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CRC Press eBooks

Particle Motion in One Dimension

Walter Wilcox

Published Apr 19, 2016• 0 citations
Publisher

Abstract

Synopsis: After drilling down to the basic theory, the process of building up the quantum description from experiment is continued. ƒe reader is introduced to the Schrödinger equation and related concepts. ƒe emphasis is on what experiment tells us about particle properties, and various experiments as well as the Bohr model are used to motivate wave/particle dualism ideas. It is argued that the Fourier transform is the mathematical concept needed to build in this dualism. ƒe Schrödinger equation is deduced from an analogy with the wave equation and connection is made to the ideas of probability. Finally, the entire formalism is recovered and illuminated by reconnecting to the more formal spin basis ideas of the first chapter.

DOI
10.1201/b11927-5

Related papers

Particle Motion in One Dimension

Walter Wilcox

Synopsis: After drilling down to the basic theory, the process of building up the quantum description from experiment is continued. The reader is introduced to the Schrödinger equation and related concepts. The emphasis is on what experiment tells us about particle properties, and various experiments as well as the Bohr model are used to motivate wave–particle dualism ideas. It is argued that the Fourier transform is the mathematical concept needed to build in this dualism. The Schrödinger equation is deduced from an analogy with the wave equation, and connection is made to the ideas of probability. Finally, the entire formalism is recovered and illuminated by reconnecting to the more formal spin basis ideas of the first chapter.

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Assuming a background in basic classical physics, multivariable calculus, and differential equations, A Concise Introduction to Quantum Mechanics provides a self-contained presentation of the mathematics and physics of quantum mechanics. The relevant aspects of classical mechanics and electrodynamics are reviewed, and the basic concepts of wave-particle duality are developed as a logical outgrowth of experiments involving blackbody radiation, the photoelectric effect, and electron diffraction. The Copenhagen interpretation of the wave function and its relation to the particle probability density is presented in conjunction with Fourier analysis and its generalization to function spaces. These concepts are combined to analyze the system consisting of a particle confined to a box, developing the probabilistic interpretation of observations and their associated expectation values. The Schrödinger equation is then derived by using these results and demanding both Galilean invariance of the probability density and Newtonian energy-momentum relations. The general properties of the Schrödinger equation and its solutions are analyzed, and the theory of observables is developed along with the associated Heisenberg uncertainty principle. Basic applications of wave mechanics are made to free wave packet spreading, barrier penetration, the simple harmonic oscillator, the Hydrogen atom, and an electric charge in a uniform magnetic field. In addition, Dirac notation, elements of Hilbert space theory, operator techniques, and matrix algebra are presented and used to analyze coherent states, the linear potential, two state oscillations, and electron diffraction. Applications are made to photon and electron spin and the addition of angular momentum, and direct product multiparticle states are used to formulate both the Pauli exclusion principle and quantum decoherence. The book concludes with an introduction to the rotation group and the general properties of angular momentum.

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Finding that in the formula of expansion of a function into a series of wave-like functions the coefficients are its Fourier transforms, if existed, we deduce mathematically all the principles and hypothesis that illustrated physicists utilized to build quantum mechanics a century ago, beginning with the duality particle-wave principle of Planck and including the Schrödinger equations. By the way, we find a simple Fourier transform relation between Dirac momentum and position bras and a useful permutation relation between operators in phase and Hilbert spaces. Moreover, from the found particle-wave duality formula we prove and obtain again essentially by mathematical analysis all the laws of wave optics concerning reflections, refractions, polarizations, diffractions by one or many identical 3D objects with various forms and dimensions.

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It was Erwin Schrodinger who, in 1925, discovered an appropriate form of wave equation, making use of some deep formal analogies between optics and classical particle mechanics that had been evolved in the nineteenth century by W. R. Hamilton and others. There is all the accumulated evidence that the Schrodinger equations work; they provide the basis for a correct analysis of all kinds of molecular, atomic, and nuclear systems. The theoretical basis for the existence of states of discrete energies emerges more or less directly from the wave-particle duality; one of the most familiar features of classical wave behavior is that of standing waves. The quantum amplitudes for a particle in a bound state can be normalized. In order to make the statistical interpretation of the wave function more precise, we need to use the quantitative ideas of probability distributions.

