Abstract Discusses with some rigour the properties of electrons, based on the Schrodinger equation. Introduces the concepts of wave function, quantum-mechanical operators, and wave packets. Examples cover the electron meeting an infinitely long potential barrier and the passage of electrons through a finite barrier (which leads to the phenomenon of tunnelling).The electron in a potential well is also discussed, solving the problem both for a finite and for an infinite well, and finding the permissible energy levels. The chapter is concluded with the philosophical implications that arise from the quantum-mechanical approach. Two limericks relevant to the subject are quoted.
Abstract Discusses with some rigour the properties of electrons, based on the Schrodinger equation. Introduces the concepts of wave function, quantum-mechanical operators, and wave packets. Examples cover the electron meeting an infinitely long potential barrier and the passage of electrons through a finite barrier (which leads to the phenomenon of tunnelling).The electron in a potential well is also discussed, solving the problem both for a finite and for an infinite well, and finding the permissible energy levels. The chapter is concluded with the philosophical implications that arise from the quantum-mechanical approach. Two limericks relevant to the subject are quoted.
Abstract Introduces the Schrödinger wave equation as the key equation governing the behaviour of electrons, and presents simple solutions (known as wave functions) as electron waves, and packets of electron waves, which can represent localised, particle-like electrons. Considers the behaviour of electron waves on meeting a potential barrier and trapped in potential wells with finite and infinite walls, and introduces the idea of energy levels. Discusses the accepted interpretation of the electron wave function, namely that its modulus square leads to the probability of finding an electron in a given region of space. Considers further the uncertainty relationship and associated philosophical implications.
The Schrödinger equation assumes that a particle behaves as a wave and yields a solution in terms of wave function and the energy of the particle under consideration. Once the wave function is known, then everything about the particle can be deduced from the wave function. This chapter covers the development of the Schrödinger wave equation and its applications to one-dimensional systems. Time-dependent and time-independent Schrödinger equations, bound and scattering states, probability density, probability current and expectation values, the solution of the time-independent 1D-Schrödinger equation for a free particle, infinite as well as finite potential wells, potential steps, and the finite potential barrier are discussed in detail in the chapter. The phenomenon of tunneling, relevance and the importance of the free particle, potential wells and potential barriers to contemporary fields of physics and chemistry, periodic solids and their band structures, the Kronig-Penney model, confined states in quantum wells, and wires and dots are other topics presented in innovative manners in the chapter. The importance of the topics presented here is demonstrated through carefully chosen solved examples and unsolved exercises from contemporary fields of sciences.
Abstract This chapter contains a review of quantum mechanics of one-electron systems, suitable for undergraduate students with a limited background of modern physics. It is first explained that matter consists of electrons and nuclei, and the concept of wave functions is introduced. The Schrödinger equation is then presented, and it is shown how the static Schrödinger equation emerges from the stationary limit of the time-dependent Schrödinger equation. Two examples are discussed: the particle in a box and plane waves. The chapter finishes by listing important concepts and properties of quantum mechanics, such as probability density, normalization, observables, operators, energy spectra, and orthonormal sets.
3.4. SummaryIn this Chapter, we have shown the limitations of classical mechanics and the success of quantum mechanics. The basic concepts and formalism of quantum mechanics have been exposed, including the quantized nature of the electromagnetic field, the wave-particle duality, the probability of presence of a particle, the wavefunction, and the Schrödinger equation. Simple quantum mechanical systems have been analyzed to understand these novel concepts, including an infinite and a finite potential well. Through these, some aspects of quantum mechanics have been discussed, including the quantization of energy levels and momenta, and tunneling effects.
N 1923, during the infancy of the quantum theory, de Broglie [ 11 introducted a new fundamental hypothesis that matter may be endowed with a dualistic natureparticles may also have the characteristics of waves. This hypothesis, in the hands of Schrodinger [2] found expression in the definite form now known as the Schrodinger wave equation, whereby an electron or a particle is assumed to be represented by a solution to this equation. The continuous nonzero nature of such solutions, even in classically forbidden regions of negative kinetic energy, implies an ability to penetrate such forbidden regions and a probability of tunneling from one classically allowed region to another. The concept of tunneling, indeed, arises from this quantum-mechanical result. The subsequent experimental manifestations of this concept can be regarded as one of the early triumphs of the quantum theory. In 1928, theoretical physicists believed that tunneling could occur by the distortion, lowering or thinning, of a potential barrier under an externally applied high electric field. Oppenheimer [3] attributed the autoionization of excited states of atomic hydrogen to the tunnel effect: The coulombic potential well which binds an atomic electron could be distorted by a strong electric field so that the electron would see a finite potential barrier through which it could tunnel. Fowler and Nordheim [4] explained, on the basis of electron tunneling, the main features of the phenomenon of electron emission from cold metals by high external electric fields, which had been unexplained since its observation by Lilienfeld [SI in 1922. They proposed a one-dimensional model. Metal electrons are confined by a potential wall whose height is determined by the work function 9 plus the Fermi energy E/, and the wall thickness is substantially decreased with an externally applied high electric field, allowing electrons to tunnel through the potential wall, as shown in Fig. 1. They successfully derived the well-known Fowler-Nordheim formula for the current as a function of electric field F: J = AF* exp [-4(2nr)1'*t$a'*/3kF]. An application of these ideas which followed almost immediately came in the model for a decay as a tunneling process put forth by Gamow [6] and Gurney and Condon [7]. Subsequently, Rice [8] extended this theory to the description of molecular dissociation. The next important development was an attempt to invoke tunneling in order to understand transport properties of electrical contacts between two solid conductors. The problems of metal-to-metal and semiconductor-to-metal contacts are important technically, because they are directly related to electrical switches and rectifiers or detectors.
N 1923, during the infancy of the quantum theory, de Broglie [ 11 introducted a new fundamental hypothesis that matter may be endowed with a dualistic natureparticles may also have the characteristics of waves. This hypothesis, in the hands of Schrodinger [2] found expression in the definite form now known as the Schrodinger wave equation, whereby an electron or a particle is assumed to be represented by a solution to this equation. The continuous nonzero nature of such solutions, even in classically forbidden regions of negative kinetic energy, implies an ability to penetrate such forbidden regions and a probability of tunneling from one classically allowed region to another. The concept of tunneling, indeed, arises from this quantum-mechanical result. The subsequent experimental manifestations of this concept can be regarded as one of the early triumphs of the quantum theory. In 1928, theoretical physicists believed that tunneling could occur by the distortion, lowering or thinning, of a potential barrier under an externally applied high electric field. Oppenheimer [3] attributed the autoionization of excited states of atomic hydrogen to the tunnel effect: The coulombic potential well which binds an atomic electron could be distorted by a strong electric field so that the electron would see a finite potential barrier through which it could tunnel. Fowler and Nordheim [4] explained, on the basis of electron tunneling, the main features of the phenomenon of electron emission from cold metals by high external electric fields, which had been unexplained since its observation by Lilienfeld [SI in 1922. They proposed a one-dimensional model. Metal electrons are confined by a potential wall whose height is determined by the work function 9 plus the Fermi energy E/, and the wall thickness is substantially decreased with an externally applied high electric field, allowing electrons to tunnel through the potential wall, as shown in Fig. 1. They successfully derived the well-known Fowler-Nordheim formula for the current as a function of electric field F: J = AF* exp [-4(2nr)1'*t$a'*/3kF]. An application of these ideas which followed almost immediately came in the model for a decay as a tunneling process put forth by Gamow [6] and Gurney and Condon [7]. Subsequently, Rice [8] extended this theory to the description of molecular dissociation. The next important development was an attempt to invoke tunneling in order to understand transport properties of electrical contacts between two solid conductors. The problems of metal-to-metal and semiconductor-to-metal contacts are important technically, because they are directly related to electrical switches and rectifiers or detectors.