. Advances in ultracold physics techniques have led to the development of magneto-optical traps that permit the localization of micro-Kelvin temperature atomic samples (10⁸ - 10¹⁰ cm -³ that can be photoionized with a defined excess laser energy. Magneto-optical trapping of molecules proves difficult, and to date, lags in reaching conditions attainable for atoms. Molecules possess additional degrees of freedom where energy can flow during laser trapping and cooling. Alternatively, elastic collisions with inert gases offer another route to low temperatures. Super-sonic expansions of target molecules seeded in a noble gas can reduced the translational temperature to values as low as 0.1 K. Here I report on the formation of a molecular ultracold plasma in a molecular beam of nitric oxide seeded in an inert gas. Our method does not directly form a plasma, but instead, I create a Rydberg gas that spontaneously evolves to a plasma. I have verified the transition to a collective plasma state by applying pulsed-fields to the field-free flight region, and observe a signal that persists well beyond classical field amplitudes required to ionize individual Rydberg states. Electric field screening is a collective effect occurring over a characteristic distance, quantified by the Debye length, λ_D. Molecular ultracold plasmas described here exhibit Debye lengths smaller than the overall size, λ_D<<σ. Plasmas of this nature offer an exotic environment for which to study fundamental phenomena. While plasmas are generally thought of as hot, UNPs exist at low enough temperatures that electrostatic interaction energy between particles is greater than their kinetic energy. At this point, charged particles begin to find themselves in local potential energy minima. Over the entire sample this translates to long-range order, or correlation. It is of great interest for researchers studying UNPs to maximize particle correlation, which requires UNPs to remain very cold, and dense through their lifetime.