Quantum Mechanics in Mathematics, Chemistry, and Physics

Herbert Ackland Pohl

Donald D. Fitts

This text presents a rigorous mathematical account of the principles of quantum mechanics, in particular as applied to chemistry and chemical physics. Applications are used as illustrations of the basic theory. The first two chapters serve as an introduction to quantum theory, although it is assumed that the reader has been exposed to elementary quantum mechanics as part of an undergraduate physical chemistry or atomic physics course. Following a discussion of wave motion leading to Schrödinger's wave mechanics, the postulates of quantum mechanics are presented along with essential mathematical concepts and techniques. The postulates are rigorously applied to the harmonic oscillator, angular momentum, the hydrogen atom, the variation method, perturbation theory, and nuclear motion. Modern theoretical concepts such as hermitian operators, Hilbert space, Dirac notation, and ladder operators are introduced and used throughout. This text is appropriate for beginning graduate students in chemistry, chemical physics, molecular physics and materials science.

María Luisa Dalla Chiara

Jonathan Tennyson

In 1929 Paul Dirac pronounced that "the underlying physical laws necessary for the mathematical theory for a large part of physics and the whole of chemistry are...completely known". While the fundamental aspects of non-relativistic quantum mechanics have remained essentially unchanged ever since, physics and chemistry have been driven largely by experiment. Dirac had the answer to that too. To his comment he added a rider: "The difficulty is only that the exact application of these laws leads to equations much too complicated to be soluble."

Walter E Thirring, Evans M. Harrell

Jürgen Brickmann