The fundamental equation of quantum mechanics for a single particle is generally taken to be a Schrödinger equation of the form
iℏ∂t∂ψ(x,t)=[−2mℏ2∂x2∂2+V(x,t)]ψ(x,t), subject to some initial condition such as
limt→t′ψ(x,t)=ψ(x,t′).For a nonrelativistic quantum system of
N particles, the wave function is a function of
3N spatial coordinates and one temporal coordinate. The relativistic generalization of this wave function is a function of
N time variables known as the multitime wave function, and its evolution is described by
N Schrödinger equations, one for each time variable. To guarantee the existence of a nontrivial common solution of these
N equations, the
N Hamiltonians must satisfy a compatibility condition known as the integrability condition. In this work, the integrability condition is expressed in terms of Lagrangians. The time evolution of a wave function with
N time variables is derived in Feynman’s picture of quantum mechanics. However, these evolutions are compatible if and only if the
N Lagrangians satisfy a certain relation called the consistency condition, which can be expressed in terms of Wilson line. As a consequence of this consistency condition, the evolution of the wave function gives rise to a key feature called the “path-independence” property on the space of time variables. This suggests that one must consider all possible paths not only on the space of dependent variables (spatial variables) but also on the space of independent variables (temporal variables). Geometrically, this consistency condition can be regarded as a zero-curvature condition and the multitime evolutions can be treated as compatible parallel transport processes on the flat space of time variables.
The Weyl transform is applied in quantum dynamics to derive and extend Moyal's statistical theory of phase-space distributions for noncommuting coordinate and momentum operators. The distinction is made between Weyl transforms in Schrödinger and Heisenberg pictures; the general case of time-dependent Hamiltonians is considered. The Wigner function for the probability distribution in a phase space of Cartesian coordinates Q and momenta K propagates according to a conditional probability P(t, Q, K | t0, Q0, K0), which is exhibited as a Feynman path integral in phase space. Properties of P(t, Q, K | t0, Q0, K0) are developed; it is expressed in terms of the quantum generalization of the classical Liouville operator. The Weyl transform of a Heisenberg operator propagates according to P(t, Q0, K0 | t0, Q, K) which is also given as a Feynman path integral. An equation for the time evolution of Weyl transforms of Heisenberg operators is obtained, according to which the transform of Heisenberg coordinate and momentum operators obey a quantum form of Hamilton's equations of motion. If the initial density operator of the system commutes with the coordinate operator, then the state of the system is a mixture of pure coordinate states; the spectrum of the density operator in this case is continuous. For a Heisenberg operator AH(t) with Weyl transform AH(t, Q, K), the function A(t,Q)=∫dKAH(t,Q,K) is the expectation at time t of the dynamical property for a quantum system initially in a pure state of coordinate Q; it is the quantum-mechanical generalization of the dynamical property of the system along the classical trajectory in configuration space at time t. The probability amplitude for the time dependence of A(t,Q) can be expressed as a Feynman path integral with a Heisenberg Lagrangian. The amplitude of the conditional probability P(t, Q | t0, Q0) considered by Feynman is expressed as a path integral with a Schrödinger Lagrangian. The velocity in the Heisenberg Lagrangian is the negative of that in the Schrödinger Lagrangian of Feynman, but it agrees with the velocity appearing in the Hamiltonian equations. It is the Heisenberg Lagrangian that is the Lagrangian of classical dynamics. For a particle whose potential energy is a function of position, a quantum form of Newton's second law is obtained. An extension of the formalism to non-Cartesian coordinate systems is given.
While it is well-known that quantum mechanics can be reformulated in terms of a path integral representation, it will be shown that such a formulation is also possible in the case of classical mechanics. From Koopman-von Neumann theory, which recasts classical mechanics in terms of a Hilbert space wherein the Liouville operator acts as the generator of motion, we derive a path integral representation of the classical propagator and suggest an efficient numerical implementation using fast fourier transform techniques. We then include a first quantum correction to derive a revealing expression for the semi-classical path integral, which augments the classical picture of a single trajectory through phase space with additional wave-like spreading.
In quantum theory, vortex lines arise in the hydrodynamic interpretation of the wave equation. In this interpretation, which is originally due to Madelung, the flow of the probability density for a single particle is described in terms of the hydrodynamic variables. For the sake of simplicity, the standard time-dependent Schrödinger equation, and the related vortex lines embedded in the probability fluid of the quantum particle, are considered here. A vortex line in this case is simply the curve defined by equating the wave function to zero. The linearity of the Schrödinger equation enables us to obtain a large family of exact time-dependent analytic solutions for the wave functions with vortex lines. Moreover, the method is general enough to allow for various initial configurations of the vortex lines. Although the equation of motion of the quantum mechanical probability fluid is different in its literal form from the equations describing the real physical fluid, we believe that the evolution of the vorticity in the quantum and in the real fluid share the same qualitative features that can be described in terms of the topology of the vortex lines configurations. The general phenomena such as the switch-over, creation and annihilation of vortices can be observed in the quantum mechanical fluid. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.