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Springer series in optical sciences/SPringer series in optical sciences

Measurement of a Diamagnetic Shift in Atomic Hyperfine Structure

Nicholas P. Economou, Steven J. Lipson, Daniel J. Larson

Published Jan 1, 1977• 0 citations
Publisher
DOI
10.1007/978-3-540-35968-5_55

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The diamagnetic shifts of the mJ=0{m}_{J}=0mJ​=0 and ${m}_{J}=\ifmmode\pm\else\textpm\fi{}1$ components of 6snp1P16snp ^{1}P_{1}6snp1P1​ (n=40,55,70,85,100n=40,55,70,85,100n=40,55,70,85,100) and 6s55p3P0,16s55p ^{3}P_{0, 1}6s55p3P0,1​ Rydberg states of 172,174Yb^{172,\phantom{\rule{0ex}{0ex}}174}\mathrm{Yb}172,174Yb have been measured in external magnetic fields up to ≌3 kG by high-resolution three-photon spectroscopy. The diamagnetic shifts have been analyzed to yield the singlettriplet mixing due to spin-orbit interaction. At n=40n=40n=40, the singlet-triplet mixing derived from diamagnetic shifts and hyperfine-structure data are in excellent agreement.
We report on the measurement of the isotope shifts of the 3d74sa5F5–3d74pz5G6o3{d}^{7}4s\phantom{\rule{0.28em}{0ex}}a\phantom{\rule{0.28em}{0ex}}{}^{5}{F}_{5}\text{--}3{d}^{7}4p\phantom{\rule{0.28em}{0ex}}z\phantom{\rule{0.28em}{0ex}}{}^{5}{G}_{6}^{o}3d74sa5F5​–3d74pz5G6o​ Fe i line at 358 nm between all four stable isotopes 54Fe,56Fe,57Fe^{54}\text{Fe},\phantom{\rule{0.16em}{0ex}}^{56}\text{Fe},\phantom{\rule{0.16em}{0ex}}^{57}\text{Fe}54Fe,56Fe,57Fe, and 58Fe^{58}\text{Fe}58Fe, as well as the hyperfine structure of that line for 57Fe^{57}\text{Fe}57Fe, the only stable isotope having a nonzero nuclear spin. This line is of primary importance for laser-cooling applications. In addition, an experimental value of the field and specific mass shift coefficients of the transition is reported as well as the hyperfine structure magnetic dipole coupling constant AAA of the transition excited state in 57Fe^{57}\text{Fe}57Fe, namely A(3d74pz5G6o)=31.241(48)A(3{d}^{7}4p\phantom{\rule{0.28em}{0ex}}z\phantom{\rule{0.28em}{0ex}}{}^{5}{G}_{6}^{o})=31.241(48)A(3d74pz5G6o​)=31.241(48) MHz. The measurements were carried out by means of laser-induced fluorescence spectroscopy performed on an isotope-enriched iron atomic beam. All measured frequency shifts are reported with relative uncertainties below one third percent.