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CRC Press eBooks

Representation theory of quantum states

Tao Xiang

Published Mar 31, 2022• 0 citations
Publisher

Abstract

A number of quantum states form an orthonormal and complete basis set if they are normalized and mutually orthogonal and any quantum state can be expressed as a linear combination. In classical mechanics, any two physical variables are commutable. However, this property is no longer valid for physical operators. Commutation of operators is an important property of quantum mechanics. Although there are many representations of wave functions and observables connected by unitary transformations, it is useful to distinguish certain classes of representations, called pictures, which differ in the way the time evolution of the system is treated. The Schrodinger picture is one in which the operators are time-independent but the wave function is time dependent. The virial theorem relates the kinetic energy to its potential in an energy eigenstate.

DOI
10.1201/9781003174882-3

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A number of quantum states form an orthonormal and complete basis set if they are normalized and mutually orthogonal and any quantum state can be expressed as a linear combination. In classical mechanics, any two physical variables are commutable. However, this property is no longer valid for physical operators. Commutation of operators is an important property of quantum mechanics. Although there are many representations of wave functions and observables connected by unitary transformations, it is useful to distinguish certain classes of representations, called pictures, which differ in the way the time evolution of the system is treated. The Schrodinger picture is one in which the operators are time-independent but the wave function is time dependent. The virial theorem relates the kinetic energy to its potential in an energy eigenstate.
In classical mechanics the state of a system is defined by the numerical values of a set of dynamical variables such as the position coordinates and the velocities. In quantum mechanics the state of a system at an instant is represented by a unit vector in a Hilbert space, where a set of axes are the eigenvectors of a complete set of observables. The description of quantum dynamics where the wave function is time-dependent and the operators describing the observables are time-independent is known as the Schrodinger picture. The use of total time derivative of operator that depends on the time evolution of the wave function as well as on any intrinsic time-dependence in the operators simplifies the development of quantum mechanics and allows the development to more closely follow the corresponding development of classical mechanics. The difference between the Schrodinger and Heisenberg pictures is best understood as the difference in the basic set of observables.
This chapter demonstrates how one can find the time evolution of the operators from the knowledge of the time evolution of the state vector, and vice versa. It introduces a unitary operator and discusses the concept of a unitary transformation to show how one could transfer the time dependence from the state vectors to the operators. The possibility that either the state vectors or the operators can depend explicitly on time will lead to introduce the Schrodinger, Heisenberg, and interaction pictures. The chapter discusses the fundamental differences between these pictures. It also discusses the Ehrenfest theorem, which shows under which conditions quantum mechanics predicts the same results for measured physical quantities as classical physics. It illustrates unitary transformations of an arbitrary operator Â(t) which can depend explicitly on time. Quantum mechanics produces the same result as classical mechanics for a system in which particles are represented by well-localized wave functions.
This chapter considers the idea of representing physical as well as nonphysical quantities by operators and collect together some frequently used operator techniques. It postulates that any quantity in quantum physics is specified by a linear operator. In a manipulation with operators, it is very important to maintain the order of the operators because operator algebra is not in general commutative for multiplication. An important concept in quantum physics is a commutator. The chapter focuses on to define a special class of operators called Hermitian operators. They are distinguished by the relationship of  and † The Hermitian operators are of great importance in quantum physics, as they represent physical (measurable) quantities. The chapter defines a very important property of wave functions: orthogonality. This property, for example, allows to identify whether the given wave functions belong to the same operator or not. The orthogonality condition of two functions is analogous to the orthogonality condition of two vectors.
In non-relativistic quantum mechanics, there exist several different ways of describing the time dependence of dynamics of physical systems. Of particular importance for quantum scattering theory are the Schrodinger, Heisenberg and Dirac pictures. For establishing a connection between quantum mechanical formalisms and classical mechanics, as well as for investigating relativistic solutions, the Heisenberg picture appears to be the most convenient. This picture of quantum mechanics is particularly adapted for the examination of free fields. The customary wave-mechanical version of quantum theory is obtained if we choose, e.g., in the framework of the Schrodinger picture to work with the coordinate representation. Possible results of measurements on a quantum system are called eigenvalues. To each of the latter values corresponds one or more eigenstates. An eigenstate is degenerate when more than one eigenstate correspond to a single eigenvalue.
We review the postulates of quantum mechanics with respect to the representation of physical states and measurable quantities, their time evolution, and the interpretation of measurements. We first formulate the postulates in terms of wave functions and differential operators, and then reformulate them in the abstract Hilbert space of state vectors, using Dirac’s notations. Improper states subject to Dirac’s delta normalization are introduced, and the space of physical states is extended to include them. The postulates are rationalized by associating each Hermitian linear operator with a complete orthonormal system of its eigenvectors, where measurement probabilities depend on the projections of these eigenvectors on the system’s state vector. Particularly, wave functions are identified as projections of state vectors on the position operator eigenstates. State vectors representing multidimensional systems are formulated as tensor products of vectors in their subspaces. Finally, we address the general uncertainty relations in simultaneous measurements of different observables.
Some aspects of the interpretation of quantum theory are discussed.It is emphasized that quantum theory is formulated in a Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutator relations between 'canonically conjugated' coordinate and momentum operators leads to a wrong version of quantum mechanics.In this connection the Feynman integral formalism is also discussed.In this formalism the measure is not well-defined and there is no idea how to distinguish between the true version of quantum mechanics and an incorrect one; it is rather a mnemonic rule to generate perturbation series from an undefined zero order term.The origin of time is analyzed in detail by the example of atomic collisions.It is shown that the time-dependent Schrödinger equation for the closed three-body (two nuclei + electron) system has no physical meaning since in the high impact energy limit it transforms into an equation with two independent time-like variables; the time appears in the stationary Schrödinger equation as a result of extraction of a classical subsystem (two nuclei) from a closed three-body system.Following the Einstein-Rosen-Podolsky experiment and Bell's inequality the wave function is interpreted as an actual field of information in the elementary form.The relation between physics and mathematics is also discussed.