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Springer eBooks

Heteronuclear Single Quantum Coherence

Published Jan 1, 2005• 8 citations
Publisher
DOI
10.1007/3-540-29623-9_201

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The Journal of Chemical Physics•Nov 15, 2000•15 citations
We formulate and exactly solve a model for coherent association and dissociation of fermionic heteronuclear dimers in the deep-lattice Mott regime. Starting from the onsite three-component atom--molecule Hamiltonian, we show how the single-site model maps to the paradigmatic Jaynes--Cummings Hamiltonian from quantum optics. In this mapping, the fermionic molecular/free-atom sector forms an effective two-level system, while the bosonic atomic mode plays the role of the oscillator degree of freedom. We fix the conserved number of fermionic constituent atoms to one but allow an arbitrary conserved number NNN of bosonic constituent atoms. The accessible doublet is then ∣e,N−1⟩↔∣g,N⟩|e,N-1\rangle\leftrightarrow|g,N\rangle∣e,N−1⟩↔∣g,N⟩, and the coherent conversion coupling is bosonically enhanced to χNχ\sqrt{N}χN​. Exact analytic expressions are derived for molecular dissociation, atom-pair association, mode populations, and boson--fermion correlation dynamics. The model provides a transparent matter-wave realization of Jaynes--Cummings physics in a heteronuclear Bose--Fermi system and an exactly solvable setting for understanding coherent atom--molecule conversion and bosonic enhancement in lattice systems.
We report analytical solutions to the unitary bound problem for coherence/polarization transfer in IS two-spin-12 systems by means of unitary operations. Theoretical upper bounds for the transfer efficiency along with the associated optimum transformation operators are obtained analytically by decomposing the unitary operator as a product of exponentials in the special unitary Lie group SU(4). Addressing NMR spectroscopy as a specific example, the method is demonstrated for the non-Hermitian transfers I−→S− and 2I−Sz→S− being relevant for heteronuclear single-quantum coherence (HSQC) experiments as well as the double- to single-quantum transfer I−S−→I−Sβ+IβS− being representative for coherence-order and spin-state-selective transfer in INADEQUATE CR experiments. Furthermore, using a Lagrangian function approach it is demonstrated how the method enables analytical description of two-dimensional bounds for Iz→Sz cross polarization.