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Siberian Journal of Physics

Coherent Transients in a Gas 13CH3F Generated by Step Switch of Electric Field

Anton A. Rozhin, Ледовских Дмитрий Васильевич, Н. Н. Рубцова

Published Oct 1, 2011• 0 citations
Publisher

Abstract

Transient signals of optical nutations and free polarization decay arising in a gas 13CH3F (rotational transition R(4,3) of vibration mode 0–1 ν3 ) at the step-wise switch of electric field in the presence of resonant radiation of CO2 laser are investigated. In the limit of low intensity of radiation the peaks of free polarization decay are observed; the frequency of their appearance is proportional to the electric field strength. The number of observable peaks of free polarization decay decreases at laser intensity growth, and free polarization decay signal becomes indistinguishable at a background of optical nutations at high laser intensity. At high laser intensity the signal of transient optical nutations dominates. Results of calculations are in qualitative agreement with experimental data

DOI
10.54362/1818-7919-2011-6-3-5-10

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Transient signals of optical nutations and free polarization decay arising in a gas 13CH3F (rotational transition R(4,3) of vibration mode 0–1 ν3 ) at the step-wise switch of electric field in the presence of resonant radiation of CO2 laser are investigated. In the limit of low intensity of radiation the peaks of free polarization decay are observed; the frequency of their appearance is proportional to the electric field strength. The number of observable peaks of free polarization decay decreases at laser intensity growth, and free polarization decay signal becomes indistinguishable at a background of optical nutations at high laser intensity. At high laser intensity the signal of transient optical nutations dominates. Results of calculations are in qualitative agreement with experimental data
Free polarization decay and photon echo were studied experimentally in polar gas 13CH3F at the transition R(4,3) of vibrational mode 0 yields 1 (nu) 3 by Stark switching of molecular levels under irradiation by CW CO2 laser at 9P(32) line. Application of 4.5 mcs pulse to the Stark electrodes inside the gas cell allows to detect the free polarization decay signal, combined with the optical nutation. The sign of the signal corresponds to the increase of absorption in the limit of low intensity (not over 0.01 W/cm2) saturating radiation. Exciting intensity growth till the level of 6.0 W/cm2 implies decrease of signal absolute value, till the change of its sign, while the oscillation of the free polarization decay signal reveals remarkable frequency shift. Such behavior is attributed to the combined action of the dynamic Stark effect of CW radiation field and the levels splitting by the Stark voltage. Two shorter (of about 0.1 and 0.2 mcs) Stark pulses, applied to the gas, generate the photon echo signals detected by the same heterodyne technique. The study of the variations of photon echo parameters versus exciting radiation intensity is in progress.
The possibility of controlling the processes of the free-polarization decay and photon echo in a gas by means of resonant CW radiation has been shown. The photon echo and free-polarization decay are formed using the method of the Stark switching of levels in a low-intensity radiation field in the presence of an orthogonally polarized strong field. The experiments in the gas at the R(4, 3) transition in the vibrational band 0 ↔ 1 v3 13CH3F in the presence of radiation from a CW CO2 laser and the calculations by the evolution operator method show a strong effect of the high-intensity radiation field on the photon echo and free-polarization decay to its complete suppression.
Free polarization decay formed by Stark switching technique in a presence of 9P(32) CO2 laser low intensity radiation in a low pressure gas 13CH3F is investigated as a function of Stark field strength. Rotation transition R(4,3) of vibrational mode 0 ↔ 1 ν3 was used. The beatings between free polarization signals originating from transitions with different magnetic quantum numbers appeared as periodic peaks with the period inversely proportional to the Stark field strength. The weighted difference between permanent dipole moments of upper and lower vibration states is estimated from these data, in agreement with known values of permanent dipole moments.
Coherent transient phenomena can be generated by the abrupt changes of parameters either of the electromagnetic field or of the matter. Comparative analysis of these two approaches, made on the base of experimental research in molecular gases SF6, 15NH3, HFCO and 13CH3F, excited by the radiation of CW CO2 and 13CO2 lasers, is presented. The first approach of photon echo (and its modifications) generation, based on electro-optic pulses formation from the resonant CW exciting radiation, has proven to be successful for intense infrared molecular transitions. The coherent responses are sufficiently powerful to be applied in high resolution spectroscopy, the spectral markers creation ,and molecular collisions investigations. However, this technique is not very effective for the free polarization decay investigations. Another approach based on the Stark switching molecular levels of polar gas, irradiated by CW laser, was demonstrated for free polarization decay and photon echo generation in 13CH3F. Free polarization decay has shown the pronounced frequency shift because of dynamic Stark effect in the CW radiation field. This specific feature of coherent transients, created by Stark switching, limits the high resolution spectroscopy by the low intensity range of exciting radiation. From other viewpoint, it gives unique possibility to investigate coherent transients generated at the dressed molecular levels.
Possibilities for the control of the parameters of free-polarization decay (FPD), optical nutation, and photon echo (PE) using the dressing field are studied. Coherent transients are generated with the Stark switching technique and are detected in the radiation of the probe field polarized orthogonally to the dressing field. The evolution-operator technique is employed in the calculations. The experiments are performed at the R (4, 3) transition of the 0 ↔ 1 v 3 13 CH 3 F vibrational band with the radiation of a cw CO 2 laser. It is theoretically and experimentally demonstrated that FPD and PE are suppressed upon an increase in the intensity of the dressing field. The observed shapes of the transient FPD and PE signals and their variations with the dressing field intensity are in qualitative agreement with the results of the calculations.