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Advances in chemical and materials engineering book series

Interacting Quantum Systems

Published Nov 7, 2013• 0 citations
Publisher

Abstract

In this chapter, basic quantum tools such as time-evolution operators, transition rates and amplitudes, statistical and projector operators, and interaction and density matrix representations are employed to characterize the open and interacting quantum systems with the aid of Schrödinger, quantum master, Fokker-Planck, and Feynman path integral equations and formulations.

DOI
10.4018/978-1-4666-4687-2.ch001

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In this chapter, basic quantum tools such as time-evolution operators, transition rates and amplitudes, statistical and projector operators, and interaction and density matrix representations are employed to characterize the open and interacting quantum systems with the aid of Schrödinger, quantum master, Fokker-Planck, and Feynman path integral equations and formulations.
Basically, there are two approaches to the formulation of quantum mechanics, i.e., the operator and the Feynman path integral approach. The main object in quantum mechanics is referred to as the transition amplitude between those states, matrix elements of physical operators and, in particular, the S- matrix in the problem of quantum scattering. On the basis of quantum mechanics, the operator method is closed, well formulated mathematically, and so is an appropriate universal language describing quantum field theory, the quantum physics of condensed states and quantum relativistic statistical physics. The differential equation defining the path of the system in the configuration space is called the equation of motion of the system. The aim of classical as well as quantum mechanics is to predict the time evolution of the system, starting from knowledge of the state of the system at a given point in time.
The quantizer–dequantizer method is employed. Using the construction of probability distributions describing density operators of a quantum system states, the connection between the Feynman path integral and the time evolution of the density operator (Landau density matrix) as well as the wave function of the stateconsidered. For single–mode systems with continuous variables, a tomographic propagator is introduced in the probability representation of quantum mechanics. An explicit expression for the probability in terms of the Green function of the Schrödinger equation is obtained. Equations for the Green functions defined by arbitrary integrals of motion are derived. Examples of probability distributions describing the evolution of state of a free particle, as well as states of systems with integrals of motion that depend on time (oscillator type) are discussed.
Abstract This chapter introduces the density operator and the Liouville equation and outlines how reduced dynamical description of open quantum systems naturally leads to the appearance of relaxation processes. (1) The density operator and the quantum Liouville equation (the density matrix for a pure system, statistical mixtures, representations, coherences, thermodynamic equilibrium). (2) An example: The time evolution of a two-level system in the density matrix formalism. (3) Reduced descriptions. (4) Time evolution equations for reduced density operators: The quantum master equation (projection operators, The Nakajima–Zwanzig equation, Derivation of the quantum master equation using the thermal projector, The quantum master equation in the interaction representation, The Markovian limit—the Redfield equation, The secular approximation and the Lindblad equation). (5) The Lindblad equation in the ‘Heisenberg representation’. (6) Relaxation of a two-level system and a harmonic oscillator revisited. (7) The optically driven two-level system in a thermal environment—the Bloch equations. (8) The oscillating dipole model of a two-level molecule. (9) Analogy of a coupled two-level system to a spin ½ system in a magnetic field.
All the chapters of the book have examined and studied various aspects of path integrals and Hamiltonians, which in turn exemplified different aspects of quantum mathematics. The principles of quantum mathematics, stated in Chapter 2, can be summarized as follows: • The fundamental degrees of freedom F form the bedrock of the quantum system. • A linear vector state space V based on the degrees of freedom F provides an exhaustive description of the quantum system. • Operators O, which includes the Hamiltonian H , represent the physical properties of the degree of freedom and act on the state space V . Observable quantities are the matrix elements of the physical operators. • A spacetime description of quantum indeterminacy is encoded in the Lagrangian L and the Dirac–Feynman formula relates it to the Hamiltonian. • The path integral provides a representation of all the physical properties of a quantum system. In particular, the path integral yields the correlation functions of the degrees of freedom as well as the probability amplitudes for quantum transitions. • The interconnection of the path integral with the underlying Hamiltonian and state space is a specific feature of quantum mathematics that distinguishes path integration from functional integration in general.
In this chapter we study some properties of systems of coupled quadratic quantum Hamiltonians. The well known example is coupled harmonic oscillators appearing in the Quantum Brownian Motion. An open system is a physical (S) interacting with the environment (E) such that the total system (S∪E)(S\cup E)(S∪E) is isolated from the rest of the universe. So we have two independent Hamiltonians H^S\hat{H}_SH^S​, H^E\hat{H}_EH^E​ and an interaction V^\hat{V}V^ between (S) and (E). The main problem discussed for open systems is to understand the dynamical action of the interaction V^\hat{V}V^ with the environment on the time dependent evolution of (S) which is now irreversible because a part of its energy escapes to the environment. An important physical effect of the interaction of the environment on a quantum system is decoherence which give an explanation for the mechanism driving the quantum-to-classical transition. We restrict ourself to few mathematical problems related with this very active field of research in physics [155, 200, 231, 270]. In a first part we study the purity of a state of (S) (or the linear entropy) in a short time approximation. In a second part we discuss the separability of bipartite systems. In a third part we establish a master equation (or a Fokker-Planck type equation) for the time evolution of the reduced matrix density for coupled quadratic Hamiltonians by a bilinear inter-action. We give an explicit formula for the solution of this master equation so that the time evolution of the reduced density at time t is written as a convolution integral for the reduced density at initial time t0=0t_0=0t0​=0, with a Gaussian kernel, for 0≤t<tc0 \le t < t_c0≤t<tc​ where tc∈]0,∞]t_c\in ]0, \infty ]tc​∈]0,∞] is a critical time such that reversibility is lost for t>tct > t_ct>tc​ if tc<+∞t_c<+\infty tc​<+∞. Some manifestations of decoherence, for t>0t>0t>0 small enough, are proved on our simple model which is similar to a representation of the Schrödinger cat.
Open quantum systems describe quantum systems that interact unavoidably with their environments. These notes introduce the physical origins of decoherence and dissipation in realistic settings, developing the theoretical framework of reduced dynamics and quantum master equations within the connection to thermodynamics in the quantum regime. Additionally, a set of relevant exercises are proposed to reinforce the acquisition of knowledge. The text equips readers with the tools to model and analyze open quantum dynamics.