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Mathematical physics studies

An Application to Transition Probability

Fabio Bagarello

Published Jan 1, 2022• 0 citations
Publisher
DOI
10.1007/978-3-030-94999-0_8

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Rotating wave approximation (RWA) plays a key rule in quantum optics to solve some Schrödinger equation approximately. For example, it is well known that RWA has been used to calculate the transition probability. However, so far no one shows the validity of RWA. Recently Larson [J. Larson, Phys. Rev. Lett. 108, 033601 (2012)] gave the first example showing that the application of RWA in the Jaynes-Cummings model may lead to false conclusions. In this paper, we analytically and numerically show that the application of RWA leads to false conclusions about the transition probability for the near or exact resonance.
An expansion formula for Stark effect transition probabilities is derived in terms of field-free (spherical) transition probabilities. Expansion coefficients are squares of Clebsch-Gordan coefficients from the SO(4) = SU(2) \ifmmode\times\else\texttimes\fi{} SU(2) description of the hydrogen atom. The method provides new sum rules for Stark transitions which explain regularities in previous calculations. Accurate formulas for average Stark transition probabilities obtain from application of the method to an empirical model for field-free transition probabilities. The approximation permits estimation of Stark lifetimes in the large-nnn regime.
We identify a nontrivial multistate Landau–Zener (LZ) model for which transition probabilities between any pair of diabatic states can be determined analytically and exactly. In the semiclassical picture, this model features the possibility of interference of different trajectories that connect the same initial and final states. Hence, transition probabilities are generally not described by the incoherent successive application of the LZ formula. We discuss reasons for integrability of this system and provide numerical tests of the suggested expression for the transition probability matrix.