Two particles are said to be identical when it is not possible to distinguish one particle from the other particle with their inherent physical properties such as mass, charge, spin, etc. Study of identical particles is important for two reasons: 1. Many-body systems contain usually identical particles and 2. they give rise quantum mechanical phenomena that have no classical analogues.
Two particles are said to be identical when it is not possible to distinguish one particle from the other particle with their inherent physical properties such as mass, charge, spin, etc. Study of identical particles is important for two reasons: 1. Many-body systems contain usually identical particles and 2. they give rise quantum mechanical phenomena that have no classical analogues.
Details of the many-particle system can also be read from my book titled “Quantum Field Theory: Feynman Path Integrals and Diagrammatic Techniques in Condensed Matter” [ 23 ]. The fundamental difference between classical and quantum mechanics relates the concept of indistinguishability of identical particles where each particle can be equipped with an identifying marker without influencing its behavior in classical mechanics. Besides in classical mechanics, the particle follows its own continuous path in phase space and so it is possible to determine the particular process taking place. So, principally, each particle in a group of identical particles can be identified which is not so in quantum mechanics. It is not possible to mark a particle without influencing its physical state, and worse, if a number of identical particles are brought to the same region in space, their wave functions will rapidly spread out and overlap with one another, thereby soon rendering it impossible to say which particle is where. One of the fundamental assumptions for many-particle systems is therefore that identical particles (i.e., particles characterized by the same quantum numbers such as mass, charge and spin) are, in principle, indistinguishable.
Two particles are said to be identical if all their intrinsic properties, e.g., mass, electrical charge, spin, colour are exactly the same. Similarly, all protons are identical to one another, and so are all quarks. They possess the same defining properties under similar interactions with each other. The exchange in position of identical particles has a so-called permutation symmetry. Clearly, this permutation symmetry is extremely important for quantum mechanical calculations of the multi-indistinguishable particles. So knowing how a collection of fermions (or bosons) behave is kinematically determined by their permutation symmetry. If we have different cycles in a permutation and there is no element common to any two different cycles, then all these cycles are termed disjoint. In fact any permutation of a finite set is the product of disjoint cycles. A cycle of length two is called a transposition.
For a quantum mechanical system of N particles, the Hamiltonian is a sum of the total kinetic energy and the potential energy. In classical physics, it is possible to keep track of individual particles. A system of N identical particles is said to satisfy Bose-Einstein statistics if its wave function is symmetric under the exchange of particles, and these particles are known as bosons. In the nonrelativistic quantum mechanics, this principle must be accepted as an empirical postulate. In the relativistic quantum theory, it can be proven that half-integer-spin particles cannot be bosons and integer-spin particles cannot be fermions. The Pauli exclusion principle plays a critical role in programming physical properties of electrons or more generally fermions.
Particles that must have symmetric states are called bosons; pions, photons, and He 4+ nuclei are such particles. Particles whose states must be ant symmetric under interchange of the two particles are called fermions; electrons, protons, and neutrons are examples of fermions. Particles with integer spin are always bosons while particles with half-integer spin are always fermions. It is not at all obvious from the point of view of non-relativistic quantum mechanics why this relation, called the connection between spin and statistics, is true, and one must look within the framework of relativistic quantum field theory to understand it fully theoretically. Effects of identity can also show up in the scattering of seemingly non-identical particles. The elastic scattering of a He 4+ ion from a He 4+ atom, both are in their ground states. These are certainly distinguishable particles, since they have different charges. Particle identity also plays an important role in determining the properties of molecules made of identical atoms.
Abstract According to classical physics particles are basic building blocks of the world. These classical particles are distinguishable objects, individuated by unique combinations of physical properties. By contrast, in quantum mechanics the received view is that particles of the same kind (“identical particles”) are physically indistinguishable from each other and lack identity. This doctrine rests on the quantum mechanical (anti)symmetrization postulates together with the “factorist” assumption that each single particle is represented in exactly one factor space of the tensor product Hilbert space of a many-particle system. Even though standard in theoretical physics and the philosophy of physics, the assumption of factorism and the ensuing indistinguishability of particles are problematic. Particle indistinguishability is irreconcilable with the everyday meaning of “particle”, and also with how this term is used in the practice of physics. Moreover, it is a consequence of the standard view that identical quantum particles remain indistinguishable even in the classical limit, which makes a smooth transition to the classical particle concept impossible. Lubberdink (1998; 2009) and Dieks and Lubberdink (2011) have proposed an alternative conception of quantum particles that does not rely on factorism and avoids these difficulties. We further explain and discuss this alternative framework here. One of its key consequences is that particles in quantum theory are not fundamental but emergent; another that once they have emerged, quantum particles are always physically distinguishable and thus possess a physically grounded identity.
Although many of the principles of quantum mechanics can be adequately illustrated by considering systems that consist of only one particle subject to external forces, there are a number of important phenomena that are manifest only in systems containing two or more particles, and these will be the subject of the present chapter. We shall begin with some general statements and go on to consider the case of two interacting particles subject to no external forces, when we shall find that, in this case, the problem can be separated into one describing the behaviour of the centre of mass of the system and another describing the relative motion. We shall then consider the case of two noninteracting particles and show that these can often be treated independently as would be expected. In the case of indistinguishable particles, however, we shall find that a symmetry is imposed on the wave function that ensures that the behaviour of such particles is coupled even when they do not interact. We shall introduce the problem of interacting systems containing more than two identical particles, explaining what is meant by “fermions” and “bosons” and how their properties compare. These results will be illustrated by discussing the energy levels and optical spectra of the helium atom, starting with the approximation that the two electrons do not interact and extending the discussion to the realistic case using perturbation theory. The chapter closes with a consideration of the effects of particle indistinguishability on scattering theory.