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CRC Press eBooks

Thermodynamics of Weakly Interacting Bose Gas, BCS Theory

Boris V. Svistunov, Egor S. Babaev, Nikolay V. Prokof'ev

Published Apr 15, 2015• 0 citations
Publisher

Abstract

This chapter deals for the most part with a systematic microscopic description of equilibrium weakly interacting Bose gas (WIBG) in one, two, and three dimensions. Our analysis is based on Beliaev’s diagrammatic technique [1] for Matsubara Green’s functions, regularized with small but finite Bogoliubov’s symmetrybreaking terms. This approach was discussed in detail in Reference [2]; the analytic part of this chapter is based on that paper. At the end of the chapter, we will present the mean-field theory for weakly interacting Fermi gas, or the Bardeen-Cooper-Schrieffer (BCS) solution.

DOI
10.1201/b18346-20

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This chapter deals for the most part with a systematic microscopic description of equilibrium weakly interacting Bose gas (WIBG) in one, two, and three dimensions. Our analysis is based on Beliaev’s diagrammatic technique [1] for Matsubara Green’s functions, regularized with small but finite Bogoliubov’s symmetrybreaking terms. This approach was discussed in detail in Reference [2]; the analytic part of this chapter is based on that paper. At the end of the chapter, we will present the mean-field theory for weakly interacting Fermi gas, or the Bardeen-Cooper-Schrieffer (BCS) solution.
Aiming at simplicity of explicit equations and, at the same time, controllable accuracy of the theory, we present our results for all the thermodynamic quantities and correlation functions for a weakly interacting Bose gas at short-to-intermediate distances obtained within an improved version of Beliaev's diagrammatic technique. With a controllably small (but essentially finite) Bogoliubov's symmetry-breaking term, Beliaev's diagrammatic technique becomes regular in the infrared limit. Up to higher-order terms (for which we present parametric order-of-magnitude estimates), the partition function and entropy of the system formally correspond to those of a non-interacting bosonic (pseudo-)Hamiltonian with a temperature-dependent Bogoliubov-type dispersion relation. Away from the fluctuation region, this approach provides the most accurate—in fact, the best possible within the Bogoliubov-type pseudo-Hamiltonian framework—description of the system with controlled accuracy. It produces accurate answers for the off-diagonal correlation functions up to distances where the behavior of correlators is controlled by generic hydrodynamic relations and, thus, can be accurately extrapolated to arbitrarily large scales. In the fluctuation region, the non-perturbative contributions are given by universal (for all weakly interacting U(1) systems) constants and scaling functions, which can be obtained separately—by simulating classical U(1) models—and then used to extend the description of the weakly interacting Bose gas to the fluctuation region. The technique works in all spatial dimensions, and we explicitly checked the validity of this technique against first-principle Monte Carlo simulations for various thermodynamic properties and the single-particle density matrix.
Abstract This is the first of a series of chapters devoted to interacting Fermi gases, with special focus here on the effects of superfluidity. It starts with a brief discussion of the ideal Fermi gas and then focuses on the properties of dilute interacting Fermi gases. Topics include the weakly repulsive Fermi gas; the gas of composite bosons; the BCS limit of a weakly interacting Fermi gas; the strongly interacting, but still dilute, unitary Fermi gas where the scattering length is much larger than the average interatomic distance; the BCS–BEC crossover; and the Bogoliubov–de Gennes approach. A discussion of the main physical quantities predicted by mean-field theory and by quantum Monte Carlo simulations, including, in particular, the equation of state, the momentum distribution, and the condensation of pairs, is also presented.
We show that the pressure of the Bogoliubov weakly imperfect Bose gas (WIBG) can be calculated exactly in the thermodynamic limit. We point out the sufficient and necessary conditions for it not to equate with the pressure of the ideal Bose gas (IBG). We prove that they differ only in that part of the phase diagram where the WIBG has a Bose condensate. We show that in contast to the conventional Bose condensate (e.g. in the IBG) the condensate in the WIBG is due to an effective attraction between bosons in the zero-mode.
This chapter presents the crossover from the Bardeen-Cooper-Schrieffer (BCS) state of weakly-correlated pairs of fermions to the Bose-Einstein condensation (BEC) of diatomic molecules in the atomic Fermi gas. Our aim is to provide a pedagogical review of the BCS-BEC crossover, with an emphasis on the basic concepts, particularly those that are not generally known or are difficult to find in the literature. We shall not attempt to give an exhaustive survey of current research in the limited space here; where possible, we will direct the reader to more extensive reviews.
In Chapter 3, we introduced a simple but reasonable approximation for the nonequilibrium dynamics of a Bose-condensed gas based on a generalized GP equation coupled to a kinetic equation. In Chapters 4–7, we turn to the question of how to derive such coupled equations for the condensate and noncondensate components in a way that gives a deeper understanding of the ZNG theory. Chapters 4–7 involve an introduction to Green's functions and field theoretic techniques for nonequilibrium problems. These provide the natural language and formalism to deal with the many subtle aspects of a Bose-condensed gas at finite temperatures. These four chapters are fairly technical. This chapter is mainly based on Kadanoff and Baym (1962) and Imamović-Tomasović (2001). Readers who are not interested in these questions can go straight to Chapter 8, which begins the discussion of applications of the ZNG coupled equations given in Chapter 3. Overview of Green's function approach To derive a microscopic theory of the nonequilibrium behaviour of a dilute weakly interacting Bose-condensed gas at finite temperatures, there are several different approaches available in the literature. We will use the wellknown Kadanoff–Baym (KB) nonequilibrium Green's function method. The generalization of this formalism to a Bose-condensed system was first considered by Kane and Kadanoff (1965), whose goal was to derive the Landau two-fluid hydrodynamic equations for a system with a Bose broken symmetry. The general problem consists of how to calculate the nonequilibrium response of a system induced by an external (space- and time-dependent) perturbation. In response to such an external perturbation, many interesting physical phenomena appear, including the excitation of collective modes and various transport processes.
PACS. 03.75.Hh – Static properties of condensates; thermodynamical, statistical and structural properties. PACS. 03.75.Ss – Degenerate Fermi gases. PACS. 05.30.Fk – Fermion systems and electron gas. Abstract. – We present a theory for a superfluid Fermi gas near the BCS-BEC crossover, including pairing fluctuation contributions to the free energy similar to that considered by Nozières and Schmitt-Rink for the normal phase. In the strong coupling limit, our theory is able to recover the Bogoliubov theory of a weakly interacting Bose gas with a molecular scattering length very close to the known exact result. We compare our results with recent Quantum Monte Carlo simulations both for the ground state and at finite temperature. Excellent agreement is found for all interaction strengths where simulation results are available. The recent experimental realization of strongly interacting Fermi gases of 6 Li and 40 K atoms near a Feshbach resonance has opened up the exciting possibility of investigating the crossover from a Bardeen-Cooper-Schrieffer (BCS) superfluid to a Bose-Einstein condensate (BEC) [1–5]. In these systems, the inter-atomic interaction strength can be varied by tuning