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Theory of quanta

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1: The Birth of Quantum Theory. 1.1: The radiation of an ideal black body. 1.2: Line spectra and Bohr's model of the atom. 1.3: The quantum conditions of Bohr-Sommerfield. 1.4: Waves of matters. Comments. Problems. 2: Classical Physics - Quantum Physics. 2.1: The difficulties of classical theory. 2.2: The successes of quantum theory. 2.3: Problems with interpretation of quantum theory. 2.4: Quantum theory (1930. Problems. II: Schrodinger's Equation and the Interpretation of its Solutions. 3: Schrodinger's Equation. 3.1: The Schrodinger equation with time. 3.2: The time-dependent Schrodinger equation. Comments. Problems. 4: The Probabilistic Interpretation of the Wavefunction. Comments. Problems. 5: The Motion of a Free Particle in Wave Mechanics. 5.1: The spreading of wave packets. 5.2: The initial problem for Schrodinger's free particle equation. 5.3: The Gaussian wave packet. Comments. Problems. 6: The Momentum of a Particle and the Fourier Transformation of the Wavefunction. Comments. Problems. 7: Description of Experiments in Wave Mechanics and the Heinsberg Uncertainty Principle. 7.1: Heisenberg's uncertainty principle. 7.2: The entropic uncertainty principle. Comments. Problems. 8: A Charged Particle in an Electromagnetic Field. Comments. Problems. 9: The Hydrodynamic Formulation of Wave Mechanics. 9.1: The motion of the probability fluid in an electromagnetic field. Comments. Problems. 10: The Spin of the Elctron and Pauli's Equation. 10.1: The magnetic moment vector. 10.2: Pauli's equation. 10.3: The Stern-Gerlach experiments. Comments. Problems. 11: The Hydrodynamic Picture of Wave Mechanics of a Particle with Spin. Comments. Problems. 12: Ehrenfest's Equations. 12.1: A particle with spin in the electromagnetic field. Problems. 13: Descriptiopn of Particle Motion in Phase Space -- Wigner's Function. Comments. Problems. 14: Mixed States. 14.1: An unpolarized beam as a mixed state. Comments. Problems. III: Solutions of Schrodinger's Equation. 15: Classification of Solutions to Schrodinger's Equation. 15.1: Scattering states. 15.2: The completeness of the set of bound and scattering state wavefunctions. 15.3: Orthogonality of the wavefunctions. 15.4: Development of the system in time. 15.5: Bound and scattered states. Problems. 16: Bound States and Energy. 16.1: The three-dimensional spherically symmetric potential well. Comments. Problems. 17: Scattering States and Collision Cross-sections. 17.1: One-dimensional scattering. 17.2: The method of integral equations. 17.3: Three-dimensional scattering. 17.4: The scattering amplitude. 17.5: The S matrix. 17.6: Collision cross-section. 17.7: The optical theorem. Comments. Problems. 18: Partial Waves and Wave Effects in Scattering. 18.1: Phase shifts. 18.2: The spherical potential hump. 18.3: The Ramsauer-Townsend effect. 18.4: The extinction paradox. Comments. Problems. 19: Resonance States. Problems. 20: The Coulomb Potential. 20.1: Bound states. 20.2: Scattering states. Comments. Problems. 21

Oxford University Press eBooks•Jan 1, 1992•80 citations
Synopsis: After drilling down to the basic theory, the process of building up the quantum description from experiment is continued. ƒe reader is introduced to the Schrödinger equation and related concepts. ƒe emphasis is on what experiment tells us about particle properties, and various experiments as well as the Bohr model are used to motivate wave/particle dualism ideas. It is argued that the Fourier transform is the mathematical concept needed to build in this dualism. ƒe Schrödinger equation is deduced from an analogy with the wave equation and connection is made to the ideas of probability. Finally, the entire formalism is recovered and illuminated by reconnecting to the more formal spin basis ideas of the first chapter.
Synopsis: After drilling down to the basic theory, the process of building up the quantum description from experiment is continued. The reader is introduced to the Schrödinger equation and related concepts. The emphasis is on what experiment tells us about particle properties, and various experiments as well as the Bohr model are used to motivate wave–particle dualism ideas. It is argued that the Fourier transform is the mathematical concept needed to build in this dualism. The Schrödinger equation is deduced from an analogy with the wave equation, and connection is made to the ideas of probability. Finally, the entire formalism is recovered and illuminated by reconnecting to the more formal spin basis ideas of the first chapter.
Assuming a background in basic classical physics, multivariable calculus, and differential equations, A Concise Introduction to Quantum Mechanics provides a self-contained presentation of the mathematics and physics of quantum mechanics. The relevant aspects of classical mechanics and electrodynamics are reviewed, and the basic concepts of wave-particle duality are developed as a logical outgrowth of experiments involving blackbody radiation, the photoelectric effect, and electron diffraction. The Copenhagen interpretation of the wave function and its relation to the particle probability density is presented in conjunction with Fourier analysis and its generalization to function spaces. These concepts are combined to analyze the system consisting of a particle confined to a box, developing the probabilistic interpretation of observations and their associated expectation values. The Schrödinger equation is then derived by using these results and demanding both Galilean invariance of the probability density and Newtonian energy-momentum relations. The general properties of the Schrödinger equation and its solutions are analyzed, and the theory of observables is developed along with the associated Heisenberg uncertainty principle. Basic applications of wave mechanics are made to free wave packet spreading, barrier penetration, the simple harmonic oscillator, the Hydrogen atom, and an electric charge in a uniform magnetic field. In addition, Dirac notation, elements of Hilbert space theory, operator techniques, and matrix algebra are presented and used to analyze coherent states, the linear potential, two state oscillations, and electron diffraction. Applications are made to photon and electron spin and the addition of angular momentum, and direct product multiparticle states are used to formulate both the Pauli exclusion principle and quantum decoherence. The book concludes with an introduction to the rotation group and the general properties of angular momentum.
The new quantum theory was a mathematical description of the way in which an electron behaves when bounded by some kind of potential – such as being in an electric field, acting as a harmonic oscillator or simply being confined to a certain area of space. This mathematical description was then interpreted to be a description of the electron as being probabilistic. It was Schrödinger’s wave equation, together with de Broglie’s concept of a matter wave, that led to various important concepts like the Heisenberg uncertainty principle, an explanation of the emission and absorption of photons in atoms, quantum tunnelling and so on. This chapter explains what Schrödinger did – the marriage of waves and particles.
Finding that in the formula of expansion of a function into a series of wave-like functions the coefficients are its Fourier transforms, if existed, we deduce mathematically all the principles and hypothesis that illustrated physicists utilized to build quantum mechanics a century ago, beginning with the duality particle-wave principle of Planck and including the Schrödinger equations. By the way, we find a simple Fourier transform relation between Dirac momentum and position bras and a useful permutation relation between operators in phase and Hilbert spaces. Moreover, from the found particle-wave duality formula we prove and obtain again essentially by mathematical analysis all the laws of wave optics concerning reflections, refractions, polarizations, diffractions by one or many identical 3D objects with various forms and dimensions.
It was Erwin Schrodinger who, in 1925, discovered an appropriate form of wave equation, making use of some deep formal analogies between optics and classical particle mechanics that had been evolved in the nineteenth century by W. R. Hamilton and others. There is all the accumulated evidence that the Schrodinger equations work; they provide the basis for a correct analysis of all kinds of molecular, atomic, and nuclear systems. The theoretical basis for the existence of states of discrete energies emerges more or less directly from the wave-particle duality; one of the most familiar features of classical wave behavior is that of standing waves. The quantum amplitudes for a particle in a bound state can be normalized. In order to make the statistical interpretation of the wave function more precise, we need to use the quantitative ideas of probability distributions.
1: The Birth of Quantum Theory. 1.1: The radiation of an ideal black body. 1.2: Line spectra and Bohr's model of the atom. 1.3: The quantum conditions of Bohr-Sommerfield. 1.4: Waves of matters. Comments. Problems. 2: Classical Physics - Quantum Physics. 2.1: The difficulties of classical theory. 2.2: The successes of quantum theory. 2.3: Problems with interpretation of quantum theory. 2.4: Quantum theory (1930. Problems. II: Schrodinger's Equation and the Interpretation of its Solutions. 3: Schrodinger's Equation. 3.1: The Schrodinger equation with time. 3.2: The time-dependent Schrodinger equation. Comments. Problems. 4: The Probabilistic Interpretation of the Wavefunction. Comments. Problems. 5: The Motion of a Free Particle in Wave Mechanics. 5.1: The spreading of wave packets. 5.2: The initial problem for Schrodinger's free particle equation. 5.3: The Gaussian wave packet. Comments. Problems. 6: The Momentum of a Particle and the Fourier Transformation of the Wavefunction. Comments. Problems. 7: Description of Experiments in Wave Mechanics and the Heinsberg Uncertainty Principle. 7.1: Heisenberg's uncertainty principle. 7.2: The entropic uncertainty principle. Comments. Problems. 8: A Charged Particle in an Electromagnetic Field. Comments. Problems. 9: The Hydrodynamic Formulation of Wave Mechanics. 9.1: The motion of the probability fluid in an electromagnetic field. Comments. Problems. 10: The Spin of the Elctron and Pauli's Equation. 10.1: The magnetic moment vector. 10.2: Pauli's equation. 10.3: The Stern-Gerlach experiments. Comments. Problems. 11: The Hydrodynamic Picture of Wave Mechanics of a Particle with Spin. Comments. Problems. 12: Ehrenfest's Equations. 12.1: A particle with spin in the electromagnetic field. Problems. 13: Descriptiopn of Particle Motion in Phase Space -- Wigner's Function. Comments. Problems. 14: Mixed States. 14.1: An unpolarized beam as a mixed state. Comments. Problems. III: Solutions of Schrodinger's Equation. 15: Classification of Solutions to Schrodinger's Equation. 15.1: Scattering states. 15.2: The completeness of the set of bound and scattering state wavefunctions. 15.3: Orthogonality of the wavefunctions. 15.4: Development of the system in time. 15.5: Bound and scattered states. Problems. 16: Bound States and Energy. 16.1: The three-dimensional spherically symmetric potential well. Comments. Problems. 17: Scattering States and Collision Cross-sections. 17.1: One-dimensional scattering. 17.2: The method of integral equations. 17.3: Three-dimensional scattering. 17.4: The scattering amplitude. 17.5: The S matrix. 17.6: Collision cross-section. 17.7: The optical theorem. Comments. Problems. 18: Partial Waves and Wave Effects in Scattering. 18.1: Phase shifts. 18.2: The spherical potential hump. 18.3: The Ramsauer-Townsend effect. 18.4: The extinction paradox. Comments. Problems. 19: Resonance States. Problems. 20: The Coulomb Potential. 20.1: Bound states. 20.2: Scattering states. Comments. Problems. 